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A kind of nano-micro ZnO/composite cellulose strip material and preparation method thereof

A technology of composite cellulose, cellulose fiber, applied in chemical instruments and methods, nanotechnology for materials and surface science, organic compound/hydride/coordination complex catalyst, etc., can solve the high temperature of nano-ZnO , environmental pollution, unfavorable spinning into fiber or film forming process, etc., to achieve the effect of reducing the temperature of hydrothermal synthesis, cleaning and environmental protection of the preparation process, and promoting the formation of

Active Publication Date: 2017-03-01
NANJING FORESTRY UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] The above two types of methods have the following disadvantages: the first type of method uses fibers or films as carriers, and the zinc source is not easy to penetrate into the carrier; and the shape of the final product is fibers or films, while the shape of industrial catalysts is generally granular or strip
The second type of method requires the selection of solvents for cellulose or cellulose derivatives, which causes environmental pollution; nano-ZnO particles are not easily dispersed in cellulose or cellulose derivative solutions, and cause adverse effects on spinning into fibers or film-forming processes. Influence; the preparation of nano-ZnO alone generally requires a higher temperature

Method used

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  • A kind of nano-micro ZnO/composite cellulose strip material and preparation method thereof
  • A kind of nano-micro ZnO/composite cellulose strip material and preparation method thereof
  • A kind of nano-micro ZnO/composite cellulose strip material and preparation method thereof

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Effect test

Embodiment 1

[0036] Add 1 g of wood pulp cellulose fibers to 65% (wt%) ZnCl 2 In the aqueous solution, pretreat for 4 hours in a constant temperature bath at 60°C. Use a syringe to moisten and partially dissolve the cellulose ZnCl 2 The aqueous solution was slowly injected into a 30% NaOH aqueous solution, and the precipitation time was 0.5h. When the pH value of the system was adjusted to 9, it was left to stand for 24 hours to obtain a strip-shaped ZnO precursor / cellulose. The strip-shaped ZnO precursor / cellulose was put into a hydrothermal synthesis kettle, and the hydrothermal reaction was carried out under the conditions of pH 9 and temperature 120°C, and the reaction time was 6h. Wash the strips of ZnO / cellulose to be free of Cl - Finally, put it in an ultra-low temperature refrigerator. After freezing, place the sample in a freeze dryer. After drying, a new strip-shaped nano-ZnO / cellulose fiber material is obtained.

[0037] At the same time, ZnO particles were prepared by the sa...

Embodiment 2

[0041] Add 1 g of cotton pulp cellulose fiber to 65% (wt%) ZnCl 2 In the aqueous solution, it was pretreated in a constant temperature bath at 40°C for 12h. Use a syringe to moisten and partially dissolve the cellulose ZnCl 2 The aqueous solution was slowly injected into a 20% NaOH aqueous solution, and the precipitation time was 3 hours. When the pH value of the system was adjusted to 7, it was left to stand for 36 hours to obtain a strip-shaped ZnO precursor / cellulose. The strip ZnO precursor / cellulose was put into a hydrothermal synthesis kettle, and the hydrothermal reaction was carried out under the conditions of pH 7 and temperature 170°C, and the reaction time was 4h. Wash the strips of ZnO / cellulose to be free of Cl - Finally, put it in an ultra-low temperature refrigerator. After freezing, place the sample in a freeze dryer. After drying, a new strip-shaped nano-ZnO / cellulose fiber material is obtained.

[0042] Depend on Figure 8 It can be seen that the strip Zn...

Embodiment 3

[0045] Add 1 g of bamboo pulp cellulose fibers to 65% (wt%) ZnCl 2 In aqueous solution, pretreatment in a constant temperature bath at 70°C for 2h. Use a syringe to moisten and partially dissolve the cellulose ZnCl 2 The aqueous solution was slowly injected into a 15% NaOH aqueous solution, and the precipitation time was 5 hours. When the pH value of the system was adjusted to 10, it was left to stand for 48 hours to obtain a strip-shaped ZnO precursor / cellulose. The strip-shaped ZnO precursor / cellulose was put into a hydrothermal synthesis kettle, and the hydrothermal reaction was carried out under the conditions of pH 10 and temperature 100° C., and the reaction time was 10 h. Wash the strips of ZnO / cellulose to be free of Cl - Finally, put it in an ultra-low temperature refrigerator. After freezing, place the sample in a freeze dryer. After drying, a new strip-shaped nano-ZnO / cellulose fiber material is obtained.

[0046] Depend on Figure 11 It can be seen that the str...

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Abstract

The invention discloses a method for preparing nano-micro ZnO / composite cellulose strip materials. ZnCl2 aqueous solution is used as the swelling agent and solvent of cellulose and the zinc source of nano-ZnO, and the cellulose fiber of the dissolved pulp is used as the cellulose raw material. Swelling and partial dissolution, injection co-precipitation, hydrothermal synthesis and freeze-drying prepared nano-micro ZnO / cellulose strips supported by raw cellulose fibers and regenerated cellulose fibers. Since the present invention uses the ZnCl2 aqueous solution as the swelling agent and solvent of the cellulose and the zinc source of the nano-ZnO, there is no need to add other cellulose solvents, and the preparation process is clean and environment-friendly. In addition, after the cellulose is swelled and partially dissolved, the hydroxyl groups on its molecules combine with zinc ions, which promotes the formation of nano-ZnO, and the hydrothermal synthesis temperature is also significantly reduced accordingly. Therefore, the preparation process has the advantage of energy saving.

Description

technical field [0001] The invention relates to a cellulose composite material, in particular to a nano-micro ZnO / composite cellulose strip material and a preparation method thereof. Background technique [0002] Since Iijima's discovery of carbon nanotubes, nanomaterials have attracted great interest because of their many special chemical properties. ZnO is a typical wide-bandgap semiconductor material with excellent performance. Due to the quantum size and small size effect, nano-ZnO exhibits special properties and is widely used in photocatalysis, photoelectric conversion, and gas sensors. The preparation methods of ZnO nanomaterials mainly include vapor phase deposition method, template method, microemulsion method, sol-gel method, hydrothermal synthesis method, etc. The shapes of the prepared products include nanoparticles, nanorods, nanowires, nanoarrays and nanofilm, etc. Due to the small particle size and high surface energy of nano-ZnO, it is easy to agglomerate, ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J31/06B01J31/26B82Y30/00
Inventor 李小保柏茜茜张雪李力成叶菊娣洪建国李宇欣
Owner NANJING FORESTRY UNIV
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