New concept-based phosphor with planting corner angle and penetration and diffusion layer and light-emitting device

A technology of permeation diffusion and phosphor, applied in the field of LED phosphors and light-emitting devices, can solve the problems of poor color consistency of LED finished lamp beads, increased color temperature of LED finished lamp beads, unable to meet the requirements of color temperature stability, etc. Light color consistency, excellent heat absorption/heat dissipation, alleviating the effect of poor light color consistency

Active Publication Date: 2016-10-12
JIANGSU BREE OPTRONICS CO LTD
View PDF9 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In the field of LED packaging, the stability and yield rate of finished LED lamp beads have attracted much attention, especially the color temperature stability of LED lamp beads during use, because the use of existing phosphors needs to be reconciled in LED packaging materials, and LED The thermal conductivity of the packaging material is much smaller than that of the phosphor, so the self-dissipation performance of the phosphor is very poor, which cannot meet the color temperature stability requirements after the package is lit. It often occurs that the color temperature of the finished LED bead rises or falls with the prolongation of the lighting time. The phenomenon of lowering has seriously hindered the popularization and use of white light LEDs.
Furthermore, most of the existing white light LEDs are encapsulated by mixing two or more types of phosphor powders. The particle size of the phosphor powders is inconsistent, which leads to inconsistent sedimentation rates in the packaging materials, which ultimately leads to poor light and color consistency of LED finished lamp beads.
How to overcome the problems of cold-hot color temperature drift and poor packaging light color consistency in the use of existing phosphors has become one of the major problems to be solved in the technical field of LED phosphors and light-emitting devices.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • New concept-based phosphor with planting corner angle and penetration and diffusion layer and light-emitting device
  • New concept-based phosphor with planting corner angle and penetration and diffusion layer and light-emitting device
  • New concept-based phosphor with planting corner angle and penetration and diffusion layer and light-emitting device

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] Weigh 100g of (Sr,Ca)AlSiN 3 :Eu 2+ Red phosphor, 0.1g calcium oxide angular planting agent, mix the above raw materials for 3 hours, put them into a molybdenum crucible, then quickly move them into a tube furnace, and then gradually heat up to 200°C under the protection of nitrogen atmosphere, and keep warm for 12 hours , to get (Sr,Ca)AlSiN with planted CaO corners 3 :Eu 2+ Red phosphor; weigh 100g of (Sr,Ca)AlSiN with planted calcium oxide corners 3 :Eu 2+ Red phosphor, 0.5g thermal conductivity 10W / m.k, particle size 2nm, specific surface area 80cm 2 / g of nano-silica and 200mL of absolute ethanol were added to a three-necked flask equipped with a tetrafluoroethylene stirring rod and a thermometer placed in a water bath, stirred and heated to 70°C for 2h, and then the reaction was terminated. After suction filtration, washing with absolute ethanol and drying, (Sr,Ca)AlSiN with planted nano-silica infiltration diffusion layer and calcium oxide corners was obtain...

Embodiment 2

[0052] Weigh 100g of (Sr,Ca)AlSiN 3 :Eu 2+ Red phosphor, 0.2g alumina edge planting agent, mix the above raw materials for 3 hours, put them into a molybdenum crucible, then quickly move them into a tube furnace, and then gradually raise the temperature to 400°C under the protection of nitrogen atmosphere, and keep warm for 12 hours , to get (Sr,Ca)AlSiN with planted alumina corners 3 :Eu 2+ Red phosphor; Weigh 100g of (Sr,Ca)AlSiN with planted alumina corners 3 :Eu 2+ Red phosphor, 1.0g thermal conductivity 20W / m.k, particle size 15nm, specific surface area 150cm 2 / g of nano-magnesium oxide and 200mL of absolute ethanol were respectively added to a three-necked flask equipped with a tetrafluoroethylene stirring rod and a thermometer placed in a water bath, stirred and heated to 70°C for 2h, and then the reaction was terminated. After suction filtration, washing with absolute ethanol and drying, the (Sr,Ca)AlSiN with implanted nano-magnesia infiltration diffusion layer a...

Embodiment 3

[0054] Weigh 100g of (Sr,Ca)AlSiN 3 :Eu 2+ Red phosphor, 0.8g of strontium oxide angular planting agent, mix the above raw materials for 3 hours, put them into a molybdenum crucible, then quickly move them into a tube furnace, and then gradually raise the temperature to 800°C under the protection of a nitrogen atmosphere, and keep it warm for 12 hours , to obtain (Sr,Ca)AlSiN with planted strontium oxide edges 3 :Eu 2+ Red phosphor; Weigh 100g of (Sr,Ca)AlSiN with planted strontium oxide edges 3 :Eu 2+ Red phosphor, 1.8g thermal conductivity 40W / m.k, particle size 50nm, specific surface area 500cm 2 / g of nano-zinc oxide and 200mL of absolute ethanol were respectively added to a three-necked flask equipped with a tetrafluoroethylene stirring rod and a thermometer placed in a water bath, stirred and heated to 70°C for 2h, and then the reaction was terminated. After suction filtration, washing with absolute ethanol and drying, (Sr,Ca)AlSiN with implanted nano-zinc oxide inf...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

PropertyMeasurementUnit
thicknessaaaaaaaaaa
particle diameteraaaaaaaaaa
particle diameteraaaaaaaaaa
Login to view more

Abstract

The invention relates to a new concept-based phosphor with a planting corner angle and a penetration and diffusion layer. The phosphor is characterized by comprising an inorganic compound phosphor, a corner angle planting agent and a penetration planting agent, wherein primary bonding of the corner angle planting agent and the surface of the inorganic compound phosphor is carried out to form the inorganic compound phosphor with the planting corner angle; and secondary bonding of the penetration planting agent and the surface of the inorganic compound phosphor with a corner angle shape is carried out to form the phosphor with the planting corner angle and the penetration and diffusion layer. The phosphor with the planting corner angle and the penetration and diffusion layer has excellent cold-to-hot state performance and good chemical stability and is suitable for various light-emitting devices. The preparation method provided by the invention is simple, convenient and reliable, and is suitable for industrialized mass production and manufacturing.

Description

technical field [0001] The invention belongs to the technical field of LED phosphors and light-emitting devices, and in particular relates to a phosphor and a light-emitting device based on a new concept that can be effectively excited by ultraviolet light, purple light or blue light. Background technique [0002] In the context of global energy shortage, LED lighting products have attracted much attention. With the rapid development of white LED technology, the replacement of traditional lighting sources and backlights is accelerating, and semiconductor lighting will be popularized rapidly. In the field of LED packaging, the stability and yield rate of finished LED lamp beads have attracted much attention, especially the color temperature stability of LED lamp beads during use, because the use of existing phosphors needs to be reconciled in LED packaging materials, while LED The thermal conductivity of the packaging material is much smaller than that of the phosphor, so the...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): H01L33/50C09K11/80C09K11/55C09K11/64C09K11/61
CPCC09K11/616C09K11/64C09K11/7728C09K11/7734C09K11/7774H01L33/502
Inventor 何锦华梁超符义兵李树亚
Owner JIANGSU BREE OPTRONICS CO LTD
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products