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A kind of bleaching process of bamboo dissolving pulp

A dissolving pulp and process technology, applied in pulp bleaching, washing/replacing pulp treatment liquid, papermaking, etc., can solve the problems of difficult treatment, low production capacity, poor water filtration performance, etc., to simplify the production process, reduce production costs, and save cost effect

Active Publication Date: 2017-10-17
CHONGQING LEE & MAN PAPER MFG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, in the process of paper pulping, the production equipment and technology of bamboo dissolving pulp are relatively backward
In the prior art, the bleaching process of bamboo dissolving pulp mainly adopts the traditional chlorine-containing C~E~H (C~chlorine gas, E~alkali extraction, H~hypochlorite) three-stage bleaching process. The process has the following defects: 1) The three-stage bleaching process consumes a large amount of bleaching agents (mainly chlorine dioxide, hydrogen peroxide and other chemical reagents), which not only makes the raw material cost of the bleaching agent high, but also produces a large amount of wastewater pollution. The cost increases accordingly, resulting in high production cost and low production capacity of pulping; 2) In the wastewater using a large amount of bleaching agents, especially chlorine and hypochlorite will produce such as chloroform, dioxin, etc. during the bleaching process There are more than 40 kinds of organic chlorides (AOX). These toxic substances are not only carcinogenic, teratogenic, highly toxic and difficult to handle, but also pose a serious threat to the ecological environment and human health; 3) The water filtration performance of the slurry is poor, resulting in The water content of the pulp sheet is relatively high, which cannot meet the requirements; 4) The traditional three-stage bleaching still cannot meet the demand for products with high whiteness requirements, and it is prone to yellowing; 5) In order to improve the purity of the pulp, the traditional process uses The cellulose degradation in the pulp usually requires a pre-hydrolysis process before bleaching, resulting in complex processes, high energy consumption, and low cellulose degradation rate, resulting in low purity of the final pulp

Method used

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  • A kind of bleaching process of bamboo dissolving pulp

Examples

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Effect test

Embodiment 1

[0047] A kind of bleaching process of bamboo dissolving pulp of the present invention, as figure 1 shown, including the following processing steps:

[0048] a. Two-stage delignification bleaching:

[0049] a1) One stage delignification bleaching:

[0050] Add 1.2% caustic soda and 1kg / admt magnesium sulfate to the pulp washed and concentrated by the pulp washer, heat it to 90°C with low-pressure steam, and send it to the medium-concentration mixer in the first stage. Add 20kg / admt oxygen into the medium-concentration mixer and mix evenly before entering the up / down flow reaction tube. The residence time of the slurry in the up / down flow reaction tube is 6 minutes;

[0051] a2) Two-stage delignification bleaching:

[0052] The slurry from the first downflow tower is heated to 95°C by medium-pressure steam, then sent to the second-stage medium-concentration mixer, and 20kg / admt oxygen is added to the second-stage medium-concentration mixer to mix evenly, and sent to Stay in th...

Embodiment 2

[0073] A kind of bleaching process of bamboo dissolving pulp of the present invention, as figure 1 shown, including the following processing steps:

[0074] a. Two-stage delignification bleaching:

[0075] a1) One stage delignification bleaching:

[0076] Add 2.5% caustic soda and 2kg / admt magnesium sulfate to the pulp washed and concentrated by the washing machine, heat it to 93°C with low-pressure steam, and then send it to the medium-concentration mixer in the first stage. Add 22kg / admt oxygen into the medium-concentration mixer and mix evenly before entering the up / down flow reaction tube. The residence time of the slurry in the up / down flow reaction tube is 7 minutes;

[0077] a2) Two-stage delignification bleaching:

[0078] The slurry from the first downflow tower is heated to 98°C by medium-pressure steam, then sent to the second-stage medium-concentration mixer, and 22kg / admt oxygen is added to the second-stage medium-concentration mixer to mix evenly, and sent to ...

Embodiment 3

[0099] A kind of bleaching process of bamboo dissolving pulp of the present invention, as figure 1 shown, including the following processing steps:

[0100] a. Two-stage delignification bleaching:

[0101] a1) One stage delignification bleaching:

[0102] Add 3.0% caustic soda and 3kg / admt magnesium sulfate to the pulp washed and concentrated by the pulp washer, heat it to 95°C with low-pressure steam, and send it to the medium-concentration mixer in the first stage. Add 25kg / admt oxygen into the medium-concentration mixer and mix evenly before entering the up / down flow reaction tube. The residence time of the slurry in the up / down flow reaction tube is 10 minutes;

[0103] a2) Two-stage delignification bleaching:

[0104] The slurry from the first downflow tower is heated to 100°C by medium-pressure steam, and then sent to the second-stage medium-concentration mixer, and 25kg / admt oxygen is added to the second-stage medium-concentration mixer to mix evenly, and sent to St...

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Abstract

The invention relates to the technical field of paper-making pulping and particularly relates to a bleaching process of bamboo dissoluble pulp. The process comprises the processing steps: two-section delignification bleaching, first-time washing, chlorine dioxide bleaching under strong acid condition, addition of a bleaching accelerant, extraction by hydrogen peroxide, oxygen and intensified alkaline, third-time washing, chlorine dioxide bleaching, fourth-time washing and enzyme treatment. Compared with the prior art, the bleaching process has the advantages that through pentosan treatment, the fiber hydrolysis degree of pulp and the whiteness of a pulp board can be greatly improved, the using amount of bleaching agents such as chlorine dioxide and hydrogen peroxide can be reduced, the production process is greatly simplified, and the saving of the cost is facilitated.

Description

technical field [0001] The invention relates to the technical field of papermaking and pulping, in particular to a bleaching process of bamboo dissolving pulp. Background technique [0002] Dissolving pulp is widely used in textile viscose fiber, nitrocellulose, cellulose acetate and other cellulose derivative industries, and the market demand is huge. At present, the newly developed bamboo dissolving pulp has a broad market prospect and can fill the gap of dissolving pulp in my country. However, in the process of paper pulping, the production equipment and technology of bamboo dissolving pulp are relatively backward. In the prior art, the bleaching process of bamboo dissolving pulp mainly adopts the traditional chlorine-containing C~E~H (C~chlorine gas, E~alkali extraction, H~hypochlorite) three-stage bleaching process. The process has the following defects: 1) The three-stage bleaching process consumes a large amount of bleaching agents (mainly chlorine dioxide, hydrogen...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): D21C9/10D21C9/147D21C9/14D21C9/16
CPCD21C5/005D21C9/02D21C9/1057D21C9/142D21C9/147D21C9/16
Inventor 李文俊
Owner CHONGQING LEE & MAN PAPER MFG