A kind of antiskid rubber sole and preparation method thereof

A kind of anti-skid rubber and anti-skid technology, applied in the direction of soles, footwear, other household appliances, etc., can solve the problems of lack of stable manufacturers, difficult industrial production, complex nature, etc., to improve the anti-skid performance of soles, good wear resistance, Good material processing performance

Active Publication Date: 2018-10-02
MAOTAI FUJIAN SOLES CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Therefore, the oil-slip resistance of rubber soles is different from the wet-slip resistance, and its properties are more complex.
[0003] The patent application number 2016110269846 discloses a rubber sole for oil-resistant safety shoes and its preparation method. According to the test of 5.3.5.3 in BS EN ISO 20345: 2011, the friction coefficient is as high as 0.5, and the anti-oil effect is remarkable, but it is not mass-produced The high-vinyl solution polystyrene-butadiene rubber has excellent sample performance, but there is no stable manufacturer and the price is expensive, so it is difficult to industrialize the rubber sole of this anti-oil safety shoe

Method used

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  • A kind of antiskid rubber sole and preparation method thereof
  • A kind of antiskid rubber sole and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0063] In the present embodiment, a kind of preparation method of antiskid rubber sole is characterized in that, comprises the steps:

[0064] Step (1): Prepare the anti-slip premixed rubber, 61 parts by weight of NBR / PVC emulsion co-precipitation alloy 3330G, 35 parts of low melting point polyamide (DSC melting temperature 110 ° C), compatibilizer styrene-maleic anhydride 4 parts of copolymer, kneaded on a two-roll mill, and then uniformly released into sheets to obtain anti-skid premixed rubber;

[0065] Step (2): Prepare a non-slip rubber sheet, which is prepared from the following components in the following parts by weight:

[0066] Non-slip premixed glue 40 parts

[0067] Natural rubber 3L 20 parts

[0068] Solution polystyrene butadiene rubber T2000R 22 parts

[0069] Bromobutyl rubber 2030 8 parts

[0070] Silica 20 parts

[0071] Antiager 1010 0.7 parts

[0072] Polyethylene glycol PEG4000 1.6 parts

[0073] Silane coupling agent Si 69 1.5 parts

[0074] Polye...

Embodiment 2

[0085] In the present embodiment, the preparation method of a kind of non-slip rubber sole is basically the same as the preparation method in Example 1, the difference is:

[0086] In step (1): the DSC melting temperature of the low melting point polyamide is 80°C.

[0087] In step (2): 25 parts of styrene-butadiene rubber are dissolved in solution, and the degumming temperature is 110°C.

[0088] In step (3): the deflation time is 4 seconds, the descending time is 4 seconds, the deflation times are 3 times, the pressure is 16.5 MPa, and the vulcanization time is 210 seconds.

[0089] A kind of non-slip rubber sole prepared above, density 1.13g / cm 3 , Hardness 54A, dry friction coefficient 0.95, wet friction coefficient 0.85, SRA friction coefficient 0.44, SRB friction coefficient 0.51.

Embodiment 3

[0091] In the present embodiment, the preparation method of a kind of non-slip rubber sole is basically the same as the preparation method in Example 1, the difference is:

[0092] In step (1): 40% (mass ratio) of PVC content in the NBR / PVC emulsion co-precipitation alloy, 41% (mass ratio) of the acrylonitrile content of NBR in the NBR / PVC emulsion co-precipitation alloy; DSC melting of low melting point polyamide The temperature is 100°C.

[0093] In step (2): 18 parts of natural rubber and 23 parts of solution-polymerized styrene-butadiene rubber.

[0094] In step (3): the deflation time is 5 seconds, and the descending time is 5 seconds.

[0095] A kind of non-slip rubber sole prepared above, density 1.10g / cm 3 , Hardness 56A, dry friction coefficient 0.94, wet friction coefficient 0.83, SRA friction coefficient 0.47, SRB friction coefficient 0.53.

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Abstract

The invention relates to a rubber sole, and provides an anti-skid rubber sole. The anti-skid rubber sole is prepared from the following raw materials: NBR / PVC emulsion co-precipitation alloy, low-melting point polyamide, natural rubber, soluble polymerized styrene-butadiene rubber, brominated butyl rubber, white carbon black, an anti-aging agent, polyethylene glycol, a silane coupling agent, polyethylene wax, diethylene glycol, zinc oxide, stearic acid, insoluble sulfur, a vulcanization accelerator D and a vulcanization accelerator DM. The anti-skid rubber sole is vulcanized and molded in a mold of a space aluminum material, the vulcanizing temperature is 170 DEG C, the pressure is 16.5MPa-17.5MPa, and the vulcanizing time is 210-250s.

Description

technical field [0001] The invention belongs to the technical field of organic polymer compounds, in particular to an anti-slip rubber sole and a preparation method thereof. Background technique [0002] The friction between rubber soles and building ground and other materials is a very complex process, and the influencing factors include normal load, contact area, static contact time, sliding speed, rubber hardness, surface roughness, viscoelasticity, temperature, surface dry and wet pollution The influence of these factors on the friction coefficient is not isolated, but interrelated. Therefore, the coefficient of friction is not an inherent characteristic of the material, but a comprehensive characteristic of the material and conditions. In accordance with the requirements of BS EN ISO 20345: 2011, SATRA TM144:2011, ASTM F2913-11 and other test standards, when using the principle of horizontal drag for anti-skid test, pollutants (water, washing liquid, oil, etc.) are on ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L9/04C08L27/06C08L77/00C08L7/00C08L9/06C08L71/02C08K13/02C08K5/06C08K3/36C08K3/22C08K5/09A43B13/04B29C33/38B29C35/02B29L31/50
CPCA43B13/04B29C33/38B29C35/02B29L2031/504C08L9/04C08L2205/035C08L27/06C08L77/00C08L7/00C08L9/06C08L71/02C08K13/02C08K5/06C08K3/36C08K2003/2296C08K5/09
Inventor 卢鑫王育玲罗显发郑荣大丁思博廖毅彬金校红
Owner MAOTAI FUJIAN SOLES CO LTD
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