Preparation method of high efficient desulfurization and denitration adsorbent

A technology of desulfurization and denitrification and adsorbent, which is applied in the direction of separation methods, chemical instruments and methods, gas treatment, etc., can solve the problems of step-by-step desulfurization and denitrification technology, such as complicated process, large floor area, and high operating cost, and achieve scientific steps and denitrification. High removal efficiency, simple and effective process

Inactive Publication Date: 2017-06-23
营口镁质材料研究院有限公司
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  • Summary
  • Abstract
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  • Application Information

AI Technical Summary

Problems solved by technology

Due to the shortcomings of step-by-step desulfurization and denitrification technology, such as complex process, large floor space, and high operating costs, the desulfurization and denitrification technology with simple development technology, low operating cost, and stable operation has become one of the important directions for the development of coal-fired flue gas treatment technology in the future.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0022] Nano magnesium oxide powder, MgSO 4 ·7H 2 O and Tianjin powder are mixed according to the mass ratio of 75:32:1, adding deionized water as a solvent, mixing and stirring at a temperature of 40°C, and adjusting to a soft state that can be molded; use an extruder for molding processing , Extrude the nano-magnesia adsorbent with a diameter of 2mm thin strips; at 120°C, dry the adsorbent in an oven for 10min, after the adsorbent is dry, cut it into thin strips of 5mm size; heat up and activate in a resistance furnace at 500°C Roast for 3 hours, take it out and cool it at room temperature, and it will be a granular nano-magnesia adsorbent.

[0023] At flue gas temperature 150°C, bed height 5cm, O 2 The content is 7.5%, SO 2 The concentration is about 2000mg / m 3 , NO concentration is about 500mg / m 3 Under the conditions, after continuous treatment for 60min, SO 2 and NO x The removal efficiencies were 98.03% and 85.74%, respectively, and the stability of the adsorbent ...

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Abstract

The invention discloses a preparation method of a high-efficiency desulfurization and denitrification adsorbent. The preparation method includes the following steps: (1) mixing: adding nano-magnesia powder to water as a solvent and mixing (dissolving at 30-50°C) homogeneous MgSO 4 ·7H 2 In the mixed solution of O and Tianjin powder thickener, mix evenly and stir with water to adjust to a moldable soft state; (2) molding: adopt extruder to carry out molding treatment, and extrude thin strips of nano-magnesium oxide adsorbent; (3) drying: at 120°C, dry the adsorbent in an oven for 10 minutes; (4) granulation: after the adsorbent is dried, cut it into thin strips of a certain length; (5) roasting: in a resistance furnace at a certain temperature Raise the temperature to activate roasting, take it out and cool it at room temperature, that is, the granular nano-magnesia adsorbent. The process condition of the invention is simple, the reaction condition is mild, the prepared desulfurization and denitration high-efficiency adsorbent is safe and environment-friendly, the effect is stable and good, and has great market prospect.

Description

technical field [0001] The invention relates to the field of fine chemical industry, in particular to a preparation method of a high-efficiency desulfurization and denitrification adsorbent. Background technique [0002] my country is the world's largest producer and consumer of coal, and coal still accounts for a large proportion of my country's energy structure. According to statistics, about 80% of my country's electric energy, 70% of industrial fuel, 60% of chemical raw materials, 80% Both heating and domestic fuel come from coal. With the rapid development of the global economy, the development and utilization of coal has brought serious pollution to the environment. In particular, coal-fired power plant boilers emit a large amount of sulfur oxides and nitrogen oxides, accounting for about 1% of the total emissions. exacerbated the deterioration of the environment. Among them, atmospheric smoke and dust, acid rain, greenhouse effect and destruction of the ozone layer h...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/04B01J20/30B01D53/02
CPCB01J20/045B01D53/02B01D2253/1124B01D2253/1128B01D2257/302B01D2257/404B01J20/041B01J2220/42B01J2220/4806
Inventor 林宇王福明崔薇薇曾凡东
Owner 营口镁质材料研究院有限公司
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