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Alcohol and/or ether propylene product separation method

A separation method and propylene technology, applied in absorption purification/separation, chemical instruments and methods, hydrocarbon purification/separation, etc., can solve the problems of poor economic effect and high energy consumption of devices, and reduce the consumption of refrigeration and energy consumption. Low, reduced process energy consumption

Active Publication Date: 2018-10-23
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] The technical problem to be solved by the present invention is that there are problems of high energy consumption and poor economic effect in the prior art, and a new separation method for producing propylene hydrocarbon products from alcohol and / or ether is provided

Method used

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  • Alcohol and/or ether propylene product separation method
  • Alcohol and/or ether propylene product separation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] See the process flow figure 1 . Methanol is converted into propylene as the main reaction product in the methanol-to-propylene reactor, and the gas phase hydrocarbon stream 1 is obtained after dehydration and acid gas carbon dioxide. Gas-phase hydrocarbon stream 1 has a temperature of 43°C, a pressure of 0.13MPa, and a molar composition of 18.7% carbon one to carbon two components, 45.9% carbon three components, 27.5% carbon four carbon five components, 7.9% carbon six and more Minute. The gas-phase hydrocarbon stream 1 is separated into low-pressure carbon five and lighter components 2 and carbon six and heavier components 12 in the pre-separation tower T1. The low-pressure carbon five and lighter component 2 are pressurized to 2 MPa through compressor C1 to obtain high-pressure carbon five and lighter component 3 and then sent to the desorption tower T2. In the desorption tower, 70.5% by mass of the carbon tricomponent is extracted from the bottom of the tower to obt...

Embodiment 2

[0034] The same process flow as in Example 1 was adopted. In the methanol-to-propylene reactor, it is converted into propylene as the main reaction product, and the gaseous hydrocarbon stream 1 is obtained after dehydration and acid gas carbon dioxide. Gas-phase hydrocarbon stream 1 has a temperature of 43°C, a pressure of 0.12 MPa, and a molar composition of 22.3% carbon one to carbon two components, 46.4% carbon three components, 24.3% carbon four carbon five components, 7.0% carbon six and more Minute. The gas-phase hydrocarbon stream 1 is pressurized to 0.55 MPa by a compressor, and then separated into low-pressure C5 and lighter components 2 and C6 and heavier components 12 in the pre-separation tower T1. The low-pressure carbon five and lighter component 2 are pressurized to 1.5 MPa through compressor C1 to obtain high-pressure carbon five and lighter component 3 and then sent to the desorption tower T2. In the desorption tower, 72.7% of the carbon tri-component is extr...

Embodiment 3

[0037] The same process flow as in Example 1 was adopted. Dimethyl ether is converted into propylene as the main reaction product in the dimethyl ether to propylene reactor, and the gas phase hydrocarbon stream 1 is obtained after dehydration and acid gas carbon dioxide. Gas-phase hydrocarbon stream 1 has a temperature of 43°C, a pressure of 0.14 MPa, and a molar composition of 21.5% carbon one to carbon two components, 46.9% carbon three components, 25.4% carbon four carbon five components, 6.2% carbon six and more. Minute. The gas-phase hydrocarbon stream 1 is separated into low-pressure carbon five and lighter components 2 and carbon six and heavier components 12 in the pre-separation tower T1. The low-pressure carbon five and lighter component 2 are pressurized to 1.7 MPa through compressor C1 to obtain high-pressure carbon five and lighter component 3 and then sent to the desorption tower T2. In the desorption tower, 72.9% of the carbon tri-component by mass is extracted...

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Abstract

The invention relates to a method for separating propylene products prepared by alcohol and / or ether and is intended to mainly solve the problem that the preparation process of the propylene products prepared by alcohol and / or ether in the prior art has high energy consumption. The method comprises the steps of removing water and acidic gas from a product from an outlet of a reactor for propylene production by alcohol and / or ether to obtain a mixed hydrocarbon product; feeding the mixed hydrocarbon product into a pre-separation column to remove C6 and heavier components to obtain C5 and lighter components; pressurizing the C5 and lighter components, feeding to an absorption-desorption system, and acquiring absorbed tail gas, C3 component, and C4 and C5 components by separating; separating the C3 component into propylene and propane; returning at least part of the absorbed tail gas to the reactor for propylene products prepared by alcohol and / or ether; by using the above technical scheme, the above problem is well solved; the method is applicable to the industrial production of propylene products prepared by alcohol and / or ether.

Description

Technical field [0001] The invention relates to a method for separating propylene products from alcohol and / or ether. technical background [0002] Propylene is a basic organic chemical raw material with great demand, mainly from the petroleum processing process. With the increasing shortage of petroleum resources, the development of technologies for preparing propylene from non-petroleum resources such as coal or natural gas has attracted more and more attention at home and abroad. Propylene from coal usually adopts the process route of syngas from coal, methanol from syngas, and propylene from methanol. Among them, coal-to-syngas and methanol-to-syngas technology have been very mature. Methanol to propylene technology has been industrialized after years of development. However, due to the complex composition of methanol-to-propylene products, the products include carbon one to carbon seven or even heavier components, and the problems of long process flow and high energy cons...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07C7/11C07C7/04C07C7/00C07C6/04C07C11/04C07C11/06C07C9/08
Inventor 金鑫胡帅
Owner CHINA PETROLEUM & CHEM CORP