High strength high elasticity titanium alloy and preparation method

A technology of titanium alloy and high elasticity, which is applied in the field of high-strength and high-elasticity titanium alloy and its preparation, can solve the problems of large residual stress, low fatigue performance, failure to achieve high strength and high elasticity, and achieve biocompatibility and mechanical properties Excellent compatibility, excellent elastic properties, and the effect of refining grain size

Active Publication Date: 2018-02-27
SOUTHEAST UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0005] This type of medical titanium alloy also has the potential to be used as a high-performance elastic material after strengthening treatment, but there are still some problems: ① When the elastic modulus of the alloy in the solid solution state (composed of β phase) is reduced to 55GPa-65GPa, Its intensity also decreases synchronously (σ 0.2 Usually less than 700MPa), can not meet the requirements of high strength and high elasticity
②Through 80-90% cold rolling deformation of the solid solution alloy, the strength can be significantly increased and the elastic modulus can be reduced, but it will lead to high density of crystal defects, large residual stress, poor plasticity, low fatigue performance, and loss of use value
③By performing aging heat treatment at 400°C-500°C on the cold-rolled alloy, the strength and fatigue properties can be significantly improved, but due to the precipitation of a large amount of α-phase with high elastic modulus, the elastic modulus of the alloy usually increases to 80-90GPa, lead to σ 0.2 The / E value has no obvious advantage over elastic titanium alloys such as β-C and Timetal LCB mentioned above
After aging treatment at 400~600℃, the σ of the alloy 0.2 The / E value is high, up to 1.5%, but the strength is low (σ b 765~1030MPa, σ 0.2 is 634-775MPa), which cannot meet the comprehensive performance requirements of high-strength and high-elasticity titanium alloys

Method used

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  • High strength high elasticity titanium alloy and preparation method
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  • High strength high elasticity titanium alloy and preparation method

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Experimental program
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Effect test

Embodiment 1

[0034] With high-purity Ti, Nb, Zr, Sn metal blocks and TiO 2 Powder is used as raw material to prepare alloy, and the weight of each component is: Ti: 61.075g; Nb: 31.000g; Zr: 5.000g; Sn: 2.000g; TiO 2 : 0.925g; the weight percent of each alloy element is: Nb: 31wt%; Zr: 5wt%; Sn: 2wt%; O: 0.37wt%, and the balance is Ti. The prepared raw materials are placed in a magnetically stirred vacuum non-consumable electric arc furnace for five times of repeated melting to obtain an ingot with uniform composition. The ingot was hot forged into a bar at 900°C with a deformation of 70%. After solution treatment at 850°C for 120 minutes, put it into water for quenching and cooling. Turning removes the scale on the surface of the bar, and then carries out cold rolling deformation with a deformation amount of 90% at room temperature. Place the rod in a quartz tube and vacuum seal it, heat it in a heat treatment furnace to 400°C for 15 hours, then put it into water and cool it to room te...

Embodiment 2

[0036] With high-purity Ti, Nb, Zr, Sn metal blocks and TiO 2 Powder is used as raw material to prepare alloy, the weight of each component is: Ti: 59.300g; Nb: 31.500g; Zr: 4.000g; Sn: 4.000g; TiO 2 : 1.200g; the weight percent of each alloy element is: Nb: 31.5wt%; Zr: 4wt%; Sn: 4wt%; O: 0.48wt%, and the balance is Ti. The prepared raw materials are placed in a magnetically stirred vacuum non-consumable electric arc furnace for five times of repeated melting to obtain an ingot with uniform composition. The ingot was hot forged into a bar at 950°C with a deformation of 75%. After solution treatment at 900°C for 100 minutes, put it into water for quenching and cooling. Turning removes the scale on the surface of the bar, and then carries out cold rolling deformation with a deformation amount of 87% at room temperature. Place the rod in a quartz tube and vacuum seal it, heat it in a heat treatment furnace to 470°C for 1 hour, then put it into water and cool it to room temper...

Embodiment 3

[0038] With high-purity Ti, Nb, Zr, Sn metal blocks and TiO 2 Powder is used as raw material to prepare alloy, the weight of each component is: Ti: 57.225g; Nb: 33.000g; Zr: 6.500g; Sn: 2.500g; TiO 2 : 0.775g; the weight percent of each alloy element is: Nb: 33wt%; Zr: 6.5wt%; Sn: 2.5wt%; O: 0.31wt%, and the balance is Ti. The prepared raw materials are placed in a magnetically stirred vacuum non-consumable electric arc furnace for five times of repeated melting to obtain an ingot with uniform composition. The ingot was hot forged into a bar at 950°C with a deformation of 75%. After solution treatment at 930°C for 80 minutes, put it into water for quenching and cooling. Turning removes the scale on the surface of the bar, and then carries out cold rolling deformation with a deformation amount of 80% at room temperature. Place the rod in a quartz tube and vacuum seal it, heat it in a heat treatment furnace to 450°C for 24 hours, then put it into water and cool it to room tem...

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Abstract

The invention relates to a high strength high elasticity titanium alloy and a preparation method. The alloy comprises the following components in percentages by weight: 31-33wt% of Nb, 4-8wt% of Zr, 2-4wt% of Sn, 0.30-0.55wt% of O (0.3wt% endpoint value is not contained) and the balance of Ti. The preparation method of the alloy comprises the follow specific steps: adopting a vacuum nonconsumableelectric-arc furnace to smelt to obtain a uniform alloy ingot, performing solution treatment at 850-950 DEG C after hot forging of a rod, and performing water cooling to room temperature; then performing cold rolling deformation processing, wherein the deformation is 80-90%; and finally, performing ageing thermal treatment, wherein the heating temperature is 400-500 DEG C and the insulating time is 1-24h. The titanium alloy provided by the invention has high strength and relatively low elasticity modulus. The elastic deformability is superior to those of various beta-titanium alloys high in elasticity. The titanium alloy is quite suitable for preparing ultralight small-sized elastic parts in the fields of aerospace, machinery and the like, and also can be applied to preparing biomedical implants.

Description

technical field [0001] The invention relates to a high-strength and high-elasticity titanium alloy and a preparation method thereof, and belongs to the technical field of design and preparation of titanium alloy materials. Background technique [0002] Due to the high strength of titanium alloy, the elastic modulus and density are only 50% and 60% of steel, respectively, and the elastic deformation capacity is about twice that of steel, which is very suitable for use as a lightweight high-performance elastic material. β-titanium alloy has good formability and can be strengthened with age, making it an ideal choice for high-strength titanium alloy elastic materials. Since the 1980s, McDonnell Douglas, Lockheed, Boeing, Airbus and other aircraft manufacturing companies have gradually used β titanium alloy springs for the upper and lower locks of aircraft landing gear, door balance, hydraulic return and flight control. The representative titanium alloys for springs are Ti-15V-...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C14/00C22F1/18
CPCC22C14/00C22F1/183
Inventor 陈锋蓝春波余新泉张友法
Owner SOUTHEAST UNIV
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