Technique for treating fermentation wastewater by microbial fuel cell

A fuel cell, fermentation wastewater technology, applied in biochemical fuel cells, biological water/sewage treatment, chemical instruments and methods, etc., can solve the problems of lack of active groups, accelerated microbial attachment, hindered conductive microbial attachment and film formation, etc.

Inactive Publication Date: 2015-12-09
SHENYANG INSTITUTE OF CHEMICAL TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Studies have shown that the surface of existing anode materials usually lacks active groups and is relatively hydrophobic, which greatly hinders the attachment and film formation of conductive microorganisms. However, the surface of the material can be activated by alkaline hydrolysis and acid hydrolysis, which can be greatly improved. The hydrophilic property of the material, thus accelerating the attachment of microorganisms

Method used

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  • Technique for treating fermentation wastewater by microbial fuel cell
  • Technique for treating fermentation wastewater by microbial fuel cell
  • Technique for treating fermentation wastewater by microbial fuel cell

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] 1) Use a blank conductive glass with a length of 5cm and a width of 4cm as the cathode and anode.

[0043] 2) The composition of anolyte for microbial fuel cell treatment of fermented wastewater: 10g of pond sludge, 200ml of fermented wastewater, 300ml of microbial acclimation solution (every 500ml of anolyte) in a constant temperature incubator at 37 o C cultured for 3 days. Catholyte composition: 50mM potassium ferricyanide dissolved in 1000ml water.

[0044] 3) Assembly of the microbial fuel cell: the external resistance is 1000 ohms, and the UT803 data acquisition card is used, and the electrochemical activity measurement of the anode biofilm of the microbial fuel cell is measured by an electrochemical workstation.

[0045] 4) Use conductivity to test the conductivity and total solids of the cathode and anode substrates before the assembly of the microbial fuel cell and after electricity generation, and test the pH value of the cathode and anode before the assembly...

Embodiment 2

[0048] 1) The multilayer film-modified conductive glass with a length of 5cm and a width of 4cm (guaranteed length > width) is used as the anode, and a blank conductive glass is used as the cathode.

[0049] 2) The composition of anolyte for microbial fuel cell treatment of fermented wastewater: 10g of pond sludge, 200ml of fermented wastewater, 300ml of microbial acclimation solution (every 500ml of anolyte) in a constant temperature incubator at 37 o C cultured for 3 days. Catholyte composition: 50mM potassium ferricyanide dissolved in 1000ml water.

[0050] 3) Assembly of the microbial fuel cell: the external resistance is 1000 ohms, and the UT803 data acquisition card is used, and the electrochemical activity measurement of the anode biofilm of the microbial fuel cell is measured by an electrochemical workstation.

[0051] 4) Use conductivity to test the conductivity and total solids of the cathode and anode substrates before the assembly of the microbial fuel cell and af...

Embodiment 3

[0054] 1) Use a blank carbon cloth with a length of 5cm and a width of 4cm (guaranteed length > width) as the cathode and anode.

[0055] 2) The composition of anolyte for microbial fuel cell treatment of fermented wastewater: 10g of pond sludge, 200ml of fermented wastewater, 300ml of microbial acclimation solution (every 500ml of anolyte) in a constant temperature incubator at 37 o C cultured for 3 days. Catholyte composition: 50mM potassium ferricyanide dissolved in 1000ml water.

[0056] 3) Assembly of the microbial fuel cell: the external resistance is 1000 ohms, the MPS-010602 data acquisition card is used, and the electrochemical activity of the anode biofilm of the microbial fuel cell is measured by an electrochemical workstation.

[0057] 4) Use conductivity to test the conductivity and total solids of the cathode and anode substrates before the assembly of the microbial fuel cell and after electricity generation, and test the pH value of the cathode and anode before...

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Abstract

The invention discloses a technique for treating fermentation wastewater by a microbial fuel cell, and relates to a technique for treating wastewater. The method comprises the steps as follows: with conductive glass, carbon cloth or a carbon felt as electrode materials, active groups, polyelectrolyte multilayer films or nanoparticles/polyelectrolyte multilayer films are respectively modified on the electrode materials by an alkaline hydrolysis method, an acid hydrolysis method and a layer-by-layer self-assembly technique; the series materials are applied to an anode of a microbial fuel cell reaction device to treat the fermentation wastewater; with sodium acetate and lotus pond sludge as substrates, a microbial fuel cell system with a relatively high electricity generating rate, relatively good chemical oxygen demand (COD) removal effects and relatively high coulombic efficiency is obtained. The microbial fuel cell system is good in process repeatability, safe and reliable; the fermentation wastewater is treated; meanwhile, a relatively high electricity generating quantity and a relatively high electricity generating rate are achieved; the problems that the traditional microbial fuel cell is low in electricity generating efficiency and low in sewage COD removal rate are effectively solved; and the technique has a good industrial application prospect.

Description

technical field [0001] The invention relates to a process for treating waste water, in particular to a process method for treating fermentation waste water with a microbial fuel cell. Surface activation and modification of anode materials for microbial fuel cells, and construction of microbial fuel cell treatment of fermented sewage systems. In particular, it involves the activation of conductive glass by alkaline hydrolysis, the activation of carbon cloth or carbon felt by acid hydrolysis, the modification of conductive glass, carbon cloth, and carbon felt anode layer by layer self-assembled multi-layer film, and the treatment of sewage sludge generated from lotus pond sludge, microbial domestication liquid, and fermented sewage. Anode substrate system, and process design of microbial fuel cell treatment of fermentation wastewater. Background technique [0002] Microbial fuel cell (MFC) is a device that uses microorganisms as an anode catalyst to directly convert the chemi...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M8/16C02F3/34
CPCC02F3/34H01M8/16Y02E60/50Y02P70/50
Inventor 王美聪樊立萍杨珍珍夏木村
Owner SHENYANG INSTITUTE OF CHEMICAL TECHNOLOGY
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