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Plasticizing method for plant fiber raw materials

A plant fiber and fiber raw material technology, which is applied in the field of plant fiber raw material processing and application, can solve the problems of glycerin being difficult to solidify and high cost, and achieve the effect of low cost and simple and feasible process

Inactive Publication Date: 2018-04-06
NANJING FORESTRY UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

This patent uses sodium ferric tartrate and glycerin to make plant fiber raw materials have the properties of wood-plastic, but the relative cost of sodium ferric tartrate and glycerin is relatively high, and glycerin is not easy to solidify, which is unfavorable for future applications
[0006] Chinese patent CN105504585A discloses a kind of wood-plastic material, which is produced and processed through the raw materials in the following weight ratio: waste polyvinyl chloride 20-40%, plant fiber 10-15%, calcium bicarbonate 15-25%, glue 2 ~7%, lubricant 3~6%, wood powder 2~30%, straw powder 1~22%, polypropylene ester 2~10%, zirconia 1~4%, ruthenium oxide 2~6%, the inventive wood Plastic materials can be processed in one step. However, the wood-plastic material is formed by adding polymer plastics and other plastic materials, relying on the plasticizing properties of plastic polymers, without plasticizing the wood itself.
[0007] Chinese patent CN105694502A discloses a wood-plastic material, which is made of the following raw materials in parts by weight: 30-40 parts of wood powder, 25-35 parts of straw powder, 25-35 parts of plant rattan powder, 10-15 parts of paper powder, old 10-15 parts of plastic pellets, 19-25 parts of polypropylene, 19-25 parts of polyvinyl chloride, 12-18 parts of strengthening agent, 8-13 parts of filler, 8-13 parts of adhesive, the wood-plastic material of this invention is made Simple, making full use of diverse raw materials, but the method of plasticizing wood is still based on mixed plastic polymers, without plasticizing and modifying the wood itself

Method used

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  • Plasticizing method for plant fiber raw materials
  • Plasticizing method for plant fiber raw materials
  • Plasticizing method for plant fiber raw materials

Examples

Experimental program
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Effect test

Embodiment 1

[0030] The method for plasticizing plant fiber raw materials with inorganic acid in this embodiment is carried out according to the following steps:

[0031] 1. Take 300g of dry wheat straw, and use a high-speed mixer to evenly disperse sulfuric acid in the middle of the wheat straw. The mass ratio of pure sulfuric acid to dry wheat straw is 5 / 100.

[0032] 2. Set the temperature of zones I, II, III, and IV of the twin-screw extruder to 160°C, 150°C, 130°C, and 120°C, respectively. Mixing the mixture obtained in step 1 in a twin-screw extruder with a set temperature to obtain a plasticized base material of wheat straw;

[0033] 3. Add the base material obtained in step 2 into the national standard abrasive tool, and use a flat vulcanizing machine to hot press at 160°C and a pressure of 20Mpa. A standard sample with a wheat straw content of 95wt% can be obtained. Its mechanical properties are shown in Table 1. The melting temperature of the base material is about 135°C when t...

Embodiment 2

[0037] 1. Take 300g of dry wheat straw, and use a high-speed mixer to evenly disperse sulfuric acid in the middle of the wheat straw. The ratio of the mass of pure sulfuric acid to the mass of dry wheat straw is 5 / 100.

[0038]2. Set the temperature of zones I, II, III, and IV of the twin-screw extruder to 160°C, 150°C, 130°C, and 120°C, respectively. The mixture obtained in step 1 is kneaded in a twin-screw extruder with a set temperature to obtain a plasticized base material of wheat straw.

[0039] 3. Mix 21.25g, 31.75g, 42.25g of maleic anhydride modified polyethylene with 75g, 65g, 55g of the plasticized material obtained in step 2, respectively, and set the temperature in zones I, II, III, and IV of the twin-screw extruder to The settings are 170°C, 150°C, 130°C, 120°C. The mixture is kneaded and extruded in a set twin-screw extruder to obtain a composite material of maleic anhydride polyethylene and wheat straw plasticized base material.

[0040] 4. Add the composite ...

Embodiment 3

[0044] 1. Take 300g of dry wheat straw, and use a high-speed mixer to evenly disperse sulfuric acid in the middle of the wheat straw. The ratio of the mass of pure sulfuric acid to the mass of dry wheat straw is 5 / 100.

[0045] 2. Set the temperature of zones I, II, III, and IV of the twin-screw extruder to 160°C, 150°C, 130°C, and 120°C, respectively. The mixture obtained in step 1 is kneaded in a twin-screw extruder with a set temperature to obtain the wheat straw plasticized base material.

[0046] 3. Mix 31.75g ​​of maleic anhydride modified polyethylene with 65g of the plasticized base material obtained in step 2, and set the temperature in zones I, II, III, and IV of the twin-screw extruder to 170°C, 150°C, and 130°C respectively , 120°C. The mixture is kneaded and extruded in a set twin-screw extruder to obtain a composite material of maleic anhydride modified polyethylene and wheat straw plasticized base material.

[0047] 4. After crushing the above composite materi...

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Abstract

The invention relates to a plasticizing method for plant fiber raw materials and belongs to the field of plant fiber raw material processing and application. The invention provides a novel processingtechnology of the plant fiber raw materials, wherein a wood plant fiber raw material has thermoplasticity. The method includes the steps of: 1) adding inorganic acid to crushed plant fiber raw materials with uniform mixing, and feeding the mixture to a plastication device; 2) heating, plasticating and shearing the mixture to obtain a plant fiber base material which can be repeatedly processed. According to the plasticizing method, with the inorganic acid as a plasticizer, the plasticization temperature of the plant fiber raw materials is reduced by means of extrusion and shearing effects of ascrew rod or the plastication device, so that the wood fibers can be directly thermally shaped at 50-240 DEG C and can be compounded with a high-molecular material. The plant fiber raw materials can be effectively applied to the fields such as plastic, wood-plastic composite materials, texture, wood processing, etc. The invention develops the application range of the plant fiber raw materials.

Description

technical field [0001] The invention belongs to the field of processing and application of plant fiber raw materials, and mainly relates to a plasticizing method of plant fiber raw materials. Background technique [0002] At present, non-renewable resources are increasingly in short supply, and the energy crisis is becoming more and more serious. Biomass energy has become a hot spot in international research because of its advantages such as wide sources, strong renewability, and low price. Among them, plant fiber raw materials have become an ideal substitute for fossil resources. [0003] Wood plasticization traditionally refers to replacing the hydroxyl groups in wood with other functional groups by means of esterification and etherification to reduce the hydrogen bonds between components, reduce the bonding between molecules, and destroy cellulose. The crystalline structure of the wood makes the wood soften at a certain temperature and becomes a thermoplastic material. ...

Claims

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Application Information

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IPC IPC(8): C08J3/18C08L97/02C08L51/06C08L77/00
CPCC08J3/18C08J2397/02C08L97/02C08L51/06C08L77/00
Inventor 周小凡刘翠翠赵康陆海龙颜明王志国马金霞
Owner NANJING FORESTRY UNIV