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Multivariate highly active component carbon monoxide adsorbent and its preparation method and application

A technology for active components and carbon monoxide, which is applied in the field of multi-active component carbon monoxide adsorbents and their preparation, can solve the problems of short service life, small removal capacity, and low carbon monoxide removal depth, etc., and achieves long service life and removal depth. The effect of high and strong fluctuation ability of carbon monoxide content in raw gas impurities

Active Publication Date: 2020-10-02
大连圣得环保新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to solve the problems of small removal capacity, low carbon monoxide removal depth and short service life of the carbon monoxide adsorbent in the prior art, the present invention provides a carbon monoxide adsorbent with multiple components and high activity

Method used

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  • Multivariate highly active component carbon monoxide adsorbent and its preparation method and application
  • Multivariate highly active component carbon monoxide adsorbent and its preparation method and application

Examples

Experimental program
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Effect test

Embodiment 1

[0028] Weigh Cu(NO 3 ) 2 , Zn(NO 3 ) 2 , Mn(NO 3 ) 2 , Ni(NO 3 ) 2 , Fe(NO 3 ) 3 , As shown in Table 1, stir and dissolve the above substances in 65℃ hot water, pour the mixture into the reaction kettle, and configure an excess of 20% aging agent Na 2 CO 3 The solution was slowly injected into the same reaction kettle for 4h aging reaction, the reaction was controlled at 70℃, pH value 9-10, and then the reacted slurry was centrifuged to make filter cake, and washed (water temperature 70℃) repeated 2 -3 times, until the pH value of the slurry is 6-7, and then the filter cake is dried at low temperature and roasted at 600°C for 5 hours, and the activated oxide powder after high temperature roasting is granulated into a columnar Ф5×(3~7) for use. Take 200ml of catalyst respectively and put it into a Ф40mm×2.5mm×300mm stainless steel reactor, and pass nitrogen gas at a space velocity of 10h -1 Purge for 2h. Under the conditions of pressure 0.5MPa and temperature 80℃, feed ethylene, ...

Embodiment 2～6

[0030] The preparation method and test method are the same as those in Example 1, except that the composition of the adsorbent is different. See Table 1 for details.

[0031] Table 1 Example 1-6 carbon monoxide adsorbent composition and evaluation results

[0032]

Embodiment 7

[0034] Weigh Cu(NO 3 ) 2 , Zn(NO 3 ) 2 , Mn(NO 3 ) 2 , Ni(NO 3 ) 2 , Fe(NO 3 ) 3 , The formulation is shown in Table 1. Stir and dissolve the above substances in 65℃ hot water, pour the mixture into the reactor, and configure an excess of 20% aging agent Na 2 CO 3 The solution was slowly injected into the same reaction kettle for 4h aging reaction, the reaction was controlled at 70℃, pH value 9-10, and then the reacted slurry was centrifuged to make filter cake, and washed (water temperature 70℃) repeated 2 -3 times, until the pH value of the slurry is 6-7, then dry the filter cake at low temperature and roast at 600°C for 5 hours, and granulate the high-temperature roasted active oxide powder into a columnar Ф5×(3-7) for use. Take 200ml of catalyst respectively and put it into a Ф40mm×2.5mm×300mm stainless steel reactor, and introduce nitrogen gas at a space velocity of 10h -1 Purge for 2h. Under the conditions of pressure 0.5MPa and temperature 90℃, feed ethylene and the gas p...

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Abstract

The invention relates to a multi-element high-activity component carbon monoxide adsorbent as well as a preparation method and application thereof. The multi-element high-activity component carbon monoxide adsorbent is mainly prepared by an active component co-precipitation method; an active component comprises high-valence oxide of Cu, Zn, Mn, Ni and Fe: CuO, ZnO, MnOx, NiO and FeOy as well as dispersing agent Al2O3 powder. The multi-element high-activity component carbon monoxide adsorbent as well as the preparation method and application thereof have the benefits that by utilizing the characteristic of complementary performances of different components, the multiple components reach high-valence states through oxidation, and further, the ability to remove carbon monoxide by chemical adsorption is realized; the effect of a catalyst of the multi-element high-activity component carbon monoxide adsorbent is superior to that of a single or two-component catalyst; the multi-element high-activity component carbon monoxide adsorbent has the advantages of being free from loss of effective component of feed gas, high in removal depth, large in capacity, low in activation temperature, strong in anti-sintering ability, long in service life, high in mechanical strength, hard to pulverize and the like, is suitable for C2H4, C3H6, CH4, H2, N2, He, Ne, Ar, Kr, Xe and deep removal of the carbon monoxide by electron gas, and can be widely applied to large-scale industrial production.

Description

Technical field [0001] The invention relates to a carbon monoxide adsorbent used in petrochemical, electronics, metallurgy, gas, analysis, semiconductor and other industries, and a preparation method and application thereof, in particular to a multi-active component carbon monoxide adsorbent and a preparation method and application thereof. Background technique [0002] At present, the carbon monoxide removal agents involved in related patent documents are divided into two categories: the first category is catalytic reaction type such as Pd / Al 2 O 3 The removal mechanism is that the precious metal Pd is used as a catalyst, and the oxygen contained in the raw material is used or the carbon monoxide in the raw material is reacted to generate carbon dioxide to achieve the removal purpose. However, this type of carbon monoxide removal agent has the following problems: 1. Because the catalyst itself contains the precious metal Pd, in the process of removing carbon monoxide from the hyd...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J20/08B01J20/30B01D53/86B01D53/62C01B3/56B01J23/889C07C7/12C07C9/04C07C11/04C07C11/06
CPCB01D53/864B01D2253/104B01D2253/1124B01D2255/2073B01D2255/20738B01D2255/20753B01D2255/20761B01D2255/20792B01D2255/2092B01D2256/10B01D2256/16B01D2256/18B01D2256/245B01D2257/502B01J20/06B01J20/08B01J23/002B01J23/8892B01J2220/42B01J2220/4806B01J2523/00C01B3/56C01B2203/042C07C7/12B01J2523/17B01J2523/27B01J2523/31B01J2523/72B01J2523/842B01J2523/847C07C9/04C07C11/04C07C11/06Y02A50/20Y02P20/50Y02P20/52
Inventor 缪廷春
Owner 大连圣得环保新材料有限公司
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