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A method for removing cadmium from whole grain rice

A rice and solution technology, which is applied in food ultrasonic treatment, food science, etc., can solve the problems of not considering environmental pollution, reducing the efficiency of cadmium removal in the final product, negative effects, etc., and achieves the effect of easy implementation, low cost and high efficiency

Active Publication Date: 2019-03-15
JIANGNAN UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The invention patent of CN201310140019.1 discloses a decadmium-removed rice protein and its preparation method and application. The main steps are to use rice as raw material, remove the starch with high-temperature amylase to obtain rice dregs, and then use acid solution for decadmium treatment , the acid used is one of food-grade acetic acid, citric acid, malic acid, lactic acid, tartaric acid, oxalic acid, phosphoric acid, and the addition amount is that rice dregs and acid solution are mixed in a weight ratio of 1:2-5. In this step, the acid It only plays the role of adjusting the pH value; the acid solution with a large amount of acid and pH<4 has a negative effect on the quality of the protein; the rice protein obtained by centrifugation is directly washed with water, because the pH value increases, the cadmium dissolved in the solution The ions are recombined with rice protein, which reduces the efficiency of cadmium removal in the final product; and the supernatant and washing liquid also contain more acid solution, which is not considered in the invention patent that its discharge will pollute the environment

Method used

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  • A method for removing cadmium from whole grain rice
  • A method for removing cadmium from whole grain rice
  • A method for removing cadmium from whole grain rice

Examples

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Effect test

Embodiment 1

[0033] A method for removing cadmium from whole-grain rice, comprising the steps of:

[0034] (1) Impurity removal: use air separation, magnetic separation, and screening devices to remove gravel and rice husk impurities contained in rice raw materials (cadmium content is 0.65ppm);

[0035] (2) Rice filling and dissolution of metal cadmium: put the impurity-removed rice into a countercurrent elution column, and soak the rice in an aqueous solution containing a complex acid complexing agent and a complex salt for 30 minutes. At the same time, set the ultrasonic power to 12kw and the ultrasonic temperature to 25°C;

[0036] (3) Separation: adopt the continuous countercurrent washing method, set the five-stage countercurrent elution column, by controlling the flow velocity of the eluting water to be 2mm / s, and monitoring the pH value of the eluting water at the same time to be 6, it will be processed through step (2) The solution containing cadmium in the countercurrent elution ...

Embodiment 2

[0046] A method for removing cadmium from whole-grain rice, comprising the steps of:

[0047] (1) Impurity removal: adopt air separation, magnetic separation, and screening devices to remove gravel and rice husk impurities contained in rice raw materials (cadmium content is 1.8ppm);

[0048] (2) Rice filling and dissolution of metal cadmium: put the impurity-removed rice into a countercurrent elution column, and soak the rice in an aqueous solution containing a complex acid complexing agent and a complex salt for 40 minutes. At the same time, set the ultrasonic power to 14kw and the ultrasonic temperature to 30°C;

[0049] (3) Separation: adopt continuous countercurrent washing method, set three-stage countercurrent elution column, be 2.5mm / s by controlling the flow rate of eluting water, monitor the pH value of eluting water simultaneously to be 5.5, will go through step (2) The cadmium-containing solution is separated from the rice in the treated countercurrent elution colu...

Embodiment 3

[0059] A method for removing cadmium from whole-grain rice, comprising the steps of:

[0060] (1) Impurity removal: use air separation, magnetic separation, and screening devices to remove gravel and rice husk impurities contained in rice raw materials (cadmium content is 1.2ppm);

[0061] (2) Rice filling and dissolution of metal cadmium: put the impurity-removed rice into a countercurrent elution column, and soak the rice in an aqueous solution containing a complex acid complexing agent and a complex salt for 20 minutes. It is advisable to set the ultrasonic power to 10kw and the ultrasonic temperature to 30°C at the same time;

[0062] (3) Separation: adopt the continuous countercurrent washing method, set the three-stage countercurrent elution column, by controlling the flow rate of the eluting water to be 3mm / s, and monitor the pH value of the eluting water to be 6 at the same time, it will be processed by step (2) The solution containing cadmium in the countercurrent el...

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Abstract

The invention discloses a method for removing cadmium in whole rice. The method comprises the following steps: (1) removing impunity, (2) rick filling and cadmium dissolving, (3) separation, (4) neutralization, desalting, leaching and (5) drying, so as to obtain the cadmium-removed whole rice. In the method, cadmium complex is isolated from the rice through cooperation of a physical method and a chemical method, cadmium complex solution is separated in a gradient way step by step by a multi-level back flow separation method, and the content of cadmium in the rice is effectively reduced under the conditions that the appearance of the rice is kept complete and the nature difference is slight. Moreover, the method for removing cadmium in whole rice is simple in operation and low in cost, is suitable for large-scale industrial production and is worthy to be popularized and applied.

Description

technical field [0001] The invention belongs to the technical field of grain deep processing, and in particular relates to a method for removing heavy metal cadmium in whole-grain rice. Background technique [0002] China is the world's largest rice producer, with a rice output of 189 million tons in 2008, and rice is my country's largest food crop. However, the quality of soil in various places is directly related to the quality of edible rice. However, the adsorption effect of rice on heavy metal pollution is obviously stronger than that of other crops such as corn and soybean. Therefore, the rice is processed through deep processing to obtain high-quality products while removing heavy metals, which also increases the added value of rice utilization. [0003] Heavy metals in rice are mainly combined with amino acids in a chelated state. It is reported that heavy metals in plants are mainly combined with ligands formed by metallothionein, and some are combined with ligands...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): A23L5/20A23L5/30
CPCA23V2002/00A23V2300/48
Inventor 李珍妮于秋生陈正行王莉王韧冯伟
Owner JIANGNAN UNIV
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