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Emulsion pressure-sensitive adhesive and PE protection film prepared from same

A hydraulic and emulsifier technology, used in pressure-sensitive films/sheets, adhesives, film/sheet adhesives, etc., to solve problems such as pollution, watermarks on product surfaces, mottled or "ghost images, etc." The effect of preventing scratches

Inactive Publication Date: 2016-10-12
JIANGYIN JIANGTAI HIGH POLYMER NEW MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] As a product widely used in industrial production, protective film is usually used to temporarily protect the surface of products or parts to avoid scratches or contamination of the surface during processing, so the protective film came into being , which is mainly used to protect the surface of the product, but will eventually be removed from the surface of the product. Therefore, in general, the protective film needs to have the following characteristics: 1. The protective film needs to be easily attached to the surface of the product to be protected; 2. When the protective film needs to be removed, it can be peeled off from the surface of the protected object with an appropriate peeling force; 3. The surface of the protected object cannot be polluted by the protective film; at present, a Chinese patent with a publication number of 102964512A discloses a An emulsion-type acrylate pressure-sensitive adhesive and a preparation method thereof, comprising methyl methacrylate and vinyl acetate as raw materials to prepare a prepolymer, adding an acrylic diluent for dilution, and simultaneously adding 2-hydroxyethyl methacrylate Carry out modification, adjust its PH value, and finally prepare emulsion-type acrylic pressure-sensitive adhesive. May leave watermarks, mottling or "ghosting" on the surface of the product. "Ghosting" is generally due to a light haze that remains on the surface of the product when the protective film is removed, but this substance is not It is residual glue, which is generally considered to be the result of the migration of low molecular weight substances in the protective film adhesive from the protective film adhesive layer to the pasted surface

Method used

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  • Emulsion pressure-sensitive adhesive and PE protection film prepared from same

Examples

Experimental program
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Effect test

Embodiment 1

[0027] Methyl acrylate 36Kg, methyl methacrylate 4.8Kg, hydroxyethyl methacrylate 0.6Kg, hydroxyethyl acrylate 2Kg, acrylic acid 0.6Kg, γ-glycidyl etheroxypropyl trimethoxysilane (KH560 crosslinking agent) 1Kg, (alkylphenol) allyl polyether sulfate 0.5Kg, allyloxy nonylphenol polyoxyethylene ether sulfate 0.1Kg, azobisisobutylamidine hydrochloride 0.1Kg, water 45Kg, and Emulsion 1 was prepared by conventional emulsion polymerization.

Embodiment 2

[0029] Isooctyl acrylate 18Kg, ethyl acrylate 11.25Kg, isooctyl acrylate 4.8Kg, methyl methacrylate 8.25Kg, hydroxypropyl methacrylate 1Kg, methylol acrylamide 1Kg, acrylic acid 0.45Kg, itaconic acid 0.25 Kg, KH-560 1Kg, 1.5Kg of nonionic emulsifier prepared by EO / PO ring opening, 0.2Kg of anionic emulsifier, 0.1Kg of azobisisobutylamidine hydrochloride, 45Kg of water, according to the conventional emulsion polymerization method Prepare emulsion two.

Embodiment 3

[0031] Lauryl acrylate 38.02Kg, butyl acrylate 2.5Kg, isooctyl acrylate 2Kg, methacrylic acid 1Kg, glycidyl methacrylate 0.25Kg, maleic anhydride 0.1Kg, KH-560 1Kg, sodium alkyl sulfate 0.5Kg, Sodium dodecylsulfonate 0.5Kg, allyloxy fatty alcohol polyoxyethylene ether sulfate 1.4Kg, azobisisobutylamidine hydrochloride 0.5Kg, water 45Kg, prepared emulsion three by conventional emulsion polymerization method .

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Abstract

The invention discloses an emulsion pressure-sensitive adhesive and a PE protection film prepared from the same, and aims at providing the PE protection film prepared from the emulsion pressure-sensitive adhesive. The emulsion pressure-sensitive adhesive is prepared from 40-60 parts of acrylate monomers, 0.1-10 parts of functional monomers, 0.1-5 parts of epoxy group containing organosilicone, 0.1-2.0 parts of emulgator, 0.1-0.5 part of initiator and 40-60 parts of water. The surface of bright and clean metal or a coating is covered with the PE protection film prepared from the emulsion pressure-sensitive adhesive, and water stains or ghost patterns or spots or other bad phenomena cannot be left on the surface.

Description

technical field [0001] The invention relates to the field of chemical industry, in particular to an emulsion pressure-sensitive adhesive and a PE protective film prepared by using the pressure-sensitive adhesive. Background technique [0002] As a product widely used in industrial production, protective film is usually used to temporarily protect the surface of products or parts to avoid scratches or contamination of the surface during processing, so the protective film came into being , which is mainly used to protect the surface of the product, but will eventually be removed from the surface of the product. Therefore, in general, the protective film needs to have the following characteristics: 1. The protective film needs to be easily attached to the surface of the product to be protected; 2. When the protective film needs to be removed, it can be peeled off from the surface of the protected object with an appropriate peeling force; 3. The surface of the protected object c...

Claims

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Application Information

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IPC IPC(8): C09J133/08C09J7/02C08F220/18C08F220/14C08F220/28C08F220/06C08F220/58
CPCC08F220/14C08F220/18C08F220/1804C08F220/1808C09J7/22C09J7/38C09J133/08C09J2301/302C09J2433/00C08F220/281C08F220/06C08F220/58C08F220/1818
Inventor 张嘉磊张国良
Owner JIANGYIN JIANGTAI HIGH POLYMER NEW MATERIAL CO LTD
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