Flame-retardant material used for cable sheath and preparation method thereof

A technology for flame retardant materials and cable protection, applied in the field of flame retardant materials, can solve the problems of cable surface sheath damage, poor wear resistance, damage, etc., and achieve the effects of improving flame retardant performance, improving dispersion, and improving wear resistance.

Inactive Publication Date: 2017-11-24
佛山杰致信息科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the low mechanical strength and hardness of the ethylene vinyl acetate copolymer material, the material has low mechanical strength and poor wear resistance, resulting in damage to the cable surface sheath during the installation and laying of the cable, especially for large cross-section cables. Once the cable sheath is broken, it may cause the instability of the power grid system, and the cable body will be subjected to various damages, which cannot effectively protect the effective operation of the cable; moreover, the existing low-smoke, halogen-free and flame-retardant sheath materials have poor adhesion, resulting in The conductive graphite layer or conductive polyethylene layer on the surface will fall off, so that the partial discharge current of the cable cannot be effectively released, affecting the effective use of high-voltage cables

Method used

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  • Flame-retardant material used for cable sheath and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] The preparation method of composite flame retardant:

[0022] Add 6 parts by weight of nano-silicon carbide and 2 parts by weight of carboxylated multi-walled carbon nanotubes into an ethanol solution of 80 parts by weight of magnesium chloride, fully stir and disperse and add 2 parts by weight of sodium dodecylbenzenesulfonate, After ultrasonic dispersion, add 50 parts by weight of ammonia water to the dispersed suspension to obtain a mixed solution, transfer the mixed solution to a 110°C hydrothermal kettle for constant temperature reaction, and perform subsequent treatment after the reaction to obtain a composite flame retardant.

Embodiment 2

[0024] The preparation method of composite flame retardant:

[0025] 12 parts by weight of nano-silicon carbide and 8 parts by weight of carboxylated multi-walled carbon nanotubes are added to 90 parts by weight of magnesium sulfate ethanol solution, fully stirred and dispersed, and then 1 part by weight of sodium hexadecylbenzenesulfonate is added After ultrasonic dispersion, add 100 parts by weight of ammonia water to the dispersed suspension to obtain a mixed solution, transfer the mixed solution to a 180°C hydrothermal kettle for constant temperature reaction, and perform follow-up treatment after the reaction to obtain a composite flame retardant.

Embodiment 3

[0027] A flame retardant material for cable sheaths, calculated in parts by weight, comprising the following raw materials:

[0028] 8 parts of metallocene polyethylene, 24 parts of ethylene vinyl acetate copolymer, 63 parts of polyethylene resin, 10 parts of dioctyl adipate, 15 parts of composite flame retardant of embodiment 1, 4 parts of organic silicone, Dilauryl propionate 2 parts and polyethylene wax 4 parts.

[0029] Preparation:

[0030] 1) According to the proportioning ratio, weigh 8 parts of metallocene polyethylene, 24 parts of ethylene vinyl acetate copolymer, 63 parts of polyethylene resin, 10 parts of dioctyl adipate, 15 parts of the composite flame retardant of Example 1, organic Mix 4 parts of silicone, 2 parts of dilauryl thiodipropionate and 4 parts of polyethylene wax for later use;

[0031] 2) Put the mixture of step 1) into the internal mixer, and when it is heated to 115-135°C, lift the upper bolt of the internal mixer to turn over the material. 155°C...

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PUM

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Abstract

The invention provides a flame-retardant material used for a cable sheath and a preparation method thereof. The flame-retardant material used for the cable sheath is prepared from the following raw materials in parts by weight: 5-10 parts of metallocene polyethylene, 20-30 parts of an ethylene-vinyl acetate copolymer, 60-70 parts of polyethylene resin, 6-12 parts of a plasticizer, 10-20 parts of a composite flame retardant, 3-6 parts of organic silicone, 1-3 parts of an antioxidant and 2-6 parts of a lubricating agent, wherein the composite flame retardant is prepared from magnesium salt, nano silicon carbide and carbon nanotubes. The preparation method comprises the following steps: putting the raw materials into an internal mixer, heating to 115-135 DEG C, lifting the internal mixer to a top peg, reversing materials, after the materials are reversed, continuously mixing until temperature in the internal mixer reaches 145-155 DEG C, stopping heating, then continuously mixing for 2-5 minutes, then extruding by virtue of a single screw extruder, and pelletizing, so that the flame-retardant material is obtained. The flame-retardant material provided by the invention has good flame retardant effect and has the advantages of high oxygen index and strong self-extinguishing property while mechanical properties of the cable sheath are met.

Description

technical field [0001] The invention belongs to the technical field of flame retardant materials, and in particular relates to a flame retardant material for a cable sheath and a preparation method thereof. Background technique [0002] Plastic sheath materials need to be extruded on the outer layer of the cable. Usually, the sheath material of high-voltage power cables is made of black polyethylene material, and the outer surface is coated with conductive graphite or conductive polyethylene to prevent high-voltage induced voltage breakdown and reduce surface induced voltage. However, with the underground laying of urban high-voltage power grid lines, cables are required to have low-smoke, halogen-free and flame-retardant functions, and their sheath materials must be low-smoke, halogen-free, and flame-retardant black polyethylene materials. The flame retardant sheath material usually uses a large amount of inorganic aluminum hydroxide and magnesium hydroxide flame retardant ...

Claims

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Application Information

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IPC IPC(8): C08L23/06C08L23/08C08L83/04C08K13/04C08K5/11C08K3/22C08K7/24C08K3/34C08K5/372H01B3/44
CPCC08L23/06C08K2201/011C08L2201/02C08L2205/02C08L2205/025C08L2205/035C08L2314/06H01B3/441C08L23/0853C08L83/04C08K13/04C08K5/11C08K3/22C08K7/24C08K3/34C08K5/372
Inventor 刘威
Owner 佛山杰致信息科技有限公司
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