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Multivariate controllable synthesis method of BiOCl photocatalyst

The invention discloses a multivariate controllable synthesis method of a BiOCl photocatalyst, and belongs to the technical field of photocatalytic water treatment of environmental chemical engineering. The multivariate controllable synthesis method is characterized by comprising the following steps: adding BiCl3 with proper concentration to diethylene glycol or a mixed solvent of diethylene glycol and water; adding a urea precipitation agent, directly transferring sol or transferring sol subjected to ultrasonic pretreatment into a Teflon high-pressure reaction kettle to carry out solvothermal reaction at certain temperature to generate sediments after evenly mixing; and baking the sediments at 80 DEG C after washing with water and ethanol, so as to obtain BiOCl photocatalyst powder with different morphologies. The synthesis method disclosed by the invention has the characteristics that the preparation cycle of BiOCl is short, use of a surfactant is avoided, grains with controllable crystal faces (110 and 102) and controllable morphologies (two-dimensional flakes, three-dimensional flowers or spheres) can be conveniently achieved by controlling and ultrasonic pretreatment on the solvent. The catalyst is applied to photocatalytic degradation of carbamazepine medicine wastewater, displays the photocatalytic activity superior to that of TiO2(P25) under ultraviolet light and simulated sunlight, and has a practical application prospect.
Owner:TAIYUAN UNIV OF TECH

Method for reinforced ultrafiltration treatment of phenol-containing waste-water by ultrafiltration membrane

The invention discloses a method for ultra-filtration membrane strengthened ultra-filtration treatment of phenol-containing sewage. The method comprises: first adding cetylpyridinium chloride which is a cationic surfactant, and sodium carbonate into the phenol-containing sewage, stirring uniformly and standing for reaction where cetylpyridinium chloride monomer molecules produce micelles by self-assembly and then solubilize the phenol contained in the water; pumping the water to an ultra-filtration component for filtration where the cetylpyridinium chloride micelles with being solubilized the phenol contained in the water are intercepted by the ultra-filtration membrane so that the phenol contained in the water is removed. The phenol concentration in the sewage is 5mg/L-200mg/L; the addition of cetylpyridinium chloride is 20*10<-3>mol/L-30*10<-3>mol/L; the addition of sodium carbonate is 1*10<-3>mol/L-20*10<-3>mol/L; the weight of molecules intercepted by the ultra-filtration membrane is 6000-10000Dalton; the membrane operation pressure is 0.05MPa-0.20MPa. The method is carried out in an intermittent type, and the standing reaction time is 0.5-10h. In treating the phenol-containing sewage, the invention has excellent phenol removal performance, low energy consumption, simple operation, low surfactant consumption and low cost. In addition, the surfactant and the phenol can be recycled.
Owner:HUNAN UNIV
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