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A kind of gas diffusion catalytic electrode and its preparation method and its application in rechargeable zinc-air battery

A catalytic electrode and gas diffusion technology, which is applied to fuel cell type half cells and secondary cell type half cells, battery electrodes, circuits, etc. Low cost, good use effect, good catalytic activity effect

Active Publication Date: 2020-09-04
KUNMING NATAI TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] The technical problem to be solved in the present invention is to propose a high-activity gas diffusion catalytic electrode and its preparation method and its use in zinc-filled air in view of the lack of activity of the gas diffusion electrode in the existing zinc-air battery technology and the need to use noble metal catalytic materials. The application technology in the battery, while improving the activity of the gas diffusion electrode of the zinc-air battery, greatly reduces the production cost of the zinc-air battery

Method used

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  • A kind of gas diffusion catalytic electrode and its preparation method and its application in rechargeable zinc-air battery
  • A kind of gas diffusion catalytic electrode and its preparation method and its application in rechargeable zinc-air battery
  • A kind of gas diffusion catalytic electrode and its preparation method and its application in rechargeable zinc-air battery

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Experimental program
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Effect test

Embodiment 1

[0032] Embodiment 1: The gas diffusion catalytic electrode comprises a porous metal substrate, and oxidized and exfoliated graphite microflakes attached to the substrate, active catalysts are attached to the surface of the graphite microflakes, and the graphite microflakes are in an upright state, and their microscopic appearance is as follows: figure 2 shown.

[0033] Such as figure 1 As shown, the specific preparation steps of the preparation method of the gas diffusion catalytic electrode are as follows:

[0034] (1) Mix natural graphite flakes with binders and solvents to make a slurry, spread (coat) the slurry evenly on the porous metal substrate, and arrange a waterproof and breathable membrane on one side of the porous metal substrate. Dry under vacuum conditions to obtain a graphite composite electrode, and the waterproof and breathable membrane is pasted on one side of the porous metal substrate through the slurry;

[0035] (2) Put the graphite composite electrode ...

Embodiment 2

[0045] Embodiment 2: The gas diffusion catalytic electrode includes a porous metal substrate, and oxidized and exfoliated graphite microflakes attached to the substrate. The surface of the graphite microflakes is attached with an active catalyst. After the microsheet structure, its microscopic appearance is as follows figure 2 shown.

[0046] Such as figure 1 As shown, the specific preparation steps of the preparation method of the gas diffusion catalytic electrode are as follows:

[0047] (1) Mix natural graphite flakes with binders and solvents to make a slurry, spread (coat) the slurry evenly on the porous metal substrate, and arrange a waterproof and breathable membrane on one side of the porous metal substrate. 1. Dry under the negative pressure of 0.06MPa to obtain a graphite composite electrode, and the waterproof and breathable membrane is pasted on one side of the porous metal substrate through the slurry;

[0048] (2) Put the graphite composite electrode in the s...

Embodiment 3

[0052] Embodiment 3: The gas diffusion catalytic electrode includes a porous metal substrate, and oxidized and exfoliated graphite microflakes attached to the substrate. The surface of the graphite microflakes is attached with an active catalyst, and the graphite microflakes are in an upright state, that is, the natural flake graphite has undergone electrochemical exfoliation. The subsequent microchip structure.

[0053] Such as figure 1 As shown, the specific preparation steps of the preparation method of the gas diffusion catalytic electrode are as follows:

[0054] (1) Mix natural graphite flakes with binders and solvents to make a slurry, spread (coat) the slurry evenly on the porous metal substrate, and arrange a waterproof and breathable membrane on one side of the porous metal substrate. 1. Dry under the negative pressure of 0.1MPa to obtain a graphite composite electrode, and the waterproof and breathable membrane is pasted on one side of the porous metal substrate th...

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Abstract

The invention discloses a gas diffusion catalytic electrode, a preparation method thereof and application of the gas diffusion catalytic electrode to a rechargeable zinc air battery, and belongs to the technical field of battery electrode materials. The gas diffusion catalytic electrode comprises a porous metal substrate made of a nickel foam or nickel net or a nickel-plated copper net, and an oxidization-stripped graphite micro-sheet attached to the substrate, wherein the graphite micro-sheet is in an upright state; an active catalyst is attached to the surface of the graphite micro-sheet. The preparation method comprises the following steps: uniformly mixing natural flake graphite with a binder and a solvent to make slurry, and uniformly distributing the slurry on the porous metal substrate; drying to obtain a graphite composite electrode; then putting the graphite composite electrode into stripping electrolyte, and applying a voltage to realize electrochemical oxidization stripping;taking the stripped graphite composite electrode out, and cleaning; putting the graphite composite electrode into deposition electrolyte to deposit a transition metal oxide in an electrochemical way;taking the graphite composite electrode out, and cleaning; drying the cleaned graphite composite electrode to obtain the gas diffusion electrode. The electrode is taken as an electrode of the rechargeable zinc air battery, has the advantages of high activity, low cost, simple preparation process, good use effect and the like, and is suitable for use in batteries such as zinc air batteries.

Description

technical field [0001] The invention relates to a gas diffusion catalytic electrode, a preparation method thereof and an application in a zinc-filled air battery, belonging to the technical field of battery electrode materials. Background technique [0002] Energy is the lifeblood of economic development, and electrochemical power sources play an important role in it. Electrochemical power sources have undergone tremendous progress from lead-acid batteries, nickel metal hydride batteries, and now lithium-ion batteries. Lithium-ion batteries are now widely used in small electronic devices, power supplies for vehicles, and the like. However, with the development of society, the improvement potential of lithium-ion battery safety, energy density and economy can no longer meet the growth rate of people's demand. Zn-air batteries have attracted attention due to their extremely high theoretical energy density (1086 Wh / kg containing oxygen), good safety, environmental friendlines...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/86H01M4/88H01M4/90H01M12/08
CPCH01M4/8605H01M4/8673H01M4/8807H01M4/8817H01M4/8853H01M4/9016H01M12/08Y02E60/10
Inventor 肖辉刘铸
Owner KUNMING NATAI TECH CO LTD