Method for preparing environmentally-friendly polyester fibers through dope dyeing

A dope dyeing, environmentally friendly polyester technology, applied in the chemical characteristics of fibers, single-component polyester rayon, rayon manufacturing and other directions, can solve the problems of high energy consumption, high cost, large product batch difference, etc. The effect of uniform color, short residence time and high color fastness

Active Publication Date: 2015-12-30
SHANGHAI DEFULUN CHEM FIBER
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Invention patent Chinese invention patent CN103255498A (the patent number is CN201310147346.X, the invention name is "a method for preparing colored polyester fiber by dope coloring") has been improved by adding liquid color paste on-line and polyester melt direct spinning The combination of technology solves the problems of high temperature, high pressure or loaded dyeing method, which cause the colored sewage to be treated with difficulty, high cost, and direct discharge will cause serious environmental pollution. Intermittent methods such as raw material chip blending spinning method, color masterbatch and raw material chip blending spinning method cause high energy consumption, high unit consumption, and large product batch differences. However, the preparation of the dyeing system requires the polyester carrier adipic acid The mixture with 1,3-butanediol is reacted under nitrogen protection, temperature rise, and heat preservation until the acid value is 10, and then distilled under reduced pressure at 6.67-8.00kPa for 1 hour. The industrial implementation is relatively cumbersome

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Embodiment 1: the preparation of liquid color paste A

[0036] Liquid color paste consists of the following components by weight percentage:

[0037] Environmentally friendly dyes: diaminostilbene disulfonic acid dyes direct light fast green IRC, 20

[0038] Solvent: N,N-dimethylformamide, 60

[0039] Dispersant: PluronicP123, molecular formula EO20PO70EO20, 10

[0040] Wetting agent: sodium salt of isopropyl naphthalene sulfonate, 10

[0041] The above environmental dyes, solvents, dispersants and wetting agents can be purchased.

[0042] The preparation method of the liquid color paste is: adding the dispersant PluronicP123 and the wetting agent sodium salt of isopropyl naphthalene sulfonate into the solvent, stirring to dissolve it, and then adding diaminostilbene disulfonic acid dyes to directly light-fast green IRC, stir evenly, fully grind it into a slurry, and get a liquid color paste after it is evenly dispersed.

Embodiment 2

[0043] Embodiment 2: the preparation of liquid color paste B

[0044] Liquid color paste consists of the following components by weight percentage:

[0045] Eco-friendly dye: Eco-friendly acid dye C.I. Acid Red 37, 30

[0046] Solvent: N,N-dimethylformamide, 55

[0047] Dispersant: PluronicF68, the molecular formula is EO80PO30EO80, 8

[0048] Wetting agent: sodium salt of isobutylnaphthalene sulfonate, 7

[0049] The above environmental dyes, solvents, dispersants and wetting agents can be purchased.

[0050] The preparation method of the liquid color paste is: add the dispersant PluronicF68 and the wetting agent sodium isobutylnaphthalene sulfonate into the solvent, stir to dissolve, then add the environment-friendly acid dye C.I. Acid Red 37, stir evenly, and grind thoroughly It is in the form of a slurry, and after it is dispersed evenly, a liquid color paste is obtained.

Embodiment 3

[0051] Embodiment 3: the preparation of liquid color paste C

[0052] Liquid color paste consists of the following components by weight percentage:

[0053] Environmentally friendly dyes: environmentally friendly disperse dyes ForonBlueRD-SE290, 25

[0054] Solvent: N,N-dimethylformamide, 45

[0055] Dispersant: Pluronic F127, molecular formula EO106PO70EO106, 15

[0056] Wetting agent: Sodium amylnaphthalene sulfonate, 15

[0057] The above environmental dyes, solvents, dispersants and wetting agents can be purchased.

[0058] The preparation method of the liquid color paste is: add the dispersant PluronicF127 and the wetting agent sodium amylnaphthalene sulfonate into the solvent, stir to dissolve it, then add the environment-friendly disperse dye ForonBlueRD-SE290, stir evenly, and fully grind it into It is in the form of a paste, and after it is dispersed evenly, a liquid color paste can be obtained.

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Abstract

The invention belongs to the technical field of preparation of polyester fibers, and concretely relates to a method for preparing environmentally-friendly polyester fibers through dope dyeing. The method for preparing environmentally-friendly polyester fibers through stock solution coloring comprises the following steps: blending an environmentally friendly dye with a solvent, a dispersant and a wetting agent to prepare a dope dyeing liquid color paste; injecting one or two or more liquid color pastes to a polyester melt pipeline through a metering injection pump; and uniformly mixing polyester melt and the liquid color paste(s) through a static mixing device, conveying the obtained mixture into a spinning box body, and spinning. Dope dyed fibers are prepared in the invention without a high pressure or a high temperature, and a dyeing system with the advantages of high temperature resistance, excellent color fastness, intermiscibility with polyester melt, realization of stable dispersion, environmental protection and simple operation is constructed.

Description

technical field [0001] The invention belongs to the technical field of polyester fiber preparation, and in particular relates to a method for preparing environmentally friendly polyester fiber by dope coloring. Background technique [0002] Dope-dyed polyester fibers are fibers that are dyed on polyester melt and then spun. Compared with conventional dyeing methods, dope-dyed fibers do not need to be dyed in subsequent processes, which reduces the production cost of fiber dyed yarns and reduces It reduces the consumption of water and energy, and has obvious advantages in energy saving and emission reduction. At the same time, the colored fiber produced by the dope coloring technology has uniform color and high color fastness. . [0003] At present, the stock solution coloring technology also has some defects in the actual production process, such as difficult color adjustment, difficult to determine the color scheme, and not suitable for small batch production. Therefore, ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/92D01F1/06D01F1/10
Inventor 陈辉华刘萍陆育明李东华沈飞王水兵杨卫忠冯忠耀
Owner SHANGHAI DEFULUN CHEM FIBER
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