Solid-state lithium ion battery and preparation method thereof
A lithium-ion battery and solid-state electrolyte technology, which is applied in secondary batteries, circuits, electrical components, etc., can solve the problems of poor performance of solid-state lithium-ion batteries, inability to make good contact between electrolyte and electrodes, and achieve easy operation, reduced interface impedance, Performance-enhancing effects
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[0024] (1) Preparation of positive electrode sheet
[0025] A Dissolve polyvinylidene fluoride (PVdF) in N-methylpyrrolidone at a concentration of 5wt.%.
[0026] B. After mixing PVdF, conductive carbon, and positive electrode active material in a mass ratio of 10:10:80, stir for at least 1 hour.
[0027] C Evenly coat the slurry obtained in the previous step on the aluminum foil, with a thickness of 100-120μm, dry at 100°C, then dry in a vacuum oven at 120°C, roll pressing, punching, weighing and continue Dry in a vacuum oven at 120°C and put in a glove box for later use.
[0028] (2) Preparation of negative electrode sheet
[0029] Use metal lithium sheet or negative electrode active material to prepare negative electrode sheet using the following steps
[0030] A Dissolve PVdF in N-methylpyrrolidone at a concentration of 5wt.%.
[0031] B. After mixing PVdF, conductive carbon, and negative electrode active material in a mass ratio of 10:10:80, stir for at least 1 hour.
[0032] C Evenl...
Embodiment 1
[0040] Electrolyte: polyvinyl carbonate (mass: 10%) / poly(vinylidene fluoride-hexafluoropropylene) (mass: 50%) + lithium bistrifluoromethanesulfonimide (mass: 40%)
[0041] Cathode active material: lithium iron phosphate
[0042] Negative electrode: lithium metal
[0043] Organic solvent: propylene carbonate
[0044] Organic solvent coating amount, 10μL / cm 2
Embodiment 2
[0046] Electrolyte: Polyethylene carbonate (mass: 60%) + lithium perchlorate (mass: 40%)
[0047] Positive electrode: lithium cobalt oxide
[0048] Negative electrode: lithium metal
[0049] Organic solvent: ethylene carbonate
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