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Special magnesian clay crosslinking suspending agent for liquid fertilizer and preparation method thereof

A technology of magnesia clay and suspending agent, applied in liquid fertilizer, application, fertilization equipment, etc., can solve the problems of short storage time, high cost, large proportion of cellulose, etc., achieve good compatibility and stability, overcome The effect of short suspension time and strong fertilizer storage

Inactive Publication Date: 2017-06-13
CHENDU NEW KELI CHEM SCI CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The storage and transportation of liquid fertilizers must use specific containers and transportation vehicles, which are expensive and require the preparation of special application tools, etc.
At the same time, under the previous conditions, it is only suitable for on-site production and application, and the procurement cost is generally higher than that of solid fertilizers. Some products or mixtures may have salting-out or precipitation, which are all constraints on the development of liquid fertilizers.
[0004] In solving the layering problem of liquid fertilizers, the United States mainly adopts adding a part of colloidal clay minerals, such as bentonite, white clay, attapulgite, sepiolite, etc., with an amount of about 1% to 2%, and making the suspension at 28°C When the viscosity is controlled in the range of 300-700mPa·s, this method is applied to high-concentration liquid fertilizer and compound fertilizer for a short period of time, and the fertilizer must be used up in a short period of time (15 days), and stratified agglomeration will occur if it is placed for a long time; , mainly by adding high-viscosity and high-molecular-weight cellulose substances, such as the patent 200910192150.6 suspension type liquid compound fertilizer and its preparation method, adding 4-12% hydroxyethyl cellulose to increase the viscosity of the suspension. This method adds The proportion of cellulose is relatively large, and the cost is too high

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] (1) Heat 80 parts by weight of high-magnesia clay with a magnesium oxide content greater than 18% to 350°C, and rapidly cool and expand it in a completely dispersed state through air spray and spray deionized cold water to make the magnesia clay fluffy;

[0023] (2) Under stirring conditions, disperse the fluffy magnesia clay in step (1) and 0.05 parts by weight of crosslinking auxiliary trimethylolpropane triacrylate in deionized water, and the deionized water and magnesia clay The mass ratio of the mixture is 2:1, and 0.1 weight part of glycerin is added as a surfactant, and the stirring is continued for 10 minutes to obtain a mixed solution;

[0024] (3) Add 0.05 parts by weight of initiator azobisisobutyronitrile and 4 parts by weight of melamine to the mixed solution obtained in step (2), heat up to 60-80°C, and stir for 20-60 minutes; Fluffy magnesia clay cross-linked with melamine under action;

[0025] (4) Adjust the viscosity of the cross-linked product obtain...

Embodiment 2

[0027] (1) Heat 90 parts by weight of rod-shaped high-magnesium clay to 400°C, and rapidly cool and expand it in a completely dispersed state through air spray and spray deionized cold water to make the magnesia clay fluffy;

[0028] (2) Under stirring conditions, disperse the fluffy magnesia clay in step (1) and 0.1 parts by weight of crosslinking auxiliary trimethylolpropane triacrylate in deionized water, and the deionized water and magnesia clay The mass ratio is 3:1, and 0.5 parts by weight of isomeric alcohol polyoxyethylene ether is added as a surfactant, and the stirring is continued for 20 minutes to obtain a mixed solution;

[0029] (3) Add 0.05 parts by weight of initiator azobisisobutyronitrile and 5 parts by weight of melamine to the mixed solution obtained in step (2), raise the temperature to 60-80°C, and stir for 60 minutes; fluffy magnesia clay cross-linked with melamine;

[0030](4) Adjust the viscosity of the cross-linked product obtained in step (3) to 0.1...

Embodiment 3

[0032] (1) Heating 85 parts by weight of high-magnesium clay with a particle size of less than 10 microns to 500°C, and rapidly cooling and puffing the magnesia clay in a completely dispersed state through air spraying and spraying deionized cold water colliding, so that the magnesia clay forms a fluffy shape;

[0033] (2) Under stirring conditions, disperse the fluffy magnesia clay in step (1) and 0.15 parts by weight of crosslinking auxiliary trimethylolpropane triacrylate in deionized water, and the deionized water and magnesia clay The mass ratio of the mixture is 4:1, and the cocamide betaine of 0.3 parts by weight is added as a surfactant, and the stirring is continued for 30min to obtain a mixed solution;

[0034] (3) Add 0.1 parts by weight of initiator benzoyl peroxide and 7 parts by weight of melamine to the mixed solution obtained in step (2), heat up to 60-80°C, stir and react for 30 minutes; fluffy under the action of crosslinking auxiliary agent Magnesia clay cro...

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Abstract

The invention belongs to the technical field of fertilizer production and specifically relates to a special magnesian clay crosslinking suspending agent for a liquid fertilizer and a preparation method thereof. The special magnesian clay crosslinking suspending agent for a liquid fertilizer is prepared from the following raw materials (by weight): 80-90 parts of magnesian clay, 2-8 parts of melamine, 0.01-0.2 part of a crosslinking adjuvant, 0.05-0.5 part of an initiator, and 0.1-0.8 part of a surfactant. Through high-temperature collision dispersion and quenching of the magnesian clay with high magnesium content, the magnesian clay becomes fluffy and light; and under the action of the crosslinking adjuvant, the magnesian clay and melamine are cross-linked to form a light porous magnesian clay crosslinking suspending agent. The suspending agent is used in a liquid fertilizer, can rapidly absorb water to be expanded to form gel and has good compatibility and stability in water. On one hand, a liquid fertilizer can be suspended due to the thickening effect; and on the other hand, the product will not settle and prevents segregability in water. Defects such as short suspension time and easy layering of traditional clay in a liquid suspension fertilizer are overcome.

Description

technical field [0001] The invention belongs to the technical field of fertilizer production, and in particular relates to a special magnesia clay cross-linked suspending agent for liquid fertilizer and a preparation method. Background technique [0002] Liquid fertilizer, also known as fluid fertilizer, commonly known as liquid fertilizer, is a liquid product of one or more nutrients required by crops, generally with the theme of N, P, K or one of the three major nutrients. Also often includes the need for micronutrients. The development of liquid fertilizers has a history of more than 200 years, and there are many varieties, which can be roughly divided into two categories: liquid nitrogen fertilizers and liquid compound fertilizers. Liquid nitrogen fertilizers include ammonium, nitrate and amide nitrogen, such as liquid ammonia, ammonia water, ammonium nitrate and ammonia, urea and ammonia, etc. Liquid compound fertilizer contains two or three nutrients in N, P and K, s...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C05G3/00
CPCC05G3/00C05G5/20
Inventor 陈庆曾军堂王镭迪
Owner CHENDU NEW KELI CHEM SCI CO LTD
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