Reaction-activity-controllable acrylate emulsion and preparation method thereof

An acrylate and reactive technology, which is applied in the coating and other directions, can solve the problems of poor water whitening resistance, poor viscosity storage stability, and poor storage stability of coatings, so as to ensure water whitening resistance, improve hydrophilic performance, and improve water resistance. staining effect

Active Publication Date: 2016-03-23
佛山市顺德区巴德富实业有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] Silicone acrylic emulsion and pure acrylic emulsion have strong reactivity, so their activity is not controlled by other conditions in the chemical reaction system, so both of them have the defect of poor viscosity storage stability
This defect makes the storage stability of the coating worse, and causes the viscosity of the coating itself to be extremely unstable during storage or film formation
At the same time, due to the uncontrolled reactivity of the silicone acrylic emulsion and pure acrylic emulsion in the entire reaction system, the process of the chemical reaction becomes disordered. When the above two emulsions are added to the liquid granite coating, the coating is emulsified into a chain reaction to complete The final permeability becomes extremely poor, seriously affecting the normal use of liquid granite paint
In addition, due to the cross-linking effect of silicone in the silicone-acrylic emulsion, the film-forming property of the coating itself is poor, and it is easy to crack after film formation.
Although the pure acrylic emulsion does not have the cross-linking effect of organic silicon, its film-forming property is better, but after the pure acrylic emulsion is formulated into a liquid granite coating, its water whitening resistance is extremely poor, and it may even appear irreversible after being exposed to water, which greatly affects the normal use of the paint

Method used

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  • Reaction-activity-controllable acrylate emulsion and preparation method thereof

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preparation example Construction

[0033] The preparation method of the acrylate emulsion with controllable reactivity of the present invention comprises the following steps:

[0034] a: Preparation of monomer solution A and acid solution B: under normal temperature and pressure, mix isooctyl acrylate, methyl methacrylate, styrene, functional monomer and 50% water in total and stir evenly for 20-40 Minutes to make monomer solution A; mix the hydrophilic unsaturated organic acid with a total amount of 30% water and stir evenly for 10-20 minutes to make acid solution B;

[0035] b: Divide the monomer solution A and the acid solution B into two parts and mix them evenly to form a blend solution 1 and a blend solution 2. The mass ratio of the monomer solution A in the blend solution 1 and the blend solution 2 is 1: (1-4) , the mass ratio of the acid solution B in the blend 1 and the blend 2 is (1-4):1;

[0036] c: Preparation of pre-emulsion C: Add 50% emulsifier into blend 1 at normal temperature and pressure, an...

Embodiment 1

[0046] The acrylate emulsion with controllable reactivity of the present invention includes water, isooctyl acrylate, methyl methacrylate, styrene, acrylic acid, vinyltrimethoxysilane, sodium dodecylsulfonate and ammonium persulfate, the above-mentioned The component contents are calculated in parts by mass: 100 parts of water, 10 parts of isooctyl acrylate, 10 parts of methyl methacrylate, 5 parts of styrene, 30 parts of acrylic acid, 10 parts of vinyltrimethoxysilane, twelve parts 5 parts of sodium alkylsulfonate, 1 part of ammonium persulfate.

[0047] The preparation method of the acrylate emulsion with controllable reactivity of the present invention comprises the following steps:

[0048] a: Preparation of monomer solution A and acid solution B: under normal temperature and pressure, mix isooctyl acrylate, methyl methacrylate, styrene, functional monomer and 50% water in total and stir evenly for 20 minutes, Make monomer solution A; mix hydrophilic unsaturated organic a...

Embodiment 2

[0059] The reactive controllable acrylate emulsion of the present invention includes water, isooctyl acrylate, methyl methacrylate, styrene, acrylic acid, methacrylic acid, itaconic acid, vinyltrimethoxysilane, methacryloxy Propyltrimethoxysilane, Allyl Methacrylate Silicone Polymer, Sodium Dodecyl Sulfate, Sodium Dodecylbenzene Sulfonate, Sodium Lauryl Sulfate, Ammonium Persulfate, Potassium Persulfate and sodium persulfate, the contents of the above components are calculated in parts by mass: 100 parts of water, 40 parts of isooctyl acrylate, 50 parts of methyl methacrylate, 25 parts of styrene, 10 parts of acrylic acid, and 20 parts of methacrylic acid , 20 parts of itaconic acid, 10 parts of vinyltrimethoxysilane, 10 parts of methacryloxypropyl trimethoxysilane, 10 parts of silicon polymer of allyl methacrylate, 10 parts of dodecylsulfonic acid 3 parts sodium, 3 parts sodium dodecylbenzenesulfonate, 4 parts sodium lauryl sulfate, 1 part ammonium persulfate, 1 part potassiu...

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Abstract

The invention discloses reaction-activity-controllable acrylate emulsion. The reaction-activity-controllable acrylate emulsion is characterized by being prepared from, by mass, 100 parts of water, 10-40 parts of 2-ethylhexyl acrylate, 10-50 parts of methyl methacrylate, 5-25 parts of styrene, 30-50 parts of hydrophilicity unsaturated organic acid, 10-30 parts of functional monomers, 5-10 parts of emulgator and 1-3 parts of initiator. The reaction-activity-controllable acrylate emulsion has high water resistance, and activity in the reaction process can be controlled.

Description

technical field [0001] The invention relates to an architectural coating and a preparation method thereof, in particular to an acrylate emulsion with controllable reactivity and a preparation method thereof. Background technique [0002] With the continuous improvement of people's living standards, the types of architectural coatings are also increasing. The continuous emergence of real stone paint, sandstone paint, imitation stone paint, etc. has increased people's choices for painting the interior and exterior walls of buildings. Liquid granite, also known as water-in-water colorful paint, is a water-based environmentally friendly paint rich in granite texture that has emerged in recent years. It has a one-time spraying of natural granite texture, lifelike colors, and a high degree of simulation, so it is favored by consumers. However, the current processing of liquid granite paint usually encounters a major technical bottleneck, that is, the use of emulsion in the pain...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08F220/06C08F220/18C08F220/14C08F212/08C08F230/08C08F222/02C08F2/26C09D133/02C09D133/12C09D133/10C09D135/00
CPCC08F2/26C08F220/06C08F220/14C08F220/18C08F220/1808C08F222/02C09D133/02C09D133/10C09D133/12C09D135/00C08F212/08C08F230/08
Inventor 严东源杨小书黄天愿佘玲丽富岛和宪
Owner 佛山市顺德区巴德富实业有限公司
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