Method for preparation of ethylene by ethanol dehydration
An ethanol dehydration and ethylene technology, which is applied in the production of bulk chemicals, chemical instruments and methods, organic compound/hydride/coordination complex catalysts, etc., can solve problems such as temperature reduction, catalyst activity reduction, and impact on lower catalyst performance.
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Embodiment 1
[0067] 1. Catalyst preparation:
[0068] Catalyst A preparation
[0069] (1) Preparation of carrier:
[0070] Weigh 145.8g cetyltrimethylammonium bromide and 205g citric acid to make a mixed solution, add 302mL tetraethyl orthosilicate to the mixed solution, stir for 2h, then stir at 70°C until gelation , the gel was aged at 40°C for 12h, then dried at 110°C for 8h, made into a spherical shape with a particle size of 0.2mm, then dried at 110°C for 8h, and calcined at 580°C for 3h to obtain a silica carrier, in which sixteen The molar ratio of alkyltrimethylammonium bromide to silicon oxide is 0.3, and the molar ratio of citric acid to silicon oxide is 0.8. The nature of the carrier is: the specific surface area is 525m 2 / g, the pore volume is 0.64mL / g, and the average pore diameter is 4.9nm.
[0071] (2) Preparation of catalyst:
[0072] Dissolve 27.2g of nickel nitrate in deionized water, add it to 81g of silica carrier, stir at 70°C until the solution is evaporated to ...
Embodiment 2
[0081] Catalyst A and B packing volume ratio are 1:1 among the selection embodiment 1, mass space velocity 4h -1 , the reaction temperature was 250°C, and other evaluation conditions remained unchanged. The results of ethanol conversion and ethylene selectivity are shown in Table 1.
Embodiment 3
[0083] Preparation of Catalyst A:
[0084] (1) Preparation of carrier:
[0085] Weigh 200g of cetyltrimethylammonium bromide and 105.7g of citric acid to form a mixed solution, add 250mL tetraethyl orthosilicate into the mixed solution, stir for 2 hours, and then stir at 70°C until gelation , the gel was aged at 40°C for 12h, then dried at 110°C for 8h to make a spherical particle with a diameter of 0.2mm, then dried at 110°C for 8h, and calcined at 600°C for 3h to obtain a silica carrier, in which sixteen The molar ratio of alkyltrimethylammonium bromide to silicon oxide is 0.5, and the molar ratio of citric acid to silicon oxide is 0.5. The nature of the carrier is: the specific surface area is 570m 2 / g, the pore volume is 0.72mL / g, and the average pore diameter is 5.1nm.
[0086] (2) Preparation of catalyst:
[0087] Dissolve 35.0g of nickel nitrate in deionized water, add it to 73g of silica carrier, stir at 70°C until the solution is evaporated to dryness, dry the ob...
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