Hard alloy resistant to high pressure and high temperature and preparation method thereof

A cemented carbide and high-pressure-resistant technology, which is applied in the field of powder metallurgy, can solve the problems of high price and high cobalt content, and achieve the effects of reducing test costs, inhibiting plastic deformation, and saving rare metal resources

Active Publication Date: 2018-01-19
HEYUAN ZHENGXIN HARDMETAL CARBIDE
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] Both of the above two schemes produce hard alloys with good high-pressure and high-temperature performance, but the content of metal cobalt in the scheme is relatively high. Cobalt is a metal material that is expensive and has a certain impact on human health. Therefore, from the perspective of human health In consideration of reducing costs and improving the high-pressure and high-temperature performance of hard alloys, there is still a lack of a high-pressure and high-temperature hard alloy that can reduce test costs, improve work efficiency, and save rare metal resources for the country.

Method used

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  • Hard alloy resistant to high pressure and high temperature and preparation method thereof
  • Hard alloy resistant to high pressure and high temperature and preparation method thereof

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0045] Embodiment 1, high pressure and high temperature hard alloy

[0046] The high-pressure and high-temperature cemented carbide is composed of the following components and their mass parts: 0.1 part of cobalt with a particle size of 0.3 μm, 0.1 part of rhodium with a particle size of 0.4 μm, and 1.0 part of carbonyl nickel powder with a particle size of 0.45 μm , 1.0 parts of vanadium carbide with a particle size of 0.15 μm, 10 parts of tantalum carbide with a particle size of 0.4 μm, 0.6 parts of niobium carbide with a particle size of 0.4 μm, 2.0 parts of titanium carbide with a particle size of 0.2 μm, and a particle size of 0.1 μm 0.3 parts of hafnium carbide, 0.1 part of aluminum nitride with a particle size of 0.3 μm, and 75 parts of tungsten carbide with a particle size of 0.25 μm.

[0047] Preparation:

[0048] S1: Take all the raw materials according to the specified mass parts, mix them evenly, add ball milling medium and place it in a ball mill for ball milling...

Embodiment 2

[0052] Embodiment 2, high pressure and high temperature hard alloy

[0053] The high-pressure and high-temperature cemented carbide is composed of the following components and their mass parts: 1.0 part of cobalt with a particle size of 0.6 μm, 0.3 part of rhodium with a particle size of 0.6 μm, and 0.5 part of carbonyl nickel powder with a particle size of 0.65 μm , 0.1 parts of vanadium carbide with a particle size of 0.6 μm, 20 parts of tantalum carbide with a particle size of 0.8 μm, 1.0 parts of niobium carbide with a particle size of 1 μm, 4.0 parts of titanium carbide with a particle size of 0.8 μm, and 0.5 parts of hafnium carbide, 0.5 parts of aluminum nitride with a particle size of 0.6 μm, and 90 parts of tungsten carbide with a particle size of 0.35 μm.

[0054] Preparation:

[0055] S1: Take all the raw materials according to the specified mass parts, mix them evenly, add ball milling medium and place it in a ball mill for ball milling. The ball milling medium is...

Embodiment 3

[0059] Embodiment 3, high pressure and high temperature hard alloy

[0060] The high-pressure and high-temperature cemented carbide is composed of the following components and their mass parts: 0.4 parts of cobalt with a particle size of 0.4 μm, 0.2 parts of rhodium with a particle size of 0.5 μm, and 0.7 parts of carbonyl nickel powder with a particle size of 0.5 μm , 0.5 parts of vanadium carbide with a particle size of 0.3 μm, 14 parts of tantalum carbide with a particle size of 0.5 μm, 0.7 parts of niobium carbide with a particle size of 0.6 μm, 3 parts of titanium carbide with a particle size of 0.4 μm, and a particle size of 0.2 μm 0.4 parts of hafnium carbide, 0.3 parts of aluminum nitride with a particle size of 0.4 μm, and 82 parts of tungsten carbide with a particle size of 0.3 μm.

[0061] Preparation:

[0062] S1: Take all the raw materials according to the specified mass parts, mix them evenly, add ball milling medium and place it in a ball mill for ball milling....

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Abstract

The invention belongs to the technical field of powder metallurgy, and particularly relates to a hard alloy resistant to high pressure and high temperature and a preparation method thereof. The hard alloy resistant to high pressure and high temperature comprises the following raw materials, by mass, 0.1-1.0 part of cobalt, 0.1-0.3 part of rhodium, 0.5-1 part of nickel carbonyl powder, 0.1-1.0 partof vanadium carbide, 10-20 parts of tantalum carbide, 0.6-1.0 part of niobium carbide, 2.0-4.0 parts of titanium carbide, 0.3-0.5 part of hafnium carbide, 0.1-0.5 part of aluminum nitride and 75-90 parts of tungsten carbide. In the hard alloy resistant to high pressure and high temperature, tungsten carbide is small in particle size and uniform in distribution, and the average grain size reaches0.10-0.25 micron; and meanwhile, the hard alloy resistant to high pressure and high temperature can reach HRA96.5, the bending strength can reach 3400 N/mm<2>, the compressive strength can reach 5200MPa, and good high pressure and high temperature resistant performance is achieved.

Description

technical field [0001] The invention belongs to the technical field of powder metallurgy, and in particular relates to a high-pressure-resistant and high-temperature hard alloy and a preparation method thereof. Background technique [0002] Cemented carbide is an alloy material made of hard compounds of refractory metals and bonding metals through powder metallurgy. It has a series of excellent properties such as high hardness, wear resistance, good strength and toughness, heat resistance, and corrosion resistance. Performance, known as "industrial teeth", widely used in tool materials, machining, aerospace, high pressure and high temperature tests and other fields. The hardness of cemented carbide commonly used in the domestic market can reach HRA86-93, and it remains basically unchanged even at a temperature of 500°C, and remains high at 1000°C. [0003] In the high-pressure and high-temperature test, because the test chamber can reach a pressure above 10-20GPa and a temp...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C29/02C22C1/05
Inventor 叶惠明叶少良诸优明叶戈
Owner HEYUAN ZHENGXIN HARDMETAL CARBIDE
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