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Preparation method of metal protective coating for inner wall surface of inner bore part

A technology of surface metal and protective coating, applied in the direction of metal material coating process, coating, etc., can solve the problem that the small inner wall surface cannot be effectively clad, the coating falls off and fails, and the inner wall coating preparation of large-sized parts cannot be realized, etc. question

Inactive Publication Date: 2015-07-29
河北京津冀再制造产业技术研究有限公司 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Among them, due to the limitation of the coating deposition principle, the thermal spraying technology only forms a mechanical bond between the substrate and the coating, and there are a large number of pores, micro-cracks and other defects inside the coating, and the coating is prone to peeling off and failure under harsh working conditions. When the diameter of the inner wall is less than 80mm, effective spraying cannot be carried out due to the limitation of the pore structure; the cladding coating prepared by laser cladding technology can form a metallurgical bond with the substrate, and the coating has no pores inside, but due to the heat input during laser cladding Large amount, it is easily affected by thermal stress to form cracks inside the coating, and it is also limited by the size of the inner wall like thermal spraying technology, which cannot effectively clad the narrow and small inner wall surface; electroplating hard chrome technology is the current hydraulic cylinder and other inner wall parts The most commonly used coating preparation technology on the inner wall surface, hard chromium coating has good corrosion resistance and wear resistance, high coating quality, but hexavalent chromium is toxic, the coating preparation process has a large negative impact on the environment, and the coating deposition efficiency Low, the thickness of the coating is usually less than 0.1mm; vapor deposition technology can also prepare thin film coatings with excellent performance on the inner wall surface, but the coating thickness is usually in the range of several microns to tens of microns, and it cannot be realized due to the size of the deposition equipment cavity Coating preparation for inner walls of large-sized parts
In summary, the currently commonly used surface coating preparation technology is not suitable for the rapid preparation of high-performance thick coatings for inner wall parts that fail to wear or corrode under harsh working conditions, and cannot realize cylindrical narrow and long coatings with inner wall diameters less than 80 mm and lengths between 200 mm and 1000 mm. , Strengthening or repairing inner hole parts with small inner wall diameter

Method used

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  • Preparation method of metal protective coating for inner wall surface of inner bore part
  • Preparation method of metal protective coating for inner wall surface of inner bore part
  • Preparation method of metal protective coating for inner wall surface of inner bore part

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0134] This embodiment is used to illustrate the preparation method of the metal protective coating on the inner wall surface of the inner hole part of the present invention. Specifically, the steps of this embodiment are as follows:

[0135] (1) Using acetone as a cleaning agent, perform ultrasonic cleaning on the parts to be treated to clean the surface of the inner wall and remove surface pollutants such as oil stains. Ultrasonic cleaning power 10kW, cleaning time 30min.

[0136] (2) Mix rosin and turpentine in a mass ratio of 1:3, pour into a beaker and heat to 90°C, so that the rosin is completely dissolved in the turpentine solution to make a binder. Mix NiCrBSi and binder according to the mass ratio of 10:1 and stir evenly to make a paste. With the help of a scraper and a clamping rotary tool, evenly coat the prepared paste NiCrBSi / binder mixture on the surface of the inner wall of the part after step (1), with a thickness of about 0.5 mm.

[0137] (3) Put the parts p...

Embodiment 2

[0146] This embodiment is used to illustrate the preparation method of the metal protective coating on the inner wall surface of the inner hole part of the present invention. Specifically, the method of this embodiment is similar to the method of Example 1. The difference is that the induction is increased in this embodiment. Oscillating power output by heating power supply P s , the specific operating conditions are shown in Table 2.

[0147] Table 2

[0148]

[0149] The average thickness of the NiCrBSi coating obtained on the inner wall surface of the part by the above method is 0.39-0.41mm, the coating surface hardness is 720-740HV, the coating interface bonding strength is 90-95Mpa, and the coating porosity is 0.4-0.8%. The coating phase structure is close to the coating obtained by the method used in Example 1, except that the amount of hard precipitated phase increases; the microstructure of the coating is as follows: Figure 5 shown. From the results of this exam...

Embodiment 3

[0152]This embodiment is used to illustrate the preparation method of the metal protective coating on the inner wall surface of the inner hole part of the present invention. Specifically, the method of this embodiment is similar to the method of Example 2. The difference is that the part is adjusted higher in this embodiment. Horizontal movement speed v, the specific operating conditions are shown in Table 3.

[0153] table 3

[0154]

[0155] The average thickness of the NiCrBSi coating obtained on the inner wall surface of the part by the above method is 0.41-0.42mm, the coating surface hardness is 730-750HV, the coating interface bonding strength is 81-86Mpa, and the coating porosity is 0.6-0.9%. The coating phase structure is close to the coating obtained by the method used in Example 1; the microstructure of the coating interface region is as follows Figure 6 As shown, the internal microstructure of the coating section is as follows Figure 7 shown. It can be seen ...

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Abstract

The invention discloses a preparation method of a metal protective coating for the inner wall surface of an inner bore part and belongs to the technical field of surface engineering. The metal protective coating is mainly applied to perform protective treatment on the inner wall surface of a mechanical inner bore part. The preparation method comprises the following steps: the inner wall surface of the part is subjected to cleaning, presetting a powder / binder coating, drying, high-frequency induction heating cladding, cooling and the like, and then a high-frequency induction cladding coating is prepared on the inner wall surface. The metal protective coating is not only applicable to parts made of iron, cobalt and nickel, but also applicable to ti-based, aluminium-based, copper-based and other conductive inner bore metal parts. The metal protective coating prepared on the inner wall surface of the part has the following advantages: metallurgical bonding is formed between a matrix and the coating; a heat affected zone is narrow, and thermal damage and deformation are not caused for the matrix; a cladding coating and an interface texture are compact, a crystal grain is fine and small, and defects like holes, slag inclusion and cracks are avoided; different metals or alloy powder can be selected as coating materials for preparing a wearproof, antifriction or anticorrosion coating according to the actual working condition demands of the inner wall of the part.

Description

technical field [0001] The invention designs a method for preparing a metal protective coating on the inner wall surface of inner hole parts, which belongs to the field of surface engineering technology. The invention is mainly used for protective treatment of the inner wall surface of mechanical parts, and can be used for strengthening new parts and also for waste parts. repair and remanufacturing. Background technique [0002] Inner hole parts have a large quantity and a wide range. For example, hydraulic cylinders, friction couplers, oil and gas pipelines and other parts are widely used in industry. Due to wear or corrosion conditions, in the process of strengthening the inner wall surface of new inner hole parts, or repairing and remanufacturing the inner wall of failed parts, the preparation technology of inner wall surface coating of parts is the key to improving and restoring the quality and performance of parts. The essential. At present, the commonly used inner wa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C23C24/10
Inventor 张伟于鹤龙汪勇宋占永张梦清张攀
Owner 河北京津冀再制造产业技术研究有限公司
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