Method for producing a polymer porous support in batch
A technology of porous scaffolds and polymers, applied in coatings, medical science, prostheses, etc., can solve the problems of solvent residues, time-consuming preparation methods, and porogen residues, etc., to improve internal connectivity and cell compatibility. performance, high efficiency
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Embodiment 1
[0030] (1) After PCL and PEO are vacuum-dried, they are placed in a twin-screw extruder for melt blending, the content of PEO is 50% of the total mass of PCL and PEO, the temperature of the extrusion die is 100 ° C, and the screw speed is 100rad / s.
[0031](2) After the blend prepared in step (1) is plasticized and melted on the twin-screw extruder, supercritical nitrogen is injected into the melt, the constant pressure is 15MPa, the extrusion die temperature is 100°C, and the screw speed is 100rad / s; PCL / PEO foam material was prepared.
[0032] (3) Place the PCL / PEO foam material prepared in step (2) in a continuous circulating water flow device, filter for 24 hours, filter out the PEO phase, and obtain a PCL porous scaffold after vacuum drying for 24 hours.
[0033] (4) The PCL porous scaffold obtained in step (3) is placed in a chitosan solution with a mass concentration of 0.01% and soaked for 12 hours. The solvent used in the chitosan solution is acetic acid with a mass ...
Embodiment 2
[0035] (1) After PCL and PEO are vacuum-dried, they are placed in a twin-screw extruder for melt blending, the content of PEO is 50% of the total mass of PCL and PEO, the temperature of the extrusion die is 100 ° C, and the screw speed is 100rad / s.
[0036] (2) The blend prepared in step (1) is used as the base material, and the NaCl that the mass fraction is 10% (that is, the mass is 10% of the total mass of the polycaprolactone and the polymer porogen phase) is added in the twin-screw extruder Melt blending is carried out on the extruder, supercritical nitrogen is injected into the melt, the constant pressure is 15MPa, the temperature of the extrusion die is 100°C, and the screw speed is 100rad / s; the PCL / PEO / NaCl foam material is obtained.
[0037] (3) The PCL / PEO / NaCl foaming material prepared in the step (2) is placed in a continuous circulating water flow device, the filtration time is 24h, the porogen phase PEO and NaCl are filtered off, and the PCL porous support is ob...
Embodiment 3
[0040] (1) After PCL and PEO are vacuum-dried, they are placed in a twin-screw extruder for melt blending, the content of PEO is 50% of the total mass of PCL and PEO, the temperature of the extrusion die is 100 ° C, and the screw speed is 100rad / s.
[0041] (2) The blend prepared in step (1) is used as the base material, and the NaCl that the mass fraction is 10% (that is, the mass is 10% of the total mass of the polycaprolactone and the polymer porogen phase) is added in the twin-screw extruder Melt blending is carried out on the extruder, supercritical nitrogen is injected into the melt, the constant pressure is 15MPa, the temperature of the extrusion die is 100°C, and the screw speed is 100rad / s; the PCL / PEO / NaCl foam material is obtained.
[0042] (3) The PCL / PEO / NaCl foaming material prepared in the step (2) is placed in a continuous circulating water flow device, the filtration time is 24h, the porogen phase PEO and NaCl are filtered off, and the PCL porous support is ob...
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