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Solvent-free epoxy coating material and preparation method thereof

An epoxy coating, solvent-free technology, applied in the field of coatings, can solve the problems of pits, pinholes, orange peels on the surface of the coating, the thickness of the coating film easily exceeding 120um, and poor storage stability of the operational coating. Provides smoothness and gloss, provides high temperature resistance, and improves flow time

Active Publication Date: 2017-04-05
BC P INC CHINA NAT PETROLEUM CORP +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The disadvantages of solvent-based coatings are: high VOC content, sensitivity to moisture in the environment, poor construction operability and paint storage stability, and easy foaming of the paint film. More importantly, solvent-based coatings are usually not environmentally friendly.
However, solvent-free coatings also have disadvantages. The more prominent one is that the coating has a high viscosity, which is not very convenient for construction, and the coating needs to be heated when spraying; due to the high viscosity, it is difficult to obtain a thinner coating, which is often suitable for thick coating.
When spraying, the thickness of the coating film is likely to exceed 120um, resulting in waste. When the thickness of the coating film is less than 100um, defects such as pits, pinholes, and orange peel are likely to appear on the surface of the coating

Method used

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  • Solvent-free epoxy coating material and preparation method thereof

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preparation example Construction

[0091] The preparation method of the solvent-free epoxy coating of the embodiment of the present invention, described method comprises the following steps:

[0092] After mixing bisphenol F resin, bisphenol A epoxy resin E51, liquid petroleum resin and isomeric glycidyl carboxylate, add anti-wear agent, dispersant, defoamer, first slip agent, second slip agent Cooling agent, defoamer and anti-sedimentation thixotropic agent are mixed evenly, dispersed, and ground to make the first component of the coating;

[0093] The second component of the coating is prepared by mixing phenolic modified fatty amine, allylphenol modified cycloaliphatic amine, modified polyurea and dispersant evenly, adding iron oxide red and anti-corrosion filler, mixing, stirring and grinding;

[0094] The first component and the second component are mixed and stirred uniformly to obtain the solvent-free epoxy coating.

[0095] In the solvent-free epoxy coating, the mass ratio of the first component to the...

Embodiment 1

[0099] The preparation method of the embodiment of the present invention 1 solvent-free epoxy paint comprises the following steps:

[0100] In a stainless steel bucket, 1 part by weight of bisphenol F resin, 0.9 part by weight of bisphenol A epoxy resin E51, 0.18 part by weight of liquid petroleum resin, and 0.2 parts by weight of isomeric glycidyl carboxylate are mixed together, and then add 0.12 Parts by weight of quartz powder, 0.3 parts by weight of alumina powder, 0.15 parts by weight of fluorine-modified polyacrylate, 0.06 parts by weight of fluorine-modified silicone, 0.04 parts by weight of silicone-modified polyorganosiloxane, 0.07 parts by weight of fluorocarbon modified Non-toxic polymer, 0.08 parts by weight of silicone modified polymer carboxylic acid, 0.016 parts of polyamide wax, etc. are mixed evenly and dispersed at a high speed. Components: 1 weight part of phenolic modified aliphatic amine, 1.2 weight part of allylphenol modified alicyclic amine, 0.015 weigh...

Embodiment 2

[0103] The preparation method of the embodiment of the present invention 2 solvent-free epoxy coatings comprises the following steps:

[0104] In a stainless steel bucket, 1 part by weight of bisphenol F resin, 0.95 parts by weight of bisphenol A epoxy resin E51, 0.16 parts by weight of liquid petroleum resin, and 0.18 parts by weight of isomeric glycidyl carboxylate are mixed together, and then add 0.15 Parts by weight of quartz powder, 0.25 parts by weight of alumina powder, 0.16 parts by weight of fluorine-modified polyacrylate, 0.08 parts by weight of fluorine-modified silicone, 0.08 parts by weight of silicone-modified polyorganosiloxane, 0.06 parts by weight of fluorocarbon modified Non-toxic polymer, 0.09 parts by weight of silicone modified polymer carboxylic acid, 0.018 parts of polyamide wax, etc. are mixed evenly, dispersed at high speed, and the temperature reaches 50-60 ° C. Keep this temperature range and continue to disperse for more than 50 minutes. Grind to mak...

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Abstract

The invention provides a solvent-free epoxy coating material and a preparation method thereof. The solvent-free epoxy coating material comprises a first component and a second component, wherein the first component comprises the following components in parts by weight: 1 part of bisphenol F resin, 0.8-1.0 part of bisphenol A epoxy resin E51, 0.1-0.2 part of liquid petroleum resin, 0.15-0.3 part of isomerous monocarboxylic acid glycidyl ester, 0.2-0.7 part of an anti-wear agent, 0.1-0.3 part of a dispersant, 0.02-0.1 part of an air-release agent, 0.01-0.1 part of a first slip agent, 0.05-0.1 part of a second slip agent, 0.05-0.1 part of a defoaming agent and 0.01-0.02 part of an anti-settling thixotropic agent; and the second component comprises the following components in parts by weight: 1 part of phenolic aldehyde modified aliphatic amine, 0. 8-1.2 parts of allylphenol modified alicyclic amine, 0.015-0.03 part of modified polyurea, 0.01-0.03 part of a dispersant, 0.1-0.3 part of iron oxide red and 0.15-0.35 part of anti-corrosion packing. A coating formed by the solvent-free epoxy coating material has an excellent thin-coating property, the one-step film-forming thickness of the solvent-free epoxy coating material can be equal to or less than 100 mu m, and the coating has high apparent quality.

Description

technical field [0001] The invention belongs to the technical field of coatings, in particular to a solvent-free epoxy coating and a preparation method thereof. Background technique [0002] In order to ensure the anti-rust and anti-corrosion of pipelines such as oil and natural gas transportation and reduce the transmission resistance of fluids in pipelines, special coatings are usually used; the research on drag reduction technology of internal coatings in pipelines began in the early 20th century and was widely used in long-distance transportation. Natural gas pipelines are in the 1950s. After decades of application development, the coating production and construction technology of pipeline inner coating is becoming more and more mature. In European and American countries with relatively advanced natural gas pipeline transportation technology, pipeline inner coating drag reduction technology has been widely used. Many large-diameter and long-distance natural gas pipelin...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D163/00C09D5/08C09D7/12C09D7/06C09D7/47
CPCC08L2201/08C08L2205/025C08L2205/035C09D5/084C09D5/18C09D7/47C09D7/61C09D7/65C09D163/00C08L63/00C08L57/02C08L33/08C08L83/04C08L77/00C08K13/02C08K3/36C08K2003/2227C08K3/34C08K2003/2272
Inventor 段绍明林竹郭晓军崔灿灿丁超王磊何鱼游韩忠智刘浩亮刘杨宇尹晓琳李石
Owner BC P INC CHINA NAT PETROLEUM CORP
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