Flame-retardant degradable antibacterial polylactic acid elastic fiber and preparation method thereof

An elastic fiber, polylactic acid technology, applied in the field of fibers, can solve the problems of the elastic properties to be improved, the hardness is high, the polylactic acid is brittle, etc., and achieves the effects of good flame retardant effect, high elasticity and simple preparation method.

Active Publication Date: 2017-08-08
飞马新材料(山东)股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the defects of high brittleness and high hardness of polylactic acid limit its further application, especially in the fiber field, and the elastic properties also need to be improved.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0018] The flame-retardant and degradable antibacterial polylactic acid elastic fiber provided by the present embodiment comprises 100 parts of polylactic acid, 8 parts of maleic anhydride graft compatibilizer, 2 parts of tert-butyl peroxybenzoate, and 12 parts of antibacterial agent in parts by mass. parts, 6 parts of citric acid, 12 parts of tert-butanol, 5 parts of vinyl polydimethylsilane, 0.3 parts of phosphite, 10 parts of flame retardant; 75 parts of nano zinc oxide, 5 parts of modified activated carbon, wherein said modified activated carbon comprises 80 parts of activated carbon, 5 parts of cerium nitrate, 5 parts of starch, and 10 parts of citric acid solution whose concentration is 3mol / L by mass fraction; The flame retardant includes 20 parts of phosphoric acid ester, 8 parts of cobalt oxide and 25 parts of diammonium phosphate in parts by weight.

[0019] The preparation method of flame-retardant and degradable antibacterial polylactic acid elastic fiber is as fol...

Embodiment 2

[0027] The raw material and preparation method of the flame-retardant and degradable antibacterial polylactic acid elastic fiber provided in this example are roughly the same as those in Example 1, the main difference being that in this example, 14 parts by mass of the flame retardant is used.

[0028] The prepared flame-retardant degradable antibacterial polylactic acid elastic fiber is tested for performance, and the recovery rate under 100% elongation is 96.9%; The inhibition rate of fiber to Escherichia coli and Staphylococcus aureus reaches 99.99%; According to the standard of GB / T5455-1997 "Textile Combustion Performance Test Vertical Method", the flame-retardant and degradable antibacterial polylactic acid provided by this embodiment is measured The LOI of the elastic fiber was 31.0%.

Embodiment 3

[0030] The raw material and preparation method of the flame-retardant and degradable antibacterial polylactic acid elastic fiber provided in this example are roughly the same as those in Example 1, the main difference being that in this example, 18 parts by mass of the flame retardant is used.

[0031] The prepared flame-retardant degradable antibacterial polylactic acid elastic fiber is tested for performance, and the recovery rate under 100% elongation is 96.9%; The inhibition rate of fiber to Escherichia coli and Staphylococcus aureus reaches 99.99%; According to the standard of GB / T5455-1997 "Textile Combustion Performance Test Vertical Method", the flame-retardant and degradable antibacterial polylactic acid provided by this embodiment is measured The LOI of the elastic fiber was 31.9%.

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Abstract

The invention discloses a flame-retardant degradable antibacterial polylactic acid elastic fiber. The flame-retardant degradable antibacterial polylactic acid elastic fiber is prepared from the following raw materials in parts by mass: 100 parts of polylactic acid, 5 to 10 parts of maleic anhydride grafted compatilizer, 1 to 2 parts of tert-butyl peroxybenzoate, 8 to 12 parts of antibacterial agent, 5 to 8 parts of citric acid, 10 to 16 parts of tert-butyl alcohol, 2 to 5 parts of vinyl polydimethylsilane, 0.2 to 0.5 part of phosphite, and 10 to 18 parts of flame-retardant agent; the antibacterial agent is prepared from the following components in parts by mass: 20 parts of nanometer cerium oxide, 75 parts of nanometer zinc oxide, and 5 parts of modified activated carbon; the flame-retardant agent is prepared from the following components in parts by weight: 15 to 25 parts of phosphate, 5 to 10 parts of cobalt oxide, and 20 to 30 parts of diammonium phosphate. The flame-retardant degradable antibacterial polylactic acid elastic fiber has the advantages that the raw materials are non-toxic or are basically non-toxic, and the green chemical principle is met; the effects of degradability, large elasticity, good flame-retardant effect and antibacterial property are realized; the whole preparation method is simple and feasible.

Description

technical field [0001] The invention relates to a fiber, in particular to a flame-retardant, degradable and antibacterial polylactic acid elastic fiber. Background technique [0002] Polylactic acid is compounded in units of microbial fermentation product lactic acid. Polylactic acid products can be completely decomposed into carbon dioxide and others after being discarded, and will not pollute the environment, so it is a completely natural cycle degradable material. However, the defects of high brittleness and high hardness of polylactic acid limit its further application, especially in the fiber field, and its elastic properties need to be improved. As people pay more and more attention to the environment and their own health, the functional requirements for polylactic acid fibers are gradually increasing. In addition, polylactic acid is extremely flammable, and its limiting oxygen index is only 19%. Contents of the invention [0003] The object of the present inventi...

Claims

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Application Information

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IPC IPC(8): D01F6/92D01F1/07D01F1/10D01D5/08D01D5/088
CPCD01D5/08D01D5/088D01F1/07D01F1/10D01F1/103D01F6/92
Inventor 余三川陈岳
Owner 飞马新材料(山东)股份有限公司
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