Copper-nickel-tin alloy bar and manufacturing method thereof

A technology of alloy rods and copper-nickel-tin, which is applied in the field of material processing, can solve problems such as insufficient mechanical properties and Sn segregation, and achieve the effects of excellent mechanical properties, wear resistance and corrosion resistance of alloys, increased strength, and inhibition of discontinuous precipitation

Active Publication Date: 2016-01-20
CENT SOUTH UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The technical problem to be solved by the present invention is to overcome the deficiencies and defects mentioned in the above background technology, solve or avoid the serious problem of Sn segregation in the production of ingots by smelting and casting methods and the obvious lack of mechanical properties caused by discontinuous precipitation in the alloy aging process problem, provide a copper-nickel-tin alloy bar and its preparation method

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A kind of preparation method of copper-nickel-tin alloy rod is as follows:

[0033] The alloy composition and mass percentage of the copper-nickel-tin alloy bar are: nickel 15.0%, tin 8.0%, yttrium 0.2%, aluminum 0.8%, niobium 0.25%, and the balance is copper and other impurities.

[0034] (1) Preparation of alloy powder: The raw materials with the above mass ratio are prepared into alloy powder (oxygen content is 240ppm, particle size is -100 mesh) by gas atomization method, and the alloy powder is put into a plastic bag and vacuum-sealed for later use;

[0035] (2) Cold isostatic pressing: put the alloy powder obtained after step (1) into the latex mold and put it on the vibrator to vibrate while filling the alloy powder. After the alloy powder is filled, it is tightly sealed, and then the pressure is 280MPa. Cold isostatic pressing is carried out compression molding 15min, obtains green body;

[0036] (3) Vacuum sintering: Put the green body obtained after step (2) ...

Embodiment 2

[0043] A kind of preparation method of copper-nickel-tin alloy rod is as follows:

[0044] The alloy composition and mass percentage of the copper-nickel-tin alloy bar are: nickel 15.0%, tin 8.0%, yttrium 0.3%, aluminum 0.8%, niobium 0.50%, and the balance is copper and other impurities.

[0045] (1) Preparation of alloy powder: Prepare the raw materials with the above mass ratio into alloy powder (oxygen content of 255ppm, particle size of -100 mesh) by gas atomization method, put the alloy powder into a plastic bag and vacuum seal it for later use;

[0046](2) Cold isostatic pressing: put the alloy powder obtained after step (1) into the latex mold and put it on the vibrator to vibrate while filling the alloy powder. After the alloy powder is filled, it is tightly sealed, and then the pressure is 300MPa. Cold isostatic pressing is carried out compression molding 15min, obtains green body;

[0047] (3) Vacuum sintering: Put the green body obtained after step (2) into a vacuu...

Embodiment 3

[0054] A kind of preparation method of copper-nickel-tin alloy rod is as follows:

[0055] The alloy composition and mass percentage of the copper-nickel-tin alloy rod are: nickel 15.0%, tin 8.0%, yttrium 0.3%, aluminum 0.6%, niobium 0.75%, and the balance is copper and other impurities.

[0056] (1) Preparation of alloy powder: The raw materials with the above mass ratio are prepared into alloy powder (oxygen content is 260ppm, particle size is -100 mesh) by gas atomization method, and the alloy powder is put into a plastic bag and vacuum-sealed for later use;

[0057] (2) Cold isostatic pressing: put the alloy powder obtained after step (1) into the latex mold and put it on the vibrator to vibrate while filling the alloy powder. After the alloy powder is filled, it is tightly sealed, and then the pressure is 280MPa. Cold isostatic pressing is carried out compression molding 15min, obtains green body;

[0058] (3) Vacuum sintering: Put the green body obtained after step (2) ...

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Abstract

The invention discloses a copper-nickel-tin alloy bar. The copper-nickel-tin alloy bar comprises, by mass, 14%-16% of nickel, 7%-9% of tin, 0.05%-0.3% of yttrium, 0.8%-1.0% of aluminum, 0.2%-1.0% of niobium, and the balance copper and other impurities. The invention further discloses a manufacturing method of the copper-nickel-tin alloy bar. The method comprises the steps that alloy powder is prepared according to the ingredients and the mass percentages through a gas atomization method, then an alloy ingot blank is prepared through the methods of cold isostatic pressing molding, vacuum sintering and ingot blank covering, and finally the high-quality copper-nickel-tin alloy bar is obtained through the processes of water-sealing hot extrusion, cold rotary swaging, aging treatment and the like. By means of the method, the problems of composition segregation and the like generated in the casting process of a copper-nickel-tin alloy can be avoided, and the yield is high; the copper-nickel-tin alloy bar can have high strength, high toughness and excellent abrasion and corrosion resistance at the same time, and the overall performance is higher than that of beryllium bronze. The copper-nickel-tin alloy bar can be widely applied to manufacturing of bearings, shaft sleeves, bearing bushes and other wear-resisting components which are used in high-load, high-speed and high-corrosion environments like space flight and aviation and oil drilling platforms.

Description

technical field [0001] The invention belongs to the field of material processing, and in particular relates to a copper-nickel-tin alloy rod and a preparation method thereof. Background technique [0002] Copper-nickel-tin alloy (such as Cu-15Ni-8Sn and Cu-9Ni-6Sn) is a high-end copper alloy material with high strength and excellent wear resistance and corrosion resistance, especially the strength of Cu-15Ni-8Sn alloy The maximum can reach more than 1100MPa, which is equivalent to high-strength steel and beryllium copper. The corrosion resistance in seawater or acidic, oil and gas environments, and the wear resistance under high load conditions are better than beryllium copper and aluminum bronze. [0003] The Cu-Ni-Sn alloy belongs to the aging amplitude modulation decomposition (Spinodal) strengthened copper alloy. Through solid solution treatment, Ni and Sn are solid-dissolved into the α phase of Cu to obtain an unstable supersaturated solid solution. After aging treatmen...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C9/06B22F3/04B22F3/10C22F1/08
Inventor 甘雪萍姜业欣周科朝张县委李志友欧阳亦
Owner CENT SOUTH UNIV
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