Fully-biodegradable plastic and preparation method thereof

A fully degradable plastic technology, applied in the field of fully biodegradable plastics and its preparation, can solve the problems of easy fiber aggregation, poor dispersion, and less research, and achieve the effects of improving mechanical properties, reducing hydrophobicity, and improving dispersion

Inactive Publication Date: 2018-04-06
肖宇萍
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

As the basic agricultural products, rice and wheat have a large annual output. Except for a small amount of rice and wheat by-product straw, which is used for gaskets, feeding livestock, and partly used for composting, most of them are abandoned or burned as fuel; wheat The by-product bran of wheat bran is mainly used as feed or discarded, resulting in a great waste of resources; current research mainly focuses on the functional research of some components or components of wheat bran, and less research on other aspects; therefore rice straw and wheat bran are not properly ut

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Weigh the following raw materials in weight proportions: 40 parts of polycaprolactone, 10 parts of straw fiber, 10 parts of bran, 5 parts of chitosan, 4 parts of biuret modified epoxy resin, diphenylmethane 2 parts of isocyanate, 1 part of acetyl tributyl citrate, 0.1 part of 2,2-bis(4-hydroxyphenyl) propane, 1 part of polypropylene grafted maleic anhydride, 1 part of silane coupling agent, 1 part of stearic acid 1 part, 1 part carrageenan, 1 part glycerin.

[0022] Prepare as follows:

[0023] (1) Pretreatment of bran: crush wheat bran to a particle size of 100 mesh, mix the crushed wheat bran with water at a mass ratio of 1:10, add 1 mol / L of sulfuric acid to adjust the pH to 5, Heat to 60°C for 4 hours; then wash with absolute ethanol and water until neutral, then sonicate for 10 minutes under the condition of ultrasonic power 200W; adjust the pH to 4 with 1mol / L sulfuric acid, add α-amylase, and Enzymolysis at 40°C for 30 minutes; add 1mol / L sodium hydroxide to ad...

Embodiment 2

[0029] Weigh the following raw materials in weight ratio: 60 parts of polycaprolactone, 20 parts of straw fiber, 20 parts of bran, 15 parts of chitosan, 10 parts of biuret modified epoxy resin, diphenylmethane 8 parts of isocyanate, 7 parts of acetyl tributyl citrate, 0.5 parts of 2,2-bis(4-hydroxyphenyl)propane, 8 parts of polypropylene grafted maleic anhydride, 5 parts of silane coupling agent, 5 parts of stearic acid parts, carrageenan 5 parts, glycerin 7 parts.

[0030] Prepare as follows:

[0031](1) Pretreatment of bran: crush wheat bran to a particle size of 150 mesh, mix the crushed wheat bran with water at a mass ratio of 2:10, add 1 mol / L of sulfuric acid to adjust the pH to 6, Heat to 40°C for 3 hours; then wash with absolute ethanol and water until neutral, then sonicate for 5 minutes under the condition of ultrasonic power 400W; adjust the pH to 5 with 1mol / L sulfuric acid, add α-amylase, and Enzymolysis at 40°C for 30 minutes; add 1mol / L sodium hydroxide to adj...

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PUM

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Abstract

The invention discloses a fully-biodegradable plastic and a preparation method thereof and relates to the technical field of plastic preparation. The fully-biodegradable plastic is prepared from, by weight, 40-60 parts of polycaprolactone, 10-20 parts of straw fiber, 10-20 parts of bran, 5-15 parts of chitosan, 4-10 parts of biuret modified epoxide resin, 2-8 parts of methylene diphenyl diisocyanate, 1-7 parts of acetyl tributyl citrate, 0.1-0.5 part of 2,2-bis(4-hydroxyl phenyl) propane, 1-8 parts of polypropylene grafted maleic anhydride, 1-5 parts of silane coupling agent, 1-5 parts of stearic acid, 1-5 parts of carrageenan and 1-7 parts of glycerin. The preparation method comprises the steps of bran pretreatment, straw fiber modification, mixture, extrusion, blow molding and the like.The plastic can be fully biodegradable, can be completely biodegraded outdoors in 3-9 months and does not pollute the environment. In addition, the structural strength and the mechanical strength of the fully-biodegradable plastic are improved, the tensile strength of the plastic is 9-18 N/mm<2>, the breaking strength is 10-28 N/mm<2>, and the elongation at break is 100-240%.

Description

technical field [0001] The invention relates to the technical field of plastic preparation, in particular to a fully biodegradable plastic and a preparation method thereof. Background technique [0002] With the increasingly serious problems of environmental pollution and energy shortage, the development and application of environmentally friendly materials have become the focus of research. Environmentally friendly materials use renewable resources as raw materials, the products are biodegradable, the sources of raw materials are abundant, and the advantages of product degradation and pollution-free promote their vigorous development and application. In the process of product development, degradable polymers have received extensive attention due to the use of non-petroleum raw materials. [0003] Natural fibers are often used as reinforcements and fillers instead of some synthetic fibers due to their cheap availability, renewable and good biocompatibility. In recent years...

Claims

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Application Information

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IPC IPC(8): C08L67/04C08L1/10C08L97/02C08L5/08C08L5/00C08L63/00C08K5/11C08K5/053C08K5/13C08B3/10
CPCC08B3/10C08K2201/018C08L67/04C08L2201/06C08L2203/16C08L2205/02C08L2205/035C08L2205/08C08L2205/16C08L1/10C08L97/02C08L5/08C08L5/00C08L63/00C08K5/11C08K5/053C08K5/13
Inventor 肖宇萍
Owner 肖宇萍
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