Arsenic-antimony-cyanogen-containing mine wastewater treatment method
A mine wastewater and treatment method technology, applied in the direction of mining wastewater treatment, multi-stage water treatment, water/sewage treatment, etc., can solve the problem that the water quality of the treated water is difficult to meet, and achieve the effect of realizing resource utilization
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Embodiment 1
[0071] After the downhole wastewater is generated, it should be clarified for 24 hours, then ferrous sulfate should be added to the downhole wastewater, stirred for 10 minutes, then air was introduced into the wastewater, aerated for 60 minutes, 3# flocculant was added and stirred for 5 minutes, and then sampled and analyzed after standing for 60 minutes. The treatment results are shown in Table 1. When the dosage of ferrous sulfate is 1.0-2.0mg / l and the dosage of flocculant is 1.0mg / l, the concentration of heavy metal ions such as arsenic and antimony in the treated water, CODcr, CN - All have reached a relatively low level, the water quality is relatively clear, and the arsenic and antimony can stably meet the national comprehensive sewage discharge standards.
[0072] Table 1
[0073] project
Embodiment 2
[0075] Add milk of lime to the aforementioned treated water in Example 1, adjust the pH of the wastewater to PH=10-11.5, add 3# flocculant after stirring for 30 minutes, and take the supernatant for testing after natural settlement for 60 minutes. The treatment results are shown in Table 2. Pollution factors such as arsenic, antimony, lead, and fluorine have all reached a relatively low level, and the water quality is relatively clear. The indicators such as arsenic, antimony, lead, and fluorine can stably meet the national comprehensive sewage discharge standards and the "Surface Water Environmental Quality Standard" (GB3838-2002 ) Class II water quality standard.
[0076] Table 2
[0077] project
[0078] Note: Sb, Zn 2+ is the index value of raw water
Embodiment 3
[0080] Add sulfuric acid to the treated water in Example 2, adjust the pH of the waste water to 8.0-9.0, then add chlorine dioxide to the treated water, and sample and analyze after oxidizing for 60 minutes. The treatment results are shown in Table 3. The dosage of chlorine dioxide is 5- When the concentration is 20mg / l, the CN in the treated water - , CODcr, etc. have all reached a lower level, and the water quality is relatively clear. CN - , CODcr indicators can stably meet the national comprehensive sewage discharge standards and "surface water environmental quality standards" (GB3838-2002) Class II water quality standards.
[0081] table 3
[0082] project
[0083] Note: COD value is the index value of raw water.
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