Water-borne polyurethane coating agent containing superfine down fiber-polylactic acid microspheres

A polylactic acid microsphere, water-based polyurethane technology, applied in fiber processing, textiles and papermaking, etc., can solve the problems of poor moisture permeability, unfavorable large-scale production, poor hydrophobicity of silk fibroin, etc. Use experience, improve the effect of easy moisture absorption

Inactive Publication Date: 2016-07-27
ANHUI WANLING DOWN & FEATHER PROD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Water-based polyurethane coating agent is an important class of environmentally friendly coating agent, which has the advantages of excellent elasticity, soft hand feeling, wear resistance and solvent resistance, etc., but its moisture permeability is poor, which seriously affects the wearing experience of fabrics, and the production cost is high. With the improvement of market demand, it is particularly important to study waterproof and breathable environmentally friendly polyurethane fabric coating agents
"Preparation and Application of Silk Fibroin/Polyurethane Waterproof and Moisture-permeable Coating Agent" uses silk fibroin to modify polyurethane, which effectively improves the moisture permeability of the coating agent. However, the hydrophobicity of silk fibroin is poor. As the mass fraction of centrin increases, the water resistance of the coating film wi

Method used

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Examples

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Example Embodiment

[0013] The coating agent of this embodiment is prepared from the following raw materials in parts by weight: water-based polyurethane emulsion 30 with a solid content of 30%, ultra-fine down fiber polylactic acid microspheres 1, dispersant 0.1, water-based defoamer 0.1, deionized water 10 .

[0014] Wherein the preparation method of ultra-fine down fiber-polylactic acid microspheres is:

[0015] (1) After removing impurities, disinfection, cleaning and drying, the down is cut and pulverized by a high-speed shearing machine, and passed through a 625-mesh sieve. Then the sieved material is put into the refiner, and anhydrous ethanol is used as the grinding medium for refining. After grinding for 2 hours, dry at 60 °C to make ultra-fine down fibers;

[0016] (2) Dissolve polylactic acid in dichloromethane to prepare a solution with a concentration of 5%, then add the ultra-fine down fibers obtained in step (1), ultrasonically stir and disperse for 20 minutes, add absolute ethano...

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Abstract

The invention discloses a water-borne polyurethane coating agent containing superfine down fiber-polylactic acid microspheres. The superfine down fiber-polylactic acid microspheres are prepared by the following steps of treating down fibers into superfine fibers with high surface activity and high thermal stability; mixing the superfine fibers with a polylactic acid solution, wherein the superfine fibers can adsorb the polylactic acid solution by using good adsorbability of the superfine fibers; subsequently, separating out the polylactic acid by using absolute ethyl alcohol serving as a poor solvent, thus obtaining composite microspheres. The composite microspheres have air and moisture permeability of the down fibers and biocompatibility of the polylactic acid; by using the composite microspheres, the defect that superfine down fibers easily absorb moisture is overcome, the moisture and air permeability of a traditional polyurethane coating can be effectively improved, a coating with flexibility, skin friendliness, and bacteria and mildew resistance is obtained, and use experience of fabric is remarkably improved; in addition, the coating can be biodegraded and recycled.

Description

technical field [0001] The invention relates to the technical field of textile coating finishing agents, in particular to a water-based polyurethane coating agent containing ultrafine down fiber-polylactic acid microspheres. Background technique [0002] Textile coating finishing agent, referred to as coating agent, is a polymer compound film coated on the surface of the fabric to improve the style, feel and appearance of the fabric, etc., which greatly increases the added value of the textile. Water-based polyurethane coating agent is an important class of environmentally friendly coating agent, which has the advantages of excellent elasticity, soft hand feeling, wear resistance and solvent resistance, etc., but its moisture permeability is poor, which seriously affects the wearing experience of fabrics, and the production cost is high. With the improvement of market demand, it is particularly important to study waterproof and breathable environmentally friendly polyurethan...

Claims

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Application Information

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IPC IPC(8): D06M15/564D06M15/15D06M15/507D06M19/00
CPCD06M15/15D06M15/507D06M15/564D06M19/00
Inventor 周务农周茂林
Owner ANHUI WANLING DOWN & FEATHER PROD
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