Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Preparation method of hydroxyl-ferric oxide/graphene oxide composite material and application of hydroxyl-ferric oxide/graphene oxide composite material

A technology of iron oxyhydroxide and composite materials, applied in chemical instruments and methods, other chemical processes, water/sewage treatment, etc., can solve the problems of high operating cost, easy to be blocked, high toxicity, etc., and achieve rich oxygen-containing groups , efficient adsorption, and large specific surface area

Inactive Publication Date: 2016-12-14
TIANJIN UNIV
View PDF7 Cites 18 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Chemical oxidation uses a strong oxidizing agent such as O 3 , Fenton reagent, etc. for oxidation treatment, the treatment effect of phenol-containing wastewater is obvious, but the oxidant cost is high and the technical equipment requirements are high; the photocatalytic oxidation method oxidizes chlorophenol by catalyzing the generation of hydroxyl radicals. Although this method has good treatment effect and short reaction time, However, in some treatment processes, more toxic intermediate products may be produced, making it difficult to apply chemical methods to treat chlorinated phenols; the membrane separation method is to filter and treat phenol-containing wastewater through synthetic membranes, but the membranes are prone to failure after long-term operation. If it is clogged, the permeation of the membrane will decrease, and the membrane modules will need to be replaced frequently, resulting in high operating costs. These problems make the membrane separation technology have certain limitations in practical application; although the biological method of treating phenolic wastewater is low in cost and has no secondary pollution, but the biological system has low treatment efficiency and poor operation stability, which limits the application of biological methods to treat phenolic wastewater

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0025] Graphite powder and potassium permanganate are in a mass ratio of 1:1, add sulfuric acid and phosphoric acid with a volume ratio of 8:1 mixed acid, and heat in a water bath at 50°C for 2 hours. The oxidized graphite is filtered, dried and ground into powder for later use.

[0026] The mass of graphite oxide and the volume of deionized water are 1g:50ml, mixed and dispersed for 5-10min to prepare a 0.02g / ml graphene oxide suspension.

[0027] Fe(NO 3 ) 3` 2H 2 O and NaOH were mixed in 100ml deionized water for 30min according to the mass ratio of 1.2:1, and kept in an oven at 150°C for 24 hours.

[0028] Mix the obtained iron oxyhydroxide mass with deionized water volume according to 0.5g:50ml, and disperse for 5 minutes to prepare 0.1g / ml iron oxyhydroxide suspension. The uniformly dispersed iron oxyhydroxide suspension was added to the dispersed graphene oxide suspension, and the mixed solution was dispersed for 5-10 minutes, and kept in an oven at 120° C. for 24 h...

Embodiment 2

[0031] Graphite powder and potassium permanganate are in a mass ratio of 1:2, add sulfuric acid and phosphoric acid with a volume ratio of 7:1 mixed acid, and heat in a water bath at 50°C for 2 hours. The oxidized graphite is filtered, dried and ground into powder for later use.

[0032] The mass of graphite oxide and the volume of deionized water were mixed according to 1g:50ml, and dispersed for 5-10min to prepare a 0.02g / ml graphene oxide suspension.

[0033] Fe(NO 3 ) 3` 2H 2 O and NaOH were added into 100ml deionized water according to the mass ratio of 1:1, mixed for 30min, and kept in an oven at 120°C for 24 hours.

[0034] The mass of the obtained iron oxyhydroxide and the volume of deionized water were mixed according to 1g:50ml, and dispersed for 5 minutes to prepare a 0.2g / ml iron oxyhydroxide suspension. The uniformly dispersed iron oxyhydroxide suspension was added to the dispersed graphene oxide suspension, and the mixed solution was dispersed for 5-10 minute...

Embodiment 3

[0037] Graphite powder and potassium permanganate are in a mass ratio of 1:3, add sulfuric acid and phosphoric acid with a volume ratio of 6:1 mixed acid, and bathe in water at 50°C for 2 hours. The oxidized graphite is filtered, dried and ground into powder for later use.

[0038] The mass of graphite oxide and the volume of deionized water are 1g:50ml, mixed and dispersed for 5-10min to prepare a 0.02g / ml graphene oxide suspension.

[0039] Fe(NO 3 ) 3` 2H 2 O and NaOH were added into 100ml deionized water according to the mass ratio of 0.5:1, mixed for 30min, and kept in an oven at 120°C for 24 hours.

[0040] The mass of the obtained iron oxyhydroxide and the volume of deionized water were mixed according to 1g:50ml, and dispersed for 5 minutes to prepare a 0.2g / ml iron oxyhydroxide suspension. The uniformly dispersed iron oxyhydroxide suspension was added to the dispersed graphene oxide suspension, and the mixed solution was dispersed for 5-10 minutes, and kept in an ov...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
adsorption capacityaaaaaaaaaa
adsorption capacityaaaaaaaaaa
Login to View More

Abstract

The invention relates to a preparation method of a hydroxyl-ferric oxide / graphene oxide composite material and application of the hydroxyl-ferric oxide / graphene oxide composite material. The hydroxyl-ferric oxide / graphene oxide composite material is formed by mixing a turbid liquid of graphene oxide and a turbid liquid of hydroxyl-ferric oxide according to the volume ratio of 1: (1-2), dispersing, and compounding by a hydrothermal method. The prepared hydroxyl-ferric oxide / graphene oxide composite material is used for treating phenol-containing wastewater; 0.5 to 5 g of the hydroxyl-ferric oxide / graphene oxide composite adsorption material is fed into 1,000 ml of the wastewater with the chlorophenol concentration of 10 to 60 mg / l, and then fully oscillated on a constant-temperature shaking table, the water temperature is controlled to be at 25 DEG C, and after reaction is conducted for 3 h, the wastewater is filtered. Detection shows that the chlorophenol removal rate is 87 to 93.2 percent, the chlorophenol concentration of discharged water is 1.3 to 5.2 mg / l, and the adsorption amount is 11 to 17.4 mg / l.

Description

technical field [0001] The invention relates to the technical field of water pollution control, in particular to a preparation method of an iron oxyhydroxide / graphene oxide composite material and its application in water treatment. Background technique [0002] With the rapid development of the chemical industry, organochlorine compounds have been widely used in the fields of medicine, agricultural supplies, textiles, daily chemicals, and public health, but they have also caused serious environmental pollution. Many organochlorine compounds are highly toxic, difficult to biodegrade, have a long half-life, have "three effects" and genotoxicity, and the long-term residue of these organochlorine compounds in the environment will affect the environment and endanger the health of various organisms and human beings. [0003] Chlorophenol aromatic compounds are a type of typical organochlorine compounds, which can cause poisonous effects on various organisms after entering the envi...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/20B01J20/06B01J20/30C02F1/28C02F101/34C02F101/36
CPCB01J20/20B01J20/06C02F1/281C02F2101/345C02F2101/36
Inventor 李壮赵迎新
Owner TIANJIN UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products