High-glossiness high-adhesion enhanced PPS composite material and preparation method thereof

A technology of high adhesion and composite materials, applied in the field of modified polyphenylene sulfide resin, can solve the problems of difficult spraying or electroplating of PPS products, difficult to achieve good adhesion effect, difficult to meet appearance requirements, etc., to achieve enhanced toughness and easy processing , the effect of low internal stress

Inactive Publication Date: 2018-01-19
DONGGUAN HONOUR E P
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the crystallinity of PPS is greatly affected by the thermal history of the material, but still retains a high degree of crystallinity
Due to the relatively high crystallinity and the relatively low surface tension of the material, it is difficult to achieve a good adhesion effect when spraying paint, so it is very difficult to achieve spraying or electroplating on PPS products, so that it is difficult to meet products with very high appearance requirements.
Moreover, after glass fiber or carbon fiber reinforced PPS or mineral filled PPS, the appearance will also deteriorate, and the appearance effect of spraying will also be greatly affected

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Polyphenylene sulfide 50;

[0044] Nucleating agent 0.5;

[0045] Toughening agent 1;

[0046] Inorganic filler 50;

[0047] Main antioxidant 0.2;

[0048] Auxiliary antioxidant 0.3;

[0049] Lubricant 0.5;

[0050] Glass fiber 5;

[0051] Coupling agent 0.5;

[0052] A high-gloss and high-adhesion enhanced PPS composite material and its preparation method are as follows:

[0053] (1) Weigh polyphenylene sulfide, nucleating agent, toughening agent, inorganic filler, main antioxidant, auxiliary antioxidant, lubricant, coupling agent and glass fiber according to the above weight parts;

[0054] (2) Put the above components into the mixer in proportion to mix for 10-30 minutes;

[0055] (3) Put the mixed raw materials of step (2) into a twin-screw extruder, melt extrusion granulation to prepare the high gloss and high adhesion enhanced PPS composite material of Example 1.

[0056] The twin-screw extruder includes ten temperature control zones, the temperature of the temperature control zone...

Embodiment 2

[0058] Polyphenylene sulfide 50;

[0059] Nucleating agent 0.2;

[0060] Toughening agent 3;

[0061] Inorganic filler 35;

[0062] Main antioxidant 0.5;

[0063] Auxiliary antioxidant 0.5;

[0064] Lubricant 1;

[0065] Coupling agent 0.5;

[0066] A high-gloss and high-adhesion enhanced PPS composite material and its preparation method are as follows:

[0067] (1) Weigh polyphenylene sulfide, nucleating agent, toughening agent, inorganic filler, main antioxidant, auxiliary antioxidant, lubricant, and coupling agent according to the above weight parts;

[0068] (2) Put the above components into the mixer in proportion to mix for 10-30 minutes;

[0069] (3) Put the mixed raw materials of step polymerization (2) into a twin-screw extruder, weigh 10 parts of glass fiber side feed, melt-extrusion and granulate to obtain the high gloss and high adhesion enhancement of Example 2 PPS composite material.

[0070] The twin-screw extruder includes ten temperature control zones, the temperature of the ...

Embodiment 3

[0072] Polyphenylene sulfide 50;

[0073] Nucleating agent 0.6;

[0074] Toughening agent 5;

[0075] Inorganic filler 35;

[0076] Main antioxidant 0.2;

[0077] Auxiliary antioxidant 0.3;

[0078] Lubricant 1;

[0079] Coupling agent 1.5;

[0080] A high-gloss and high-adhesion enhanced PPS composite material and its preparation method are as follows:

[0081] (1) Weigh polyphenylene sulfide, nucleating agent, toughening agent, inorganic filler, main antioxidant, auxiliary antioxidant, lubricant, and coupling agent according to the above weight parts;

[0082] (2) Put the above components into the mixer in proportion to mix for 10-30 minutes;

[0083] (3) Put the mixed raw materials of step (2) into a twin-screw extruder, weigh 15 parts of glass fiber side-feed, melt-extrusion and granulate to obtain the high gloss and high adhesion enhancement of Example 3. PPS composite material.

[0084] The twin-screw extruder includes ten temperature control zones, the temperature of the temperature co...

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PUM

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Abstract

The invention discloses a high-glossiness high-adhesion enhanced PPS composite material and a preparation method thereof. The high-glossiness high-adhesion enhanced PPS composite material comprises polyphenylene sulfide, a nucleating agent, a toughening agent, inorganic filler, a main antioxidant, an auxiliary antioxidant, a lubricating agent, a coupling agent and glass fiber. According to the invention, an ethylene methyl acrylate copolymer, an ethylene butyl acrylate copolymer and polyethylene octylene block copolymer grafted maleic anhydride are added into a composite material formula. Thestrength of the composite material is greatly enhanced by ethylene-methyl acrylate-glycidyl methacrylate (GMA).

Description

Technical field [0001] The invention relates to the technical field of modified polyphenylene sulfide resins, in particular to a high-gloss and high-adhesion reinforced PPS composite material and a preparation method thereof. Background technique [0002] Polyphenylene sulfide (PPS) is a new type of polymer material that can be used in harsh environments for a long time. It not only has high temperature resistance (long-term use temperature is 200-220℃), and chemical resistance (hardly soluble in any solvent at 200℃) ), good flame retardancy (LOI> 35), easy to process and other characteristics, and has good dimensional stability and superior mechanical properties. In the plastics industry, PPS is recognized as the sixth largest after polyamide (PA), polyoxymethylene (POM), polycarbonate (PC), modified polyphenylene ether (MPPO), and thermoplastic saturated polyester (PBT / PET) Engineering plastics are widely used in fields such as automobiles, petrochemicals, electronic applia...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L81/02C08L23/08C08L51/06C08K13/04C08K7/14C08K7/08C08K3/26C08K3/30C08K5/134C08K5/526C08K5/372B29C47/92B29C48/92
Inventor 李红刚曹建伟王建平
Owner DONGGUAN HONOUR E P
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