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Modified titanium dioxide/bamboo charcoal composite environment-friendly aerogel and preparation method thereof

A titanium dioxide and composite technology, which is applied in the field of modified titanium dioxide/bamboo charcoal composite environmental protection airgel and its preparation, can solve the problems of no visible light photocatalysis, small specific surface area of ​​airgel, and uneven pore size distribution. Achieve non-irritating, pore size distribution, strong photocatalysis, and improve the effect of photocatalysis

Active Publication Date: 2015-06-17
秦皇岛杰康视电子科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, there are the following problems in the preparation of existing titanium dioxide airgel: (1) titanium source generally adopts butyl titanate, and butyl titanate will decompose to produce titanium dioxide and butanol, butanol not only smells bad, but also toxic, It can cause skin diseases and endanger health; (2) Since there is no modification of titanium dioxide, titanium dioxide airgel does not have visible light photocatalysis, and has no functions such as sterilization and releasing far-infrared rays and negative oxygen ions; (3) the prepared The specific surface area of ​​the airgel is small, the porosity is low, and the pore size distribution is uneven.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] Example 1: Dissolve 10 mL of ethyl titanate in 8 mL of absolute ethanol, then add 0.001 g of hexadecyl glucoside and stir evenly to obtain solution A; dissolve 1 mL of 0.004 mol / L silver nitrate solution in water with 0.01 In the mixed solution of mL glacial acetic acid, stir evenly to obtain solution B; drop solution B into solution A, the volume ratio of solution A to solution B is 1:0.06, and then add 2% aluminum borosilicate Potassium 400-mesh bamboo charcoal powder 0.001g, stir evenly, leave still to obtain wet gel, age the wet gel at room temperature for 20h, add absolute ethanol to soak for 5h, remove unreacted liquid in the gel, separate and remove ethanol, Then wash with n-hexane to remove the modified solution; put the washed product in a microwave oven and heat it up to 110°C for 5 hours, and then cool it to room temperature to obtain the modified titanium dioxide / bamboo charcoal composite environmentally friendly airgel; the ratio of the airgel The surface a...

Embodiment 2

[0025] Example 2: Dissolve 10 mL of ethyl titanate in 2 mL of absolute ethanol, then add 0.003 g of cetyl glucoside and stir evenly to obtain solution A; dissolve 2 mL of 0.005 mol / L silver nitrate solution in deionized water and 0.02mL glacial acetic acid mixture, stir evenly to obtain solution B; drop solution B into solution A drop by drop, the volume ratio of solution A to solution B is 1:2, and then add borosilicate mixed with 6% 0.02g of 400-mesh bamboo charcoal powder of Potassium Aluminate, stirred evenly, left to stand to obtain a wet gel, aged the wet gel at room temperature for 20h, added absolute ethanol and soaked for 5h, removed the unreacted liquid in the gel, separated and removed ethanol, and then washed with n-hexane to remove the modified solution; the washed product was placed in a microwave oven and heated to 115°C for 3.5 hours, and then cooled to room temperature to obtain the modified titanium dioxide / bamboo charcoal composite environmentally friendly ai...

Embodiment 3

[0026] Example 3: Dissolve 10 mL of ethyl titanate in 5 mL of absolute ethanol, then add 0.005 g of octadecyl glucoside and stir evenly to obtain solution A; dissolve 3 mL of 0.004 mol / L silver nitrate solution in deionized water and 0.05mL glacial acetic acid mixture, stir evenly to obtain solution B; drop solution B into solution A drop by drop, the volume ratio of solution A to solution B is 1:0.5, and then add borosilicate mixed with 3% 0.003g of 350-mesh bamboo charcoal powder of potassium aluminum acid, stir evenly, and let stand to obtain wet gel, age the wet gel at room temperature for 20h, add absolute ethanol to soak for 5h, remove unreacted liquid in the gel, separate and remove ethanol, and then washed with n-hexane to remove the modified solution; the washed product was placed in a microwave oven and heated to 120°C for 3 hours, and cooled to room temperature to obtain the modified titanium dioxide / bamboo charcoal composite environmentally friendly airgel; the airg...

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PUM

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Abstract

The invention discloses modified titanium dioxide / bamboo charcoal composite environment-friendly aerogel and a preparation method thereof. The modified titanium dioxide / bamboo charcoal composite environment-friendly aerogel comprises the following raw materials: 10mL of titanium ethoxide, 0.001g to 0.006g of a surface active agent, 1mL to 3mL of a 0.001mol / L to 0.006mol / L silver nitrate solution, glacial acetic acid and bamboo charcoal powder, the volume size of the silver nitrate solution to the glacial acetic acid is 1 to (0.01 to 0.04), and the mass of the bamboo charcoal powder is 0.01 to 0.20 percent of the mass of the titanium ethoxide. The preparation method comprises the steps: dissolving the titanium ethoxide into anhydrous ethanol, placing the surface active agent, and uniformly stirring to obtain a solution A; dissolving the silver nitrate solution in a mixed solution of the glacial acetic acid and water, and uniformly stirring to obtain a solution B; and gradually dropwise adding the solution B into the solution A, adding the bamboo charcoal powder, uniformly stirring, standing, aging, carrying out the washing, thermally treating a prepared product in a microwave oven, and then cooling the product to the room temperature to obtain the modified titanium dioxide / bamboo charcoal composite environment-friendly aerogel. The aerogel has advantages of no toxicity, large specific surface area, high porosity and highlight catalytic effect.

Description

technical field [0001] The invention relates to a modified titanium dioxide / bamboo charcoal composite environment-friendly airgel and a preparation method thereof, belonging to the technical field of environmental protection. Background technique [0002] Various building decoration materials in the living room, such as wood-based panels, wood composite floors, laminated wood furniture and adhesives, will emit toxic pollutants such as formaldehyde, halogenated hydrocarbons, and aromatic hydrocarbons, which are harmful to human health. [0003] Titanium dioxide is considered to be the most efficient and environmentally friendly photocatalyst widely used for the degradation of various pollutants. Titanium dioxide airgel is a porous three-dimensional network solid material formed by the aggregation of nanoparticles or polymer molecules. The size of its internal pores and basic constituent particles are all on the nanometer scale, and it is a mesoporous material with a high spec...

Claims

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Application Information

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IPC IPC(8): B01J21/18B01D53/86B01D53/72
Inventor 杨连威
Owner 秦皇岛杰康视电子科技有限公司
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