Preparation method of composite anode material for lithium-ion battery
A technology for lithium ion batteries and composite materials is applied in the field of preparation of composite negative electrode materials for lithium ion batteries, which can solve the problems of high irreversible capacity and poor cycle stability, and achieve rich lithium ion transport pathways, excellent electrochemical performance, and good application. Foreground effect
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[0030] (1) Preparation of a mixture of silicon-based precursor and graphite oxide:
[0031] Weigh 0.5g of GO and 0.25g of dicumyl peroxide and place them in 4.25ml of TTCS, ultrasonicate at 50KHz for 2h, then transfer to an agate mortar and grind for 30min to obtain a uniformly dispersed mixture of the three;
[0032] (2) Preparation of SiOC / graphene composite
[0033] Transfer the mixture obtained in step (1) to a ceramic boat, place it in the constant temperature zone of a vacuum tube furnace, feed high-purity nitrogen at a flow rate of 100ml / min as a protective atmosphere, and raise the temperature to 300°C at a heating rate of 10°C / min. ℃, keep warm for 2h; then heat up to 450°C at the same heating rate, keep warm for 1h; finally raise the temperature to 800°C at a heating rate of 10°C / min, keep warm for 0.25h, cool to room temperature 25°C, grind the product into powder to get SiOC / graphene composite.
[0034] The various properties of the obtained SiOC / graphene compo...
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