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Feed grade monocalcium phosphate and preparation method thereof

A calcium dihydrogen phosphate, feed-grade technology, applied in chemical instruments and methods, phosphorus compounds, inorganic chemistry, etc., can solve the problems of large equipment, small production capacity, large power consumption, etc., and achieve broad market prospects and production speed. The effect of fast and reduced production time

Inactive Publication Date: 2017-06-16
贵州越都化工有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Among them, the wet process is to add solid raw materials to the phosphoric acid solution prepared by the wet process to generate calcium dihydrogen phosphate dissolved in water. After vacuum concentration, cooling and crystallization, calcium dihydrogen phosphate crystals are precipitated, and then dried, crushed and sieved To obtain the product, the method has long technological process, large phosphorus loss, high energy consumption, large investment, small production capacity, and high cost.
The dry process is to use the phosphoric acid produced by the thermal method to react with solid materials such as CaCO3 to obtain the calcium dihydrogen phosphate slurry, and then obtain the product through drying, crushing, and screening. This method has the disadvantages of large equipment volume, small particle size, and power Insufficient consumption
Therefore, in the prior art, there are generally characteristics such as long process flow, high energy consumption, large investment and low productivity.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0039] A kind of feed grade calcium dihydrogen phosphate, by weight, by 20-30 parts of phosphate rock, 5-15 parts of calcium hydroxide, 5-15 parts of calcium carbonate, 5-15 parts of sulfuric acid, 5-15 parts of industrial waste acid, Activated carbon particles consist of 2-6 parts.

[0040] Described feed grade calcium dihydrogen phosphate and preparation method thereof comprise the following steps:

[0041] (1) Mixing sulfuric acid and waste acid to prepare mixed acid A;

[0042] (2) Mix and react the prepared mixed acid A with phosphate rock, heat and stir for 2-6 hours to obtain phosphoric acid solution B;

[0043] (3) Add activated carbon particles, calcium hydroxide, and 2-4kg of water to the prepared phosphoric acid solution B to defluorinate and remove impurities, and let it stand for 3-5 hours to obtain a clean phosphoric acid solution C;

[0044] (4) Neutralize calcium carbonate with the prepared phosphoric acid solution C, heat to concentrate, filter, wash, and dr...

Embodiment 2

[0046] A feed grade calcium dihydrogen phosphate is composed of 25 parts of phosphate rock, 10 parts of calcium hydroxide, 10 parts of calcium carbonate, 10 parts of sulfuric acid, 10 parts of industrial waste acid and 4 parts of activated carbon particles by weight.

[0047] (1) Mixing sulfuric acid and waste acid to prepare mixed acid A;

[0048] (2) Mix and react the prepared mixed acid A with phosphate rock, heat and stir for 4 hours to obtain phosphoric acid solution B;

[0049] (3) Add activated carbon particles, calcium hydroxide, and 3kg of water to the prepared phosphoric acid solution B to defluorinate and remove impurities, and let it stand for 4 hours to obtain a clean phosphoric acid solution C;

[0050] (4) Neutralize calcium carbonate with the prepared phosphoric acid solution C, heat, concentrate, filter, wash, and dry to obtain the product.

Embodiment 3

[0052] A feed grade calcium dihydrogen phosphate consists of 20 parts by weight of phosphate rock, 5 parts of calcium hydroxide, 5 parts of calcium carbonate, 5 parts of sulfuric acid, 5 parts of industrial waste acid and 2 parts of activated carbon granules.

[0053] (1) Mixing sulfuric acid and waste acid to prepare mixed acid A;

[0054] (2) Mix the prepared mixed acid A with phosphate rock, heat and stir for 2 hours to obtain phosphoric acid solution B;

[0055] (3) Add activated carbon particles, calcium hydroxide, and 2kg of water to the prepared phosphoric acid solution B to defluorinate and remove impurities, and let it stand for 3 hours to obtain a clean phosphoric acid solution C;

[0056] (4) Neutralize calcium carbonate with the prepared phosphoric acid solution C, heat, concentrate, filter, wash, and dry to obtain the product.

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PUM

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Abstract

The invention discloses a feed grade monocalcium phosphate, which comprises the following components by weight: 20-30 parts of phosphate rock, 5-15 parts of calcium hydroxide, 5-15 parts of calcium carbonate, 5-15 parts of sulfuric acid, 5-15 parts of industrial waste acid, and 2-6 parts of activated carbon particles. The method provided by the invention has the advantages of simple process, easy implementation, wide raw material sources, shortened production time, low energy consumption and low cost, is suitable for large-scale industrialized production, and has broad market prospects and good social and economic benefits.

Description

technical field [0001] The invention relates to feed grade calcium dihydrogen phosphate and a preparation method thereof, belonging to the technical field of feed additive production. Background technique [0002] The main varieties of feed grade calcium phosphate salts are tricalcium phosphate, calcium hydrogen phosphate, and calcium dihydrogen phosphate, all of which are nutritional additives of mineral elements. Among them, calcium dihydrogen phosphate (MCP) is an excellent high-efficiency phosphate feed additive with high phosphorus content and high water solubility, and is widely used as a feed additive for aquaculture animals and livestock and poultry animals. Due to the high water-soluble phosphorus content of calcium dihydrogen phosphate, which accounts for more than 90wt% of total phosphorus, it is beneficial to the absorption of calcium and phosphorus by aquatic animals. The digestion and absorption rate is above 90%, and the excretion is small, which is beneficial...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01B25/32
CPCC01B25/328
Inventor 李昂李勇吴桂清徐光兴刘福祥周德兵邓正军项代福宋运良
Owner 贵州越都化工有限公司
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