System for preparing viscose by pretreating corn straw through microbial co-culture

A technology of corn stalks and viscose fibers, which is applied to artificial filaments made of viscose, melt spinning, etc., can solve the problems of low yield of aerobic fermentation, long pretreatment period, high cost of enzyme preparations, etc. Effect of bleaching process, reduced cooking conditions, and reduced impact

Active Publication Date: 2016-11-09
吉林中之林农业科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Some directly use chemical pulping to prepare viscose fiber, but the pollution is serious; some choose enzyme preparation to pretreat biomass to prepare viscose fiber, but the cost of enzyme preparation is too high; some use dilute acid pretreatment, The pollution is also serious; some choose aerobic microorganisms to pretreat corn stalks, because the yield of aerobic fermentation is low; some use anaerobic microorganisms to ferment, but use batch fermentation equipment, and the pretreatment period is long; Processing, but not continuous pulping and spinning, and a large amount of black liquor is also required to be processed in an open environment

Method used

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  • System for preparing viscose by pretreating corn straw through microbial co-culture

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Embodiment 1

[0023] Using corn stalk husks separated from corn stalk leaves and husks as raw materials, the rumen fungus Neocallimastix frontalis isolated from the rumen of ruminant cattle and rumen bacteria Fibrobacter succinogenes were co-cultured to degrade hemicellulose and unstable fibers in straw husks. element; the domesticated co-cultivated microorganisms and the straw husks deprived of oxygen are fermented in an anaerobic continuous culture system, and the fermentation products are separated by the membrane separation device of the continuous culture system without antagonism, and the fermentation time is 48 hours. The pretreatment of corn stalk husks degrades the unstable cellulose and hemicellulose in corn stalk husks, and generates some monomers and highly crystalline lignocellulose; through regulation, the fermentation products can be separated in situ to realize the biological pretreatment of corn stalk husks, and the remaining The high crystalline lignocellulose; after anaero...

Embodiment 2

[0025]Corn stalk husks separated from corn stalk leaves and husks are used as raw materials, and rumen microorganisms are used for anaerobic co-cultivation with rumen microbial degradation products or metabolite utilization bacteria to degrade hemicellulose and unstable cellulose in straw husks; Co-cultivation of animal rumen fungus Neocallimastix frontalis and ethanologen Candida tropicalis; degradation of unstable cellulose and hemicellulose in corn stalk husks; domesticated co-cultured microorganisms and straw husks deprived of oxygen in an anaerobic continuous culture system Fermentation is carried out, and the fermentation product is separated by the membrane separation device of the continuous culture system without antagonism. The fermentation time is 36 hours, and the pretreatment of the corn stalk husk is completed; the fermentation product can be separated in situ through regulation, and the biological pretreatment of the corn stalk husk is realized. The remaining hig...

Embodiment 3

[0027] Using corn stalk husks separated from corn stalk leaves and husks as raw materials, the rumen fungus Neocallimastix frontalis and lactic acid bacteria Pediococcus acidilactic were co-cultured; the unstable cellulose and hemicellulose in corn stalk husks were degraded to generate some simple body and high crystalline lignocellulose; ferment the domesticated co-cultured microorganisms and the straw bark deprived of oxygen in an anaerobic continuous culture system, and the fermentation products are separated by the membrane separation device of the continuous culture system without antagonism. The time is 12 hours, and the pretreatment of corn stalk husks is completed. Through regulation, the fermentation product can be separated in situ, and the biological pretreatment of corn stalks can be realized. The remaining high-crystalline lignocellulose, after anaerobic fermentation, enters the anaerobic continuous cooking system under anaerobic conditions in a fully enclosed envi...

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Abstract

The invention relates to a system for preparing viscose by pretreating corn straw through microbial co-culture. Corn straw peel obtained after corn straw stalks and leaves and peel are separated is used as a raw material, microbial co-culture of biomass degradation rumen microorganisms and a rumen microorganism degradation product or metabolite is achieved through fermentation of special equipment to degrade hemicellulose and unstable cellulose in the straw peel, the fermentation product can be separated in situ through regulation to achieve biological pretreatment on the corn straw peel, remaining high-crystallized lignocellulose is continuously cooked under the anaerobic environment to remove lignin and is subjected to cellulose dyeing or bleaching, viscose dissolution spinning is directly carried out on centrifuged cellulose pulp under the condition of certain water content, or melt spinning is carried out under the dry condition to prepare viscose. Usage of agentia for following cooking delignification is reduced through biological pretreatment, and then pollution is reduced; oxidization and blackening of pulp are reduced through anaerobic cooking, and then pollution is reduced; meanwhile, characteristics of fiber are kept to the maximum.

Description

technical field [0001] The invention relates to a method for preparing viscose fiber from biomass, in particular to a method for continuously preparing viscose fiber from corn stalks under anaerobic conditions by co-cultivating microorganisms. Background technique [0002] In recent years, there have been a variety of methods for preparing biomass viscose fiber using corn stalks as raw materials through biological methods. Some directly use chemical pulping to prepare viscose fiber, but the pollution is serious; some choose enzyme preparation to pretreat biomass to prepare viscose fiber, but the cost of enzyme preparation is too high; some use dilute acid pretreatment, The pollution is also serious; some choose aerobic microorganisms to pretreat corn stalks, because the yield of aerobic fermentation is low; some use anaerobic microorganisms to ferment, but use batch fermentation equipment, and the pretreatment period is long; Processing, but not continuous pulping and spinn...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F2/06D01D5/08
CPCD01D5/08D01F2/06
Inventor 侯哲生郑勇王文刚佟金石敏马云海连建伟王九刚刘发现梁嗣超张金翠王德林陈胜任露泉殷敬华
Owner 吉林中之林农业科技有限公司
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