Terpolymer nanosphere loaded Ni-B catalyst

Abstract

The invention provides a terpolymer nanosphere loaded Ni-B catalyst. The catalyst adopts N-isopropyl acrylamide, 2-acrylamide-2-methyl propanesulfonic acid and n-tert-butyl acrylamide as copolymerized monomers, adopts N,N'-methylene bisacrylamide as a cross-linking agent, and adopts potassium peroxodisulfate as an initiator, and terpolymer nanospheres are synthesized through a soap-free emulsion polymerization method; the nanospheres are dispersed into a nickel sulfate solution for absorbing nickel ions, and adsorbed nickel ions are reduced into nickel metal after centrifuging is performed; the terpolymer nanospheres containing a small amount of nickel metal are dispersed into a nickel plating solution for chemical nickel plating, and the terpolymer nanosphere loaded Ni-B catalyst is obtained. According to the catalyst, raw materials are easy to obtain, the synthesis method is simple, the catalysis efficiency is high, the reaction operation is simple, repeated usage can be achieved, and the terpolymer nanosphere loaded Ni-B catalyst is suitable for catalyzing a sodium borohydride hydrolysis hydrogen production reaction.

Description

[0001] The patent application of the present invention is a divisional application of a Chinese patent application with the filing date of May 30, 2014, the application number of 201410240494.0, and the name of Ni-B catalyst supported by terpolymer nanospheres, its preparation method and application. technical field [0002] The invention belongs to the technical field of material science, and in particular relates to a polymer composite material, in particular to a Ni-B catalyst supported by a terpolymer, a preparation method and its application in catalyzing the hydrolysis reaction of sodium borohydride to produce hydrogen. Background technique [0003] In order to overcome the problems of future energy shortage and environmental pollution, the search for renewable green energy is an important issue that needs to be solved urgently in the world. At present, hydrogen energy is considered to be one of the most ideal clean energy sources in the future energy structure. Hydroge...

AI Technical Summary

Problems solved by technology

[0005] Chinese patent application 201010134982.5 reported a Ru / C catalyst using a porous carbon material as a carrier. This catalyst has a large surface area, high activity, and long life. However, the precious metal Ru has limited reserves and is expensive, so it is not widely used in practice.

However, this unsupported catalyst is prone to agglomeration, resulting in a sharp drop in catalytic activity and poor reusability.

[0007] At present, sodium borohydride hydrolysis catalysts have defects such as high price or low catalytic activity, poor performance, poor catalyst reuse and regeneration performance, etc.

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