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A method of using magnetic carbon to support acid and base to catalyze waste cooking oil to produce biodiesel

A technology for biodiesel and catering waste oil, applied in the field of waste recycling, can solve the problems of large waste liquid output and difficult catalyst recovery, and achieve the effect of reducing the production amount

Inactive Publication Date: 2021-07-02
UNIV OF SCI & TECH BEIJING +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The invention solves the problems of difficult catalyst recovery and large output of waste liquid in the traditional homogeneous catalysis process for preparing biodiesel, realizes the high value-added utilization of catering waste oil, and effectively reduces the preparation cost of biodiesel

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0025] (1) Preparation of magnetic carbon: take a certain amount of ferric salt and dissolve it in deionized water, and configure a solution with a ferric salt concentration of 10% to 25%; place the sawdust in the ferric salt solution after being pulverized; three The mass ratio of valent iron salt to sawdust is 4:1-10:1; the sawdust is soaked in ferric salt solution for 30-120 minutes and vacuum filtered, and the filter cake is dried to constant weight at 60°C; The dried filter cake was put into an alumina crucible and placed in a high-temperature tube furnace under N 2 Under protection, heat up to 550-900°C at a rate of 2-20°C / min, and keep it warm for 30-120min to prepare crude magnetic carbon; wash the crude magnetic carbon with deionized water to remove impurities, and the solid-to-liquid ratio is 1: 10~1:200; the magnetic carbon obtained by washing is dried at 105°C to obtain the finished magnetic carbon;

[0026] (2) Preparation of magnetic solid acid: magnetic carbon ...

Embodiment 1

[0031] Crude biodiesel was prepared by the method described above. Specifically:

[0032] (1) The preparation of magnetic carbon: After the sawdust powder is crushed through a 200 mesh sieve, it is mixed with 20% Fe(NO 3 ) 3 The mass ratio is 1:4 and its solution is immersed for 60min under the action of magnetic stirring. After the impregnation is completed, the solid-liquid separation is carried out by a vacuum filter, and the filter cake is placed in an evaporating dish and placed in an oven, and dried at 60°C until it reaches a constant weight. The filter cake was put into a crucible and placed in a microwave pyrolysis furnace under N 2 Under protection, the temperature was raised to 700°C at a rate of 5°C / min, and kept for 60 minutes to obtain magnetic carbon; the product was washed with deionized water to remove impurities;

[0033] (2) Preparation of magnetic solid acid: Mix magnetic carbon and concentrated sulfuric acid at a solid-to-liquid ratio of 1:25, sulfonate a...

Embodiment 2

[0037] (1) The preparation of magnetic carbon: After the sawdust powder is crushed through a 100-mesh sieve, it is mixed with 15% Fe(NO 3 ) 3 The mass ratio is 1:8 and its solution is immersed for 30min under the action of magnetic stirring. After the impregnation is completed, the solid-liquid separation is carried out by a vacuum filter, and the filter cake is placed in an evaporating dish and placed in an oven, and dried at 60°C until it reaches a constant weight. The filter cake was put into a crucible and placed in a microwave pyrolysis furnace under N 2 Under protection, the temperature was raised to 550°C at a rate of 5°C / min, and kept for 30 minutes to obtain magnetic carbon; the product was washed with deionized water to remove impurities;

[0038] (2) Preparation of magnetic solid acid: Mix magnetic carbon and concentrated sulfuric acid at a solid-to-liquid ratio of 1:15, sulfonate at 120°C for 10 hours, cool to room temperature, add the mixture to distilled water,...

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PUM

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Abstract

The invention discloses a method for preparing biodiesel from catering waste oil by using magnetic carbon loaded with acid and alkali to catalyze biodiesel, and belongs to the field of waste resource utilization. This method uses magnetic carbon as a carrier, loaded acid (H 2 SO 4 ) and alkali (KOH) for the two-step catalytic production of biodiesel from waste cooking oil. Waste food oil enters the acid-catalyzed esterification reactor after impurity removal. 2 SO 4 Solid catalyst and methanol vapor are introduced to react at the optimum temperature. After the reaction, the solution was allowed to stand, and glycerin, methanol and oil were separated. Grease enters the base-catalyzed transesterification reactor, and reacts at the optimum temperature by adding an appropriate amount of magnetic carbon / KOH solid catalyst and methanol. After the reaction, the solution was left to stand, and the biodiesel was harvested by liquid separation. The magnetic carbon catalyst in the acid-base reactor can be separated, recovered, regenerated and reused by a strong magnet. Compared with the traditional technology, the invention has the advantages of small amount of waste liquid, easy recovery of catalyst, low cost and the like.

Description

technical field [0001] The invention relates to the technical field of waste recycling, in particular to a method for preparing biodiesel from catering waste oil by using magnetic carbon loaded with acid and alkali to catalyze waste oil. Background technique [0002] With the rapid development of social economy, energy consumption has increased sharply, and the shortage of energy resources has become an important factor restricting my country's social and economic development. The fluctuation of international oil price has more and more influence on our country's economy. The increasingly scarce oil resources seriously threaten the country's energy security. It has become an important direction of energy research to develop renewable alternative energy and get rid of the dependence on fossil energy. Sulfur dioxide, nitrogen oxides and a large amount of particulate dust produced during the combustion of fossil fuels have caused great harm to the ecological environment. Compar...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J27/02C11C3/10C10L1/02B01J23/78
CPCC10L1/02C11C3/10B01J23/78B01J27/02B01J37/084B01J35/33Y02E50/10
Inventor 吴川福王芳霞王晓娜张秉昕张少明李信高明汪群慧
Owner UNIV OF SCI & TECH BEIJING