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Chemical polymerization solution, conductive polymer solid slice aluminum electrolytic capacitor and preparation method thereof

A technology of aluminum electrolytic capacitors and conductive polymers, applied in solid electrolytic capacitors, electrolytic capacitor manufacturing, electrolytic capacitors, etc., can solve problems such as unobtainable and unapplied high-capacity products, solid capacitor capacity, loss ESR differences, etc.

Active Publication Date: 2018-05-01
CHINA ZHENHUA GRP XINYUN ELECTRONICS COMP ANDDEV CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Similarly, when this conductive polymer solid electrolyte is applied to a conductive polymer solid chip aluminum electrolytic capacitor, there are large differences in the capacity, loss and ESR of the solid capacitor, and it is not yet possible to obtain a solid capacitor with specific performance.
Moreover, the current conductive polymer solid chip aluminum electrolytic capacitors are mainly used in 2V-6.3V products, and cannot be used in other high-capacity products

Method used

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  • Chemical polymerization solution, conductive polymer solid slice aluminum electrolytic capacitor and preparation method thereof
  • Chemical polymerization solution, conductive polymer solid slice aluminum electrolytic capacitor and preparation method thereof
  • Chemical polymerization solution, conductive polymer solid slice aluminum electrolytic capacitor and preparation method thereof

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preparation example Construction

[0040] An embodiment of the present invention provides a method for preparing a conductive polymer solid chip aluminum electrolytic capacitor, which includes the following steps:

[0041] S1. Put the aluminum foil to be polymerized into the pretreatment liquid for the first stage performance modification treatment. The pretreatment liquid is mainly composed of monomers, solvents and coupling agents. Take it out after 50-120s and dry it. Oven at 50-65°C for 8-12 minutes, then put in an oven at 110-125°C for 8-12 minutes, and cool at room temperature to obtain pretreated aluminum foil. In this embodiment, the aluminum foil is used as the anode of the capacitor, and the pretreatment solution treats the surface of the aluminum foil, which can increase the capacity extraction rate of the aluminum foil. In this embodiment, the 14VF aluminum foil containing alumina is generally cut into an aluminum foil with an effective area of ​​3.6mm×4.5mm and the oxide film is chemically repaired...

Embodiment 1

[0053] This embodiment provides a conductive polymer solid chip aluminum electrolytic capacitor, which is prepared according to the following preparation method:

[0054] (1) Preparation of pretreatment solution: respectively add 2 g of N-methylpyrrole (monomer) and 2 g of silane coupling agent (coupling agent) to 100 g of ethanol (solvent), and stir magnetically for 3 min.

[0055] Preparation of chemical polymerization solution: Take 8g of silane coupling agent (coupling agent) and add it to 100g of ethanol (solvent), stir magnetically for 3min, add 8g of iron p-toluenesulfonate (oxide), stir magnetically for 1min, then add 2g of N-methyl base pyrrole (monomer), magnetically stirred for 1 min.

[0056] Preparation of mixed solution: 60g of ethanol (solvent) and 10g of silane coupling agent (coupling agent) were stirred and mixed evenly.

[0057] (2) Cut the 14VF aluminum foil containing alumina into an aluminum foil with an effective area of ​​3.6mm×4.5mm and form it into a...

Embodiment 2

[0065] This embodiment provides a conductive polymer solid chip aluminum electrolytic capacitor, which is prepared according to the following preparation method:

[0066] (1) Preparation of pretreatment solution: respectively add 2 g of N-methylpyrrole (monomer) and 2 g of silane coupling agent (coupling agent) to 100 g of ethanol (solvent), and stir magnetically for 3 min.

[0067] Preparation of the first chemical polymerization solution: Take 8g of silane coupling agent (coupling agent) and add it to 100g of ethanol (solvent), stir magnetically for 3min, add 8g iron p-toluenesulfonate (oxide), stir magnetically for 1min, then add 2g N - Methylpyrrole (monomer), magnetically stirred for 1 min.

[0068] Preparation of the second chemical polymerization solution: Take 6g of silane coupling agent (coupling agent) and add it to 100g of ethanol (solvent), stir magnetically for 3min, add 12g iron p-toluenesulfonate (oxide), stir magnetically for 1min, then add 4g N - Methylpyrrol...

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Abstract

The present invention relates to a chemical polymerization solution, a conductive polymer solid slice aluminum electrolytic capacitor and a preparation method thereof, and relates to the technical field of production of conductive polymer solid slice aluminum electrolytic capacitors. The chemical polymerization solution comprises the compositions of percentage by weight: 0.1-20% of a monomer, 2-20% of oxygenant, 60-93% of solvent, and 0.5-10% of coupling agent. The chemical polymerization solution is configured to prepare a solid electrolyte layer with controllable performances to obtain a capacitor with expected performances. The preparation method of the conductive polymer solid slice aluminum electrolytic capacitor employs premixed solution, a chemical polymerization solution and mixedliquor to perform multi-time chemical polymerization processing until the compact and uniform solid electrolyte layer is formed at the surface of an aluminum foil to prepare the capacitor, and therefore the method is simple. The conductive polymer solid slice aluminum electrolytic capacitor prepared by the chemical polymerization solution is good in electric parameter and excellent in performance,and can be applied to the high-capacity products.

Description

technical field [0001] The invention relates to the technical field of production of conductive polymer solid chip aluminum electrolytic capacitors, and in particular to a chemical polymerization solution, conductive polymer solid chip aluminum electrolytic capacitors and a preparation method thereof. Background technique [0002] In recent years, the CPU frequency has become higher and higher, and the high heat generated has higher and higher requirements on the motherboard capacitance. Major motherboard manufacturers have used solid electrolytic capacitors on the motherboards produced, making the global solid electrolytic capacitor market Demand rose rapidly to shine. Solid electrolytic capacitors are capacitors composed of a thin layer of oxides generated by oxidation on the surface of valve metals such as aluminum, tantalum, niobium, titanium, or oxides such as niobium monoxide as electrolytes, and solid electrolytes as cathodes. Conductive polymer solid capacitors Refe...

Claims

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Application Information

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IPC IPC(8): H01G9/028H01G9/15H01G9/00
CPCH01G9/0036H01G9/028H01G9/15
Inventor 陈琛秦钟华武林玉靳博李如升蒋松成
Owner CHINA ZHENHUA GRP XINYUN ELECTRONICS COMP ANDDEV CO LTD
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