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Preparation method of modified carbon fiber thermal insulation composite material

A composite material, modified carbon technology, applied in the direction of carbon fiber, fiber treatment, fiber chemical characteristics, etc., can solve the problems of poor interface adhesion between materials, low adsorption performance, etc., to achieve high thermal insulation capacity, high porosity, high Adsorbent effect

Active Publication Date: 2018-05-11
嘉兴德毅新材料有限公司
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  • Abstract
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  • Application Information

AI Technical Summary

Problems solved by technology

[0005] At the same time, because the carbon fiber preparation process includes carbonization or graphitization, the carbon atom stacking orientation on the carbon fiber surface is more consistent, and the atomic layer spacing is smaller, so the fiber surface is non-polar and chemically inert. In addition, the carbon fiber surface has hydrophobic, Shortcomings such as smoothness and low adsorption performance lead to poor interfacial bonding between carbon fiber and its composite material

Method used

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Experimental program
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Embodiment Construction

[0020] A method for preparing a modified carbon fiber thermal insulation composite material, comprising the following steps:

[0021] (1) Crush the silicon powder through a 180-mesh sieve, and soak it in hot water at 60°C for 20 minutes. When putting in the hot water, add half of the silicon powder first, then add the remaining silicon powder in 3 times, and then pour off the hot water. Add the activated silica powder into 20% sodium hydroxide solution, stir continuously after being completely submerged and heat to 90°C, and react at this temperature for 8 hours to obtain alkaline silica sol;

[0022] (2) Put the spinning solution in the electrospinning apparatus, wrap the receiver with aluminum foil, and collect the as-spun fibers on the aluminum foil. The process parameters of the spinning process are positive pressure 15kV, negative pressure 1.5kV, and advance rate 0.04 mm / min, the receiving rate is 30r / min, the distance between the needle and the receiver is 15cm, and the ...

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Abstract

The invention discloses a preparation method of a modified carbon fiber thermal insulation composite material. The modified carbon fiber thermal insulation composite material is prepared from raw materials of silicon powder, coconut shell, phenol, polyvinyl alcohol, etc. The preparation method is characterized in that the coconut shell is used to prepare porous carbon fiber and undergoes a plurality of modification processes to obtain porous carbon fiber with high mechanical strength and high adsorption; and then the porous carbon fiber is impregnated with alkaline silica sol, so that the well-developed mesoporous structure of the silica sol makes the carbon fiber have high temperature resistance and extremely low thermal conductivity, and further strengthens the thermal insulation capacity of the carbon fiber. The obtained composite material is not only light in weight, but also has high thermal insulation ability and low thermal conductivity, so that use cost of the thermal insulation material is greatly reduced, and the modified carbon fiber thermal insulation composite material is suitable for the needs of thermal insulation materials in various fields.

Description

technical field [0001] The invention relates to the technical field of heat insulation materials, in particular to a preparation method of a modified carbon fiber heat insulation composite material. Background technique [0002] With the development of science and technology, the demand for thermal insulation materials in various fields of national economy such as military, national defense, metallurgy, and chemical industry is increasing day by day, and the performance requirements for thermal insulation materials are getting higher and higher. my country has at least 100,000 high-temperature furnaces such as cemented carbide sintering furnaces, monocrystalline silicon furnaces, polycrystalline ingot furnaces, vacuum smelting furnaces, vacuum heat treatment furnaces, and vapor deposition furnaces. A large part of these high-temperature furnaces are still common Traditional thermal insulation materials are heavy, have high thermal conductivity, and part of the molding process...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B28/24D01F9/24D06M10/06D06M101/40
CPCC04B28/24D01F9/24D06M10/06D06M2101/40C04B14/386
Inventor 孙仁贵
Owner 嘉兴德毅新材料有限公司
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