Manufacturing method of flexible substrate
A flexible substrate and manufacturing method technology, which is applied in the direction of final product manufacturing, sustainable manufacturing/processing, semiconductor/solid-state device manufacturing, etc., can solve problems such as no record, no record of resin layer or support transmittance, etc. the effect of making
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[0131] Hereinafter, the present invention will be described in detail based on test examples, but the present invention is not limited to the following.
[0132] Abbreviations and measurement methods of various physical properties and their conditions in the test examples are shown below.
[0133] TFMB: 2,2′-bis(trifluoromethyl)-4,4′-diaminobiphenyl
[0134] 6FDA: 2,2′-bis(3,4-dicarboxyphenyl)hexafluoropropane dianhydride
[0135] PMDA: pyromellitic dianhydride
[0136] AAPBZI: 5-Amino-2-(4-aminophenyl)benzimidazole
[0137] 4,4'-DDS: 4,4'-sulfonyl diphenylamine
[0138] DMAc: N,N-Dimethylacetamide
[0139] NMP: N-methyl-2-pyrrolidone
[0140] CBDA: cyclobutane-1,2,3,4-tetracarboxylic dianhydride
[0141] BPDA: 3,3′,4,4′-Biphenyltetracarboxylic dianhydride
[0142]
[0143] Regarding the transmittance, the transmittance at each wavelength of 300 nm to 800 nm was measured with a spectrophotometer (UV-3600Plus manufactured by Shimadzu Corporation). Table 2 and Table 3 ...
Synthetic example 1
[0147] (Polyimide Precursor Solution 1)
[0148] Under nitrogen flow, 8.9334 g of TFMB was dissolved in 70 g of DMAc as a vehicle in a 300 ml separable flask. Then, 6.0666 g of PMDA was added to this solution, and 85 g of DMAc was added so that the solid content might become 15 wt%, and it stirred at room temperature for 6 hours, and performed the polymerization reaction. After the reaction, a viscous colorless and transparent polyimide precursor solution was obtained. Moreover, the structure of a raw material monomer is shown in Table 1 (the following synthesis example is also the same).
Synthetic example 2
[0150] (polyimide precursor solution 2)
[0151] Under nitrogen flow, 8.4914 g of TFMB was dissolved in 70 g of DMAc as a solvent in a 300 ml separable flask. Then, 1.4680 g of 6FDA was added and stirred to this solution, 5.0406 g of PMDA was further added, 85 g of DMAc was added so that the solid content became 15 wt %, and the mixture was stirred at room temperature for 6 hours to conduct a polymerization reaction. After the reaction, a viscous colorless and transparent polyimide precursor solution was obtained.
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