Neutral hard scale softening agent for three-component compound flooding screw pump well

A ternary compound, screw pump technology, applied in drilling compositions, chemical instruments and methods, etc., can solve the problems of reduced pump efficiency, leakage of screw pumps, enlarged stator and rotor gaps, etc. The effect of improving permeability and improving hydrophilicity

Inactive Publication Date: 2017-07-07
PETROCHINA CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] In the process of oilfield water injection development, the generation of inorganic scale is a common problem encountered in production. Due to the existence of reservoir heterogeneity, the composition of rock minerals in different underground layers and the properties of fluid in the reservoir are different. When the oil well When underground fluids produced from several different formations are mixed in the wellbore or when the temperature and pressure of various fluids and the concentration of scale-forming ions in the fluid change greatly, it is easy to generate inorganic scale, and these scales will adhere to the Pump barrels, rotors, sucker rods and other parts of screw pump wells cause frequent leakage, rod breakage, and reduced pump efficiency in screw pump wells, which seriously affect the production time rate and increase production costs.
[0003] At present, pickling measures are taken to remove scale in ASP flooding oil wells, which has a good scale removal effect on oil wells, but the hydrogen ions in these pickling agents will react quickly with the chrome-plated coating of the screw pump rotor. The chrome-plated coating on the rotor of the screw pump will fall off, and the gap between the stator and the rotor will increase, resulting in a decrease in pump efficiency after pickling and descaling, seriously affecting the recovery efficiency, and even causing the pump to be stuck.

Method used

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  • Neutral hard scale softening agent for three-component compound flooding screw pump well
  • Neutral hard scale softening agent for three-component compound flooding screw pump well

Examples

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Effect test

specific Embodiment approach

[0025] Specific embodiments: the present invention will be further described below in conjunction with examples: it is made up of organic phosphate, organic phosphonate, dispersant, alkali and water, and their weight percent is: organic phosphate 10~40%, organic phosphate 2-10%, dispersant 1-5%, alkali 1-3%, water 50-80%.

[0026] The organic phosphate can be any one of acrylic acid-vinyl alcohol phosphate copolymer, maleic acid-vinyl alcohol phosphate or polyvinyl alcohol phosphate.

[0027] The organic phosphonate can be tetrasodium aminotrimethylene phosphonate, potassium aminotrimethylene phosphate, tetrasodium 2-phosphonic acid butane-1,2,4-tricarboxylic acid or ethylenediamine tetramethylene phosphonic acid Any of the pentasodium.

[0028] The dispersant can be any one of sodium polyacrylate, sodium polymaleate or hydrolyzed polymaleic anhydride.

[0029] Described alkali can be any one in sodium hydroxide, potassium hydroxide, sodium carbonate or potassium carbonate. ...

Embodiment 1

[0035] Embodiment 1: it is made up of acrylic acid-vinyl alcohol phosphate copolymer, tetrasodium aminotrimethylene phosphonate, polysodium maleate, sodium hydroxide, water, and their weight percent is: acrylic acid-vinyl alcohol phosphate copolymer 25%, tetrasodium aminotrimethylene phosphonate 5%, sodium polymaleate 2%, sodium hydroxide 2%, water 66%. This example shows the field test results of neutral hard scale softeners.

[0036] This example is used in the screw pump well C271-SP12 of the second class upper return block in the west area of ​​Daqing Oilfield. The current of the screw pump well rises from 51A to 63A due to scale deposition in this well. The current of the oil well recovers after being treated with a neutral hard scale softener Normally reduced to 52A, the oil well produced normally, and no leakage occurred; it was used in the screw pump well N4-10-P3039 in the upper return block in the eastern part of the South Fourth District of Daqing Oilfield. After the...

Embodiment 2

[0037] Embodiment 2: It is made up of maleic acid-vinyl alcohol phosphate copolymer, 2-phosphonic acid butane-1,2,4-tetrasodium tricarboxylate, sodium polyacrylate, potassium hydroxide, water, their weight The percentages are: maleic acid-vinyl alcohol phosphate copolymer 25%, tetrasodium 2-phosphonic acid butane-1,2,4-tricarboxylate 5%, sodium polyacrylate 2%, potassium hydroxide 3%, water 65%.

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Abstract

The invention belongs to the technical field of oil field chemistry and in particular relates to a neutral hard scale softening agent for a three-component compound flooding screw pump well, aiming at solving the problem that the screw pump well is excessively corroded by a scale cleaning agent so that the screw pump well cannot be washed with acid after scale is formed. The neutral hard scale softening agent is prepared from organic phosphate, organic phosphonate, a dispersant, alkali and water and the content of the components is as follows in percentage by weight: 10 percent to 40 percent of the organic phosphate, 2 percent to 10 percent of the organic phosphonate, 1 percent to 5 percent of the dispersant, 1 percent to 3 percent of the alkali and 50 percent to 80 percent of the water. The neutral hard scale softening agent provided by the invention can be used for scale removal and releasing of the three-component compound flooding screw pump well; the scale of parts including a screw pump rotor and the like is completely softened and fallen off and completely cleaned; the neutral hard scale softening agent has the advantages that the corrosion is low, any injury on a chromium-plated coating of the screw pump rotor is not caused, the coating of the rotor does not fall off, a condition that working is not carried out due to pump leakage is avoided and the production time efficiency of the screw pump well can be effectively ensured and the like.

Description

technical field [0001] The invention belongs to the technical field of oilfield chemistry, in particular to a neutral hard scale softener used in three-element compound flooding screw pump wells. Background technique [0002] In the process of oilfield water injection development, the generation of inorganic scale is a common problem encountered in production. Due to the existence of reservoir heterogeneity, the composition of rock minerals in different underground layers and the properties of fluid in the reservoir are different. When the oil well When underground fluids produced from several different formations are mixed in the wellbore or when the temperature and pressure of various fluids and the concentration of scale-forming ions in the fluid change greatly, it is easy to generate inorganic scale, and these scales will adhere to the Pump barrels, rotors, sucker rods and other parts of screw pump wells cause frequent leakage, rod breakage, and reduced pump efficiency i...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09K8/528
CPCC09K8/528C23F14/02
Inventor 程杰成周万富孔衔霄管公帅韩露黄小会随大伟余瀚森杨海洋王鑫王庆国
Owner PETROCHINA CO LTD
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