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Pyrolysis and reduction reaction system and method for recycling type laterite-nickel ore wet pellets in flue gas waste heat furnace body

A technology of laterite nickel ore and waste heat of flue gas, which is applied in the field of chemical industry and metallurgy, can solve the problems that oil and gas resources cannot be realized, and recovery of reduced coal has not been considered, so as to reduce energy consumption, reduce process energy consumption and cost, and increase by-products.

Active Publication Date: 2016-12-14
JIANGSU PROVINCE METALLURGICAL DESIGN INST
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In view of the current situation that the existing rotary hearth furnace technology for processing laterite nickel ore does not consider the recovery of oil and gas resources in the reduced coal in the direct reduction process and the fact that the wet pellets cannot be directly fed into the furnace, the present invention proposes a method for reusing the waste heat of flue gas inside the furnace body. Pyrolysis and reduction reaction system and method of laterite nickel ore wet pellets to realize coal pyrolysis and reduction smelting of laterite nickel ore wet pellets in the coal-based direct reduction process of laterite nickel ore

Method used

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  • Pyrolysis and reduction reaction system and method for recycling type laterite-nickel ore wet pellets in flue gas waste heat furnace body
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  • Pyrolysis and reduction reaction system and method for recycling type laterite-nickel ore wet pellets in flue gas waste heat furnace body

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Effect test

Embodiment 1

[0060] The lateritic nickel ore (containing Ni 1.85%), bituminous coal (25% volatile matter) and sodium carbonate are batched and mixed in the batching device at a mass ratio of 100:10:5 to obtain a mixed material, and the mixed material is formed Wet pellets (water content 14.6%) are obtained by forming in the device, and then the wet pellets are pyrolyzed and reduced in a rotary hearth furnace with pyrolysis and reduction functions, and the pyrolysis zone and low-temperature reduction zone of the rotary hearth furnace are heated The heat of the tube comes from the heat exchange of the high-temperature dedusting flue gas of the rotary hearth furnace. The included angle of the ring in the dry pyrolysis zone is 60º, the temperature in the dry pyrolysis zone is 900°C, and the residence time is 10min; The temperature is 1100°C, and the residence time is 10 minutes; the included angle of the ring in the high-temperature reduction zone is 180º, and the temperature in the high-temper...

Embodiment 2

[0062] Three kinds of raw materials below 100 mesh: laterite nickel ore (containing Ni 2.45%), lignite (40% volatile matter) and limestone are batched and mixed in the batching and batching device at a mass ratio of 100:20:15 to obtain a mixture The mixed material is molded in a molding device to obtain wet pellets (water content 18.6%), and then the wet pellets are pyrolyzed and reduced in a rotary hearth furnace with pyrolysis and reduction functions. The heat of the heating tubes in the decomposition zone and the low-temperature reduction zone comes from the heat exchange of the high-temperature dedusting flue gas of the rotary hearth furnace. The included angle is 110º, the temperature in the low-temperature reduction zone is 1150°C, and the residence time is 20 minutes; the included angle of the ring in the high-temperature reduction zone is 140º, the temperature in the high-temperature reduction zone is 1400°C, and the residence time is 10 minutes. The pyrolysis oil and ...

Embodiment 3

[0064] The laterite nickel ore (containing Ni 1.12%), sub-bituminous coal (35% volatile matter) and lime are mixed and mixed in the batching device according to the mass ratio of 100:30:9 to obtain the mixed material, and the mixed material is molded Wet pellets (water content 25%) are obtained by forming in the device, and then the wet pellets are pyrolyzed and reduced in a rotary hearth furnace with pyrolysis and reduction functions, and the pyrolysis zone and low-temperature reduction zone of the rotary hearth furnace are heated The heat of the tube comes from the heat exchange of the high-temperature dedusting flue gas of the rotary hearth furnace. The included angle of the ring in the dry pyrolysis zone is 150º, the temperature in the dry pyrolysis zone is 750°C, and the residence time is 30 minutes; The temperature is 1000°C, and the residence time is 10 minutes; the included angle of the ring in the high-temperature reduction zone is 120º, and the temperature in the high...

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Abstract

The invention relates to the field of chemical metallurgy, in particular to a pyrolysis and reduction reaction system and method through laterite-nickel ore. Aiming at the defects in the prior art, the invention provides a pyrolysis and reduction reaction system and method for recycling type laterite-nickel ore wet pellets in a flue gas waste heat furnace body to achieve pyrolysis of coal and reduction smelting of the laterite-nickel ore wet pellets in the laterite-nickel ore coal-based direct reduction process. In the pyrolysis and reduction reaction system, the laterite-nickel ore wet pellets are put into a rotary hearth furnace, and the drying processes are decreased. Semicoke subjected to pyrolysis continuously participates in direct reduction reaction of the laterite-nickel ore in the rotary hearth furnace, so that metallized pellets are obtained. According to the pyrolysis and reduction reaction system, pyrolysis of the coal is achieved in the laterite-nickel ore direct reduction process, so that precious oil and gas resources are recycled, and by-products of the rotary hearth furnace coal-based direct reduction technology are increased; and in addition, flue gas waste heat produced in the rotary hearth furnace body can be effectively reused, thus, the environmental protection effect is achieved through the system, and technology energy consumption the cost are indirectly reduced.

Description

technical field [0001] The invention relates to the field of chemical metallurgy. Specifically, the present invention relates to a system and method for utilizing pyrolysis and reduction reactions of laterite nickel ore. Background technique [0002] In recent years, with the depletion of high-grade nickel sulfide ore and the rapid development of the domestic stainless steel industry, low-grade laterite nickel ore has become the main raw material for the production of ferronickel products. In order to solve the problem of rational utilization of laterite nickel ore, use laterite nickel ore as raw material and coal powder as reducing agent, adopt direct reduction method to reduce the iron and nickel in the ore into metallic iron and metallic nickel, and then undergo melting or grinding Enrich nickel into ferronickel products. [0003] Nowadays, there are many kinds of coal-based direct reduction processes. Among them, the rotary hearth furnace reduction process has attracte...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22B23/02C21B11/00
CPCC21B11/00C22B23/021Y02P10/20
Inventor 宋文臣王静静李红科曹志成薛逊吴道洪
Owner JIANGSU PROVINCE METALLURGICAL DESIGN INST