Polyvinyl chloride plastic pipe and preparation method thereof

A polyvinyl chloride and plastic tube technology, applied in the field of pipes, can solve the problems of carbon nanotubes dispersed carbon nanotubes, specific surface area agglomeration, bonding, etc., to achieve the effect of improving mechanical strength and high mechanical strength

Inactive Publication Date: 2016-08-17
安徽玉发塑业有限公司
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  • Abstract
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Problems solved by technology

[0004] Since carbon nanotubes can improve the mechanical properties, electrical properties and other properties of composite materials, carbon nanotube/rubber composites have attracted more and more attention. In order to achieve the purpose of strengthening, there are two problems to be solved: one is Dispersion of carbon nanotubes, another problem is the interface between carbon nanotubes and the matrix. Since the surface of carbon nanotubes is relatively inert, and the specific surface area is relatively large, it is easy to cause agglome

Method used

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Embodiment Construction

[0021] A kind of polyvinyl chloride plastic pipe, it is made up of the raw material of following parts by weight:

[0022] Carbon nanotubes 4, 90% sulfuric acid 40, 95% nitric acid 60, acryloyl chloride 1, 1,4 dioxane 0.01, azobisisobutyronitrile 0.2, hydroxyethyl acrylate 6, triethylamine 7, liquid EPDM rubber 10, dicumyl peroxide 1, polyvinyl chloride 100, wollastonite powder 17, tributyl citrate 5.

[0023] A kind of preparation method of described polyvinyl chloride plastic pipe, comprises the following steps:

[0024] (1) Add the above-mentioned carbon nanotubes into the above-mentioned mixed solution of 90% sulfuric acid and 95% nitric acid, stir ultrasonically for 20 hours, keep warm at 136°C for 50 minutes, filter with suction, wash with water 3 times, and dry at 70°C 20 minutes to get acidified carbon nanotubes;

[0025] (2) Add the above-mentioned azobisisobutyronitrile to 20 times its weight in absolute ethanol, stir evenly, mix with the above-mentioned acryloyl c...

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Abstract

The invention discloses a polyvinyl chloride plastic pipe which is prepared from the following raw materials in parts by weight: 4-6 parts of carbon nanotube, 40-60 parts of 90-93% sulfuric acid, 60-70 parts of 95-97% nitric acid, 1-2 parts of acryloyl chloride, 0.01-0.02 part of 1,4-dioxane, 0.2-0.3 part of azodiisobutyronitrile, 6-10 parts of 2-hydroxyethyl acrylate, 7-8 parts of triethylamine, 10-14 parts of liquid ethylene propylene diene monomer rubber, 1-1.2 parts of dicumyl peroxide, 100-120 parts of polyvinyl chloride, 17-20 parts of wollastonite powder and 5-6 parts of tributyl citrate. The high-dispersity liquid ethylene-propylene rubber is added into the polyvinyl chloride matrix and effectively combined with the modified carbon nanotubes through double bonds, and thus, the matrix can transfer loading stress to the carbon nanotubes through chemical bonds, thereby enhancing the mechanical strength.

Description

technical field [0001] The invention relates to the technical field of pipes, in particular to a polyvinyl chloride plastic pipe and a preparation method thereof. Background technique [0002] Carbon nanotubes have strong axial strength, toughness and elastic modulus. After theoretical calculations, it is concluded that the Young's modulus of carbon nanotubes can reach 5TPa, which is an order of magnitude higher than that of ordinary fibers; its theoretical tensile strength is 50- 20OGPa, which is 100 times that of steel, but the density is only one-sixth of steel. In addition, the hollow cage-like structure of carbon nanotubes can undergo a certain volume deformation when subjected to strong external forces, and then shows good flexibility. It can be regarded as a very excellent fiber, and the tension and strain of carbon nanotubes will not show brittle fracture, plastic deformation fracture or bond fracture, so the structure of carbon nanotubes is stronger than ordinary po...

Claims

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Application Information

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IPC IPC(8): C08L27/06C08L23/16C08K13/06C08K9/04C08K9/02C08K7/24C08K3/34C08K5/11
CPCC08K2201/011C08L27/06C08L2203/18C08L23/16C08K13/06C08K9/04C08K9/02C08K7/24C08K3/34C08K5/11
Inventor 舒峰季琨姚艳芳张宗运王克兰舒玉法胡克文马勇
Owner 安徽玉发塑业有限公司
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