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A kind of zircon beneficiation combination agent and beneficiation method

A technology of combining chemicals and zircon, applied in chemical instruments and methods, flotation, wet separation, etc., can solve the problems of poor selectivity, waste of resources, multiple recovery rates, etc. Improve grade and recovery rate, collectability and selectivity

Inactive Publication Date: 2019-08-13
ZHENGZHOU MINERALS COMPOSITIVE UTILIZATION RES INST CHINESE GEOLOGICAL ACAD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] High-purity zircon is separated by gravity separation, magnetic separation, electric separation and other processes. Due to poor separation accuracy of equipment, Zr(Hf)O in zircon concentrate 2 content is difficult to reach 65%
Even concentrate Zr(Hf)O 2 The content can reach 65%, but more recovery rate will be lost, resulting in waste of resources
The conventional zircon collectors oleic acid and sodium oleate have poor selectivity, and it is difficult for the concentrate to meet higher quality requirements

Method used

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  • A kind of zircon beneficiation combination agent and beneficiation method

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Experimental program
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Effect test

Embodiment 1

[0025] A zircon mineral beneficiation combination agent, the agent added per ton of raw ore is composed of the following raw materials by weight: sulfuric acid 100-2000g, inhibitor 0-500g, collector 100-1000g, inhibitor is water glass, collector includes The mass ratio of sodium petroleum sulfonate and hydroxamic acid, sodium petroleum sulfonate and hydroxamic acid is 1:1-10:1.

[0026] The hydroxamic acid is salicylic hydroxamic acid or benzhydroxamic acid.

[0027] The method of using the above-mentioned zircon beneficiation combination reagent for beneficiation, the specific steps are as follows:

[0028] (1) Gravity separation, enrichment, and tailing: the crude ore is separated by gravity separation and gangue minerals to obtain heavy minerals;

[0029] (2) Heavy minerals are subjected to magnetic separation, electric separation or combined magneto-electric processes to remove weak magnetic, strong magnetic and conductive materials to obtain coarse zircon concentrate; Separation...

Embodiment 2

[0034] The zircon beneficiation method, the specific steps are as follows:

[0035] (1) Gravity separation, enrichment, and tailing: the crude ore is separated by gravity separation and gangue minerals to obtain heavy minerals;

[0036] (2) Heavy minerals are subjected to magnetic separation, electric separation or combined magneto-electricity processes to remove weak magnetic substances, strong magnetic substances and conductive substances to obtain coarse zircon concentrate;

[0037] (3) Flotation process: adopts a process flow of one roughing, two sweeping, four beneficiation, and medium ore returning in sequence. The reagent system is as follows: roughing section: adjuster sulfuric acid dosage 40g / t, water glass 60g / t, collector (sodium petroleum sulfonate: salicylic hydroxamic acid ratio 1:1) dosage 60g / t, flotation concentration 34%, flotation time 5 minutes; sweeping I sulfuric acid dosage 10g / t, water glass 10g / t, collector dosage 15g / t, flotation concentration 26%, flotat...

Embodiment 3

[0040] The zircon beneficiation method, the specific steps are as follows:

[0041] (1) Gravity separation, enrichment, and tailing: the crude ore is separated by gravity separation and gangue minerals to obtain heavy minerals;

[0042] (2) Heavy minerals are subjected to magnetic separation, electric separation or combined magneto-electricity processes to remove weak magnetic substances, strong magnetic substances and conductive substances to obtain coarse zircon concentrate;

[0043] (3) Flotation process: adopts the process flow of one roughing, two sweeping, two beneficiation, and the middle ore returning in sequence. The reagent system is as follows: roughing section: adjuster sulfuric acid dosage 80g / t, water glass 120g / t, collector (sodium petroleum sulfonate: salicylic hydroxamic acid ratio 2:1) dosage 120g / t, flotation concentration 37%, flotation time 5 minutes; sweep Ⅰ sulfuric acid dosage 20g / t, water glass 20g / t, collector dosage 30g / t, flotation concentration 27%, fl...

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Abstract

The invention discloses a zircon beneficiation composite reagent and a beneficiation method. Each ton of reagents for adding to crude ore comprises, by weight, 100-2000 g of sulfuric acid, 0-500 g of inhibitors and 100-1000 g of collecting agents. The inhibitors are sodium silicate, the collecting agents comprise petroleum sodium sulfonate and hydroximic acid, and a mass ratio of the petroleum sodium sulfonate to the hydroximic acid is 1:1-10. The zircon beneficiation composite reagent and the beneficiation method has the advantages that the zircon beneficiation composite reagent is good in zircon collecting property and selectivity, and the grade and the recovery of zircon concentrate can be further improved; the sodium silicate can be added to materials to be used as the inhibitors for fine silt or clay minerals when the materials contain few fine silt or clay minerals during flotation operation.

Description

Technical field [0001] The invention belongs to the technical field of mineral processing, and specifically relates to a zircon beneficiation combination agent and a beneficiation method. Background technique [0002] The zircon is zirconium orthosilicate and the chemical formula is ZrSiO 4 , Is the most common kind of zirconium-containing minerals. Zircon deposits are mostly seashore placers, and heavy minerals such as magnetite, ilmenite, rutile, monazite, etc. are usually co-existed in heavy sands containing zircon. my country’s proven zircon ore reserves rank 5th in the world. Zircon is a very important non-metallic mineral resource. It is mainly used as a raw material for zirconate refractory bricks, and can also be used for precision casting sand and ceramics. appliance. [0003] Common ore dressing methods: gravity separation, magnetic separation, electrostatic separation and flotation are often used. Gravity separation is based on the difference in mineral density. The hea...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B03D1/018B03B7/00B03D101/02B03D101/06B03D103/02
CPCB03B7/00B03D1/018B03D2201/02B03D2201/06B03D2203/02
Inventor 张红新吕振福李洪潮冯安生
Owner ZHENGZHOU MINERALS COMPOSITIVE UTILIZATION RES INST CHINESE GEOLOGICAL ACAD
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