Carboxyethyl chitosan sponge dressing and preparation method thereof
A technology of carboxyethyl chitosan sponge and carboxyethyl chitosan, applied in medical science, bandages, absorbent pads, etc., can solve problems affecting wound healing, human tissue damage, user pain, etc. Large-scale popularization and application, large absorption and good biocompatibility
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Embodiment 1
[0034] Take by weighing carboxyethyl chitosan (prepared with reference to the following documents: Hitoshi Sashiwa, et al. acrylic acid in water.Macromol.Biosci.2003, 3, 231-233) 1g, put in 100ml water, stir and dissolve at room temperature, freeze at -80°C for 50 hours, then vacuum at -40°C, 5pa Dry for 12 hours to obtain a thickness of 0.1mm and a density of 0.016g / cm 3 carboxyethyl chitosan sponge. Place it in the reaction chamber of a plasma treatment instrument (plasma surface treatment instrument, GSL1100X-PJF, Hefei Kejing Material Technology Co., Ltd.) for glow discharge treatment, the working gas is nitrogen, the reaction chamber pressure is 20pa, and the processing power is 10w. The treatment time is 15s. After the treatment is completed, it is placed in an oven for 1 hour at a temperature of 50 degrees Celsius and a humidity of 20% to obtain a carboxyethyl chitosan sponge dressing 1 .
Embodiment 2
[0036]Take by weighing the carboxyethyl chitosan (prepared with reference to the following documents: Y.Wu, et al.Preparation of O-carboxymethyl chitosans and their effect on the viscosity-average molecular weight at 1000000Da, 6-position O-carboxyethyl molar substitution degree at 0.5) Color yield of acid dyes on silk.J.Appl.Polym.Sci.2003, 90, 2500-2502) 5g, put in 100ml water, stir and dissolve at room temperature, freeze at -20°C for 10 hours, and then put in - Vacuum drying at 40 degrees and 300pa for 24 hours to obtain a thickness of 5mm and a density of 0.025g / cm 3 carboxyethyl chitosan sponge. Place it in the reaction chamber of a plasma treatment instrument (plasma surface treatment instrument, GSL1100X-PJF, Hefei Kejing Material Technology Co., Ltd.) for glow discharge treatment, the working gas is nitrogen, the reaction chamber pressure is 50pa, and the processing power is 50w. The treatment time is 30s. After the treatment is completed, it is placed in an oven for...
Embodiment 3
[0038] Take by weighing viscosity average molecular weight at 2000000Da, 2-N-, the carboxyethyl chitosan of 6-O-molar degree of substitution at 0.8 (preparation with reference to following literature: Sun Shengling, Wang Aiqin. N, O-carboxyethyl chitosan Adsorption properties of the synthesis of metal ions, Polymer Materials Science and Engineering, 2006, 22(3), 25-29) 10g, placed in 100ml of water, stirred and dissolved at room temperature, placed in -40 ℃ low temperature for 24 hours, Then vacuum dry for 48 hours under the conditions of -40 degrees and 30pa to obtain a thickness of 10mm and a density of 0.032g / cm 3 carboxyethyl chitosan sponge. Put it in the reaction chamber of the plasma processing instrument (plasma surface treatment instrument, GSL1100X-PJF, Hefei Kejing Material Technology Co., Ltd.) for glow discharge treatment, the working gas is nitrogen, the pressure of the reaction chamber is 100pa, and the processing power is 100w , the treatment time is 60s, and ...
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