Supported foamy copper catalyst used for removing acrylonitrile through supercritical water oxidation

Abstract

The invention discloses a supported foamy copper catalyst used for removing acrylonitrile through supercritical water oxidation. A preparation method of the catalyst comprises the following steps: cleaning foamy copper and then modifying foamy copper with AgNO3, thus preparing a substance M; modifying the substance M with mixed liquor prepared from polyvinylpyrrolidone, methanol, palladium dichloride, gold chloride, concentrated hydrochloric acid and sodium borohydride, thus preparing a substance N; modifying the substance N with mixed liquor prepared from PbCl2, SrCl2, concentrated nitric acid, urea and ammonium fluoride, thus preparing a substance O; modifying the substance O with mixed liquor prepared from tetra-n-butyl titanate, tetraethyl orthosilicate and acetylacetone, thus preparing a substance P; modifying the substance P with mixed liquor prepared from ZrCl4, CdCl2 and AlCl3, thus preparing a substance Q; modifying the substance Q with mixed liquor prepared from ZnCl2, BiCl3, NaOH, Na2CO3 and CuCl2, thus obtaining a substance, namely the supported foamy copper catalyst used for removing acrylonitrile through supercritical water oxidation.

Description

technical field [0001] The invention belongs to the technical field of supercritical water oxidation for refractory organic wastewater treatment, and in particular relates to a supported foam copper catalyst used for supercritical water oxidation to remove acrylonitrile. Background technique [0002] Supercritical water oxidation is a wastewater treatment technology developed in the 1980s. It mainly uses molecular oxygen or hydrogen peroxide as an oxidant and supercritical water as a solvent to oxidize and decompose organic pollutants. In the oxidation process, due to the good solubility of supercritical water to various organic substances and oxygen, organic substances, oxidants and supercritical water form a homogeneous phase, the reaction will not be hindered by the mass transfer between the phases, and the reaction rate can be greatly increased. The reaction temperature of supercritical water oxidation treatment technology is generally 400-600°C, and the pressure is 30-5...

AI Technical Summary

Problems solved by technology

The catalyst commonly used in catalytic supercritical water oxidation technology is MnO 2 , CuO, TiO 2 , CeO 2 、Al 2 o 3 , Pt or a composite catalyst composed of several of them such as Cr 2 o 3 / Al 2 o 3 , CuO / A1 2 o 3 , MnO 2 / CeO 2 However, these catalysts have disadvantages such as poor stability and low catalytic activity, which limit the application and development of catalytic supercritical water oxidation technology in water treatment, so the research and preparation of new catalytic materials need to be further strengthened, especially However, there is still a lack of catalysts for supercritical water oxidation to remove acrylonitrile