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Modified polypropylene composite material and preparation method thereof

A composite material, polypropylene technology, used in flat products, other home appliances, applications, etc., can solve the problems of low strength and other properties, affecting the scope of application, short service life, etc., to improve mechanical properties, stable structure, and service life. long effect

Inactive Publication Date: 2017-05-10
蒋建华
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, there have been some research, development and patent literature reports on graphite-modified polypropylene materials. As a new material research and exploration and new product development, graphite-modified polypropylene tubular reactors have been successfully used to replace glass-lined reactors. , and research and development of graphite-modified polypropylene as chemical reaction trays, heat exchangers, radiators, etc., but only graphite is used as a modifier in these materials to improve the heat transfer and electrical conductivity of polypropylene. The strength and other properties of the filter plate material are obviously low, and the research and application of new graphene-modified reinforced polypropylene materials required for the filter press plate is still blank, resulting in the current polypropylene material in heat resistance, resistance Corrosion and high pressure resistance have high requirements, and its performance is obviously insufficient in the separation of waste liquid or raw material solid hydraulic filtration, which affects its application range. At the same time, its service life is short and the cost is also greatly increased.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] (1) Ingredients: Weigh the raw materials of each component according to the following mass: 13g graphene powder, 68g polypropylene, 15g glass fiber, 2.8g PP-g-MAH phase solvent, 1.2g maleic anhydride phase solvent, 2.4g organic chromium complex compound, 0.6g zirconate, 3g phosphite;

[0028] (2) Surface treatment is performed on the graphene powder and glass fiber first, and the graphene powder is put into the high-speed mixer when it reaches 80°C for thermal stirring. The thermal stirring time is 15 minutes, and the arrival time and the temperature of the graphene powder reaches 95°C Throw in the organic chromium complex and heat it together, and at the same time, the temperature of the graphene powder dropped into the organic chromium complex is raised to 110° C., and the graphene powder is heated at 110° C. and stirred for 12 minutes to carry out surface treatment and discharge; then The dried glass fiber is wetted with maleic anhydride phase solvent and zirconate, ...

Embodiment 2

[0033] (1) Ingredients: Weigh the raw materials of each component according to the following mass: 5g graphene powder, 84g polypropylene, 20g glass fiber, 7.4gPP-g-MAH phase solvent, 0.6g maleic anhydride phase solvent, 1.0g organic chromium complex compound, 1.0g zirconate, 3g phosphite.

[0034] (2) Surface treatment is performed on the graphene powder and glass fiber first, and the graphene powder is put into the high-speed mixer when it reaches 85°C for thermal stirring. The thermal stirring time is 20 minutes, the arrival time and the temperature of the graphene powder reaches 90°C Throw in the organic chromium complex and heat it together, and at the same time, the temperature of the graphene powder dropped into the organic chromium complex is raised to 120° C., and the graphene powder is heated at 120° C. for 10 minutes for surface treatment and then discharged; The dried glass fiber is wetted with maleic anhydride phase solvent and zirconate, and dried under hot air ci...

Embodiment 3

[0039] (1) Ingredients: Weigh the raw materials of each component according to the following mass: 20g graphene powder, 52g polypropylene, 10g glass fiber, 1.4g phase solvent, 0.6g maleic anhydride phase solvent, 3.6g organic chromium complex, 0.4 g zirconate, 1 g phosphite.

[0040] (2) Surface treatment is performed on the graphene powder and glass fiber first, and the graphene powder is put into the high-speed mixer when it reaches 90°C for thermal stirring. The thermal stirring time is 20 minutes, and the arrival time and the temperature of the graphene powder reaches 100°C Throw in the organic chromium complex and heat it together while stirring, and simultaneously raise the temperature of the graphene powder dropped into the organic chromium complex to 120° C., make the graphene powder heat and stir at 120° C. for 15 minutes to carry out surface treatment and then discharge; The dried glass fiber is wetted with maleic anhydride phase solvent and zirconate, and dried unde...

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Abstract

The invention relates to a modified polypropylene composite material and a preparation method thereof. The modified polypropylene composite material is prepared from the following ingredients in parts by mass: 50 to 80 parts of polypropylene, 5 to 20 parts of graphene powder, 8 to 20 parts of glass fiber, 1 to 2.2 parts of organic complexes, 0.4 to 7.4 parts of unsaturated carboxylic acid and polypropylene graft solvents, 0.6 to 1.6 parts of maleic anhydride solvents, 1 to 1.8 parts of stannate ester and 1 to 4 parts of phosphite ester. According to the preparation method of the modified polypropylene composite materia, the graphene powder and the glass fiber are subjected to surface treatment; then, the polypropylene, the unsaturated carboxylic acid and polypropylene graft solvents, the phosphite ester and the surface treated graphene powder are subjected to high-speed mixing to form a graphite / PP mixed material; then, the graphite / PP mixed material and the dried glass fiber are extruded to obtain the graphene modified enhanced PP particles; drying is performed; the graphene modified enhanced PP particles are subjected to extrusion, material melting, pressing and processing forming. The modified polypropylene composite material has the advantages that the heat-resistant and pressure-resistant performance of a plate material is excellent.

Description

technical field [0001] The invention relates to the field of polypropylene composite material manufacturing, in particular to a high-temperature-resistant, pressure-resistant and corrosion-resistant polypropylene composite material that can be widely used in chemical industry, environmental protection, metallurgy and other industries and a preparation method thereof. Background technique [0002] Now commonly used filter press plate materials are composed of polypropylene and its calcium carbonate, talcum powder or glass fiber, etc., which are obviously not adaptable to high temperature and solid-liquid separation with strong chemical corrosion resistance in the chemical industry and other industries. Disadvantages such as high cost and short service life. In response to this situation, the country began to study new polypropylene composite materials as filter press plate materials. Compared with other mineral-based materials, graphene materials have excellent heat resistanc...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/12C08L51/06C08K13/06C08K9/04C08K7/14C08K3/04C08K5/524B29C69/02B29B9/06B29B13/06B29C47/92B29L7/00B29K23/00B29C48/92
CPCC08L23/12B29B9/06B29B13/065B29C48/0011B29C48/92B29C2948/92514B29C2948/92561B29C2948/92704B29K2023/12B29L2007/002C08L2201/08C08L51/06C08K13/06C08K9/04C08K7/14C08K3/04C08K5/524
Inventor 蒋建华
Owner 蒋建华
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