Low-smoke halogen-free flame-retarding ceramizable thermoplastic polyurethane elastomer composite material, preparation method and application thereof

A thermoplastic polyurethane and composite material technology, which is applied in the field of polyurethane elastomers, can solve the problem of reduced tensile strength, tear strength and elongation at break of composite materials, failure to meet the mechanical properties requirements of insulation or sheathing materials, loss of escape opportunities, etc. problems, to achieve the effect of improving tensile strength and tear strength, good high temperature strength and thermal shock resistance, and improving processing rheology

Active Publication Date: 2017-10-24
ADVANCED THERMOPLASTIC POLYMER TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This patent has the following disadvantages: the addition of a large amount of porcelain fillers leads to a significant decrease in the tensile strength, tear strength and elongation at break of the composite material, which cannot meet the mechanical performance requirements of cables and optical cables for insulation or sheath materials
[0008] Conventional cables will also produce a large amount of toxic gas and smoke during the combustion process, which will have a great impact on people's escape, and even become a safety hazard. Many people are smoked by smoke and toxic gases in a fire. thus losing the chance of escape

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0068] A low-smoke, halogen-free, flame-retardant ceramizable thermoplastic polyurethane elastomer composite material, comprising the following raw materials in parts by weight:

[0069] Thermoplastic polyurethane 25 parts

[0070] Halogen-free flame retardant 10 parts

[0071] 5 parts polyester staple fiber

[0072] Smoke suppressant 1 part

[0073] Porcelain powder 20 parts

[0074] 0.5 parts of compatibilizer

[0075] Antioxidant 0.02 parts

[0076] Anti-hydrolysis agent 0.02 parts.

[0077] The thermoplastic polyurethane is polyether polyurethane.

[0078] The halogen-free flame retardant is ammonium phosphate, ammonium polyphosphate, modified ammonium polyphosphate or aluminum hypophosphite.

[0079] The smoke suppressant is a molybdenum compound.

[0080]The porcelain powder is composed of at least one of boron compound, low softening point glass powder, glass fiber and mineral filler; the mineral filler is attapulgite, bentonite, kaolin, montmorillonite, pottery...

Embodiment 2

[0090] A low-smoke, halogen-free, flame-retardant ceramizable thermoplastic polyurethane elastomer composite material, comprising the following raw materials in parts by weight:

[0091] Thermoplastic polyurethane 40 parts

[0092] Halogen-free flame retardant 25 parts

[0093] 8 parts polyester staple fiber

[0094] Smoke suppressant 3 parts

[0095] Porcelain powder 40 parts

[0096] Compatibilizer 2 parts

[0097] Antioxidant 0.04 parts

[0098] Anti-hydrolysis agent 0.04 parts.

[0099] The thermoplastic polyurethane is polyester polyurethane.

[0100] The halogen-free flame retardant is melamine and its compounds.

[0101] The smoke suppressant is an iron compound.

[0102] The porcelain powder is composed of at least one of boron compound, low softening point glass powder, glass fiber and mineral filler; the mineral filler is mica powder, talcum powder, feldspar powder or brucite powder; the boron compound It is borax; the low softening point glass powder is cal...

Embodiment 3

[0112] A low-smoke, halogen-free, flame-retardant ceramizable thermoplastic polyurethane elastomer composite material, comprising the following raw materials in parts by weight:

[0113] Thermoplastic polyurethane 55 parts

[0114] Halogen-free flame retardant 40 parts

[0115] 10 parts polyester staple fiber

[0116] Smoke suppressant 5 parts

[0117] Porcelain powder 50 parts

[0118] Compatibilizer 3 parts

[0119] Antioxidant 0.06 parts

[0120] Anti-hydrolysis agent 0.06 parts.

[0121] The thermoplastic polyurethane is polyether polyurethane.

[0122] The halogen-free flame retardant is zinc borate, montmorillonite or clay.

[0123] The smoke suppressant is a metal oxide.

[0124] The porcelain powder is composed of at least one of boron compound, glass powder with low softening point, glass fiber and mineral filler; the mineral filler is forsterite powder, calcium borate powder, chlorite powder or pyrophyllite powder; The boron compound is ammonium borate; the ...

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Abstract

The invention relates to the technical field of polyurethane elastomers and particularly relates to a low-smoke halogen-free flame-retarding ceramizable thermoplastic polyurethane elastomer composite material, a preparation method and an application thereof. The composite material comprises, by weight, 25-85 parts of thermoplastic polyurethane, 10-70 parts of a halogen-free flame retardant, 1-10 parts of a smoke inhibitor, 20-80 parts of a ceramization powder, 0.5-5 parts of a compatilizer, 0.02-0.1 parts of an antioxidant, and 0.02-0.1 parts of a hydrolysis inhibitor. The thermoplastic polyurethane elastomer composite material has excellent flame-retarding effect, low smoke density, high strength, good flexibility and high break elongation, can form a compact ceramized product at the temperature range of 600-1000 DEG C, is low in ceramization temperature and can form compact ceramic. The formed ceramized product has high high-temperature strength and anti-heat-flow-impact capability.

Description

technical field [0001] The invention relates to the technical field of polyurethane elastomers, in particular to a low-smoke, halogen-free, flame-retardant, ceramizable thermoplastic polyurethane elastomer composite material and its preparation method and application. Background technique [0002] With the continuous progress of social development, people's requirements for safety protection continue to increase. In the field of wire and cable, people have higher and higher requirements for the continuous power supply capability of fire-resistant power cables in fires. The insulation performance of fire-resistant power cables has an important impact on their continuous power supply capabilities in fires. [0003] The ceramizable polymer composite material is a new type of heat-resistant material, which is a composite material prepared by adding ceramizable additives to polymer / resin and melt blending. The ceramizable polymer composite material has excellent high and low tem...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/08C08L75/06C08L67/00C08L51/06C08K13/04C08K13/06C08K9/04C08K3/32C08K5/5313C08K5/134C08K3/38C08K7/14C08K5/526C08K3/34
CPCC08K2003/322C08K2003/323C08K2003/387C08K2201/003C08K2201/004C08L75/06C08L75/08C08L2201/02C08L2201/22C08L2203/202C08L2205/02C08L2205/03C08L2205/16C08L67/00C08L51/06C08K13/04C08K3/32C08K5/5313C08K7/14C08K3/346C08K5/1345C08K5/5425C08K5/3492C08K5/18C08K13/06C08K9/08C08K3/38C08K5/526C08K3/34
Inventor 李同兵刘方达钟荣栋苏俐娇
Owner ADVANCED THERMOPLASTIC POLYMER TECH
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