Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

A kind of radiation cross-linking low-smoke and halogen-free flame retardant fuel for automobile wire and its preparation method

A technology for automobile wires and fuel resistance, which is applied in the direction of plastic/resin/wax insulators, organic insulators, electrical components, etc. It can solve the problems of low decomposition temperature of polyvinyl chloride, high material density, energy-saving requirements, and poor high temperature resistance. Achieve the best production extrusion processing performance, meet the high-speed production needs, and achieve the effect of excellent mechanical properties

Active Publication Date: 2020-09-15
SHANGHAI KAIBO SPECIAL CABLE FACTORY
View PDF13 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although polyvinyl chloride has the advantages of low price and easy processing, it has disadvantages such as low decomposition temperature and poor high temperature resistance, which not only restricts its development, but also limits its use.
The rapid development of the industry will inevitably put forward higher requirements for the performance of automotive wires, high and low temperature resistance requirements, high scratch resistance, oil resistance and corrosion of various automotive liquids, etc. At the same time, environmental protection and halogen-free are also an inevitable development trend; with the new market With the gradual development of energy vehicles, more solutions are being sought to reduce the weight of traditional fuel vehicles; currently, there are automotive wire insulation layers made of radiation cross-linkable halogen-free flame-retardant polyolefin materials on the market. Poor aging resistance, poor scratch resistance, poor processing performance, and slow extrusion speed. At the same time, high material density is not conducive to energy saving requirements, and it is difficult to meet the requirements of automotive thin-walled wires with a temperature resistance of 125°C.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • A kind of radiation cross-linking low-smoke and halogen-free flame retardant fuel for automobile wire and its preparation method
  • A kind of radiation cross-linking low-smoke and halogen-free flame retardant fuel for automobile wire and its preparation method
  • A kind of radiation cross-linking low-smoke and halogen-free flame retardant fuel for automobile wire and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0040] An irradiation cross-linked low-smoke halogen-free flame-retardant material for automobile wires. The raw material components and proportions are as follows: 30 parts of base resin; 10 parts of compatibilizer; 15 parts of flame retardant; 5 parts of filler; 0.75 parts of oxygen agent; 2.5 parts of lubricant; 1.5 parts of sensitizer.

[0041] Among them, based on the total weight of the substrate resin, linear low-density polyethylene accounts for 66 percent; ethylene-butyl acrylate copolymer accounts for 17 percent; and ethylene-propylene copolymer resin accounts for 17 percent.

[0042] The compatibilizer is polyethylene grafted maleic anhydride copolymer.

[0043] The flame retardant is a combination of melamine polyphosphate and high molecular weight ammonium polyphosphate, and the mass ratio of melamine polyphosphate and high molecular weight ammonium polyphosphate is 3:1.

[0044] The filler is a combination of ultrafine silica powder and calcium carbonate silica ...

Embodiment 2

[0049] An irradiation cross-linked low-smoke halogen-free flame-retardant material for automobile wires. The raw material components and proportions are as follows: 40 parts of base resin; 15 parts of compatibilizer; 25 parts of flame retardant; 5 parts of filler; 0.9 parts of oxygen agent; 3 parts of lubricant; 2 parts of sensitizer.

[0050] Wherein, based on the total weight of the substrate resin, linear low-density polyethylene accounts for 50 percent; ethylene-butyl acrylate copolymer accounts for 25 percent; and ethylene-propylene copolymer resin accounts for 25 percent.

[0051] The compatibilizer is ethylene-octene copolymer grafted with maleic anhydride copolymer.

[0052] The flame retardant is a combination of melamine polyphosphate and high molecular weight ammonium polyphosphate, and the mass ratio of melamine polyphosphate and high molecular weight ammonium polyphosphate is 3:1.

[0053] The filler is a combination of ultrafine silica powder and calcium carbona...

Embodiment 3

[0058] An irradiation cross-linked low-smoke halogen-free flame-retardant material for automobile wires. The raw material components and proportions are as follows: 50 parts of base resin; 15 parts of compatibilizer; 30 parts of flame retardant; 8 parts of filler; 1.1 parts of oxygen agent; 3.5 parts of lubricant; 2 parts of sensitizer.

[0059] Wherein, based on the total weight of the substrate resin, linear low-density polyethylene accounts for 50 percent; ethylene-butyl acrylate copolymer accounts for 30 percent; and ethylene-propylene copolymer resin accounts for 20 percent.

[0060] The compatibilizer is ethylene-octene copolymer grafted with maleic anhydride copolymer.

[0061] The flame retardant is a combination of melamine polyphosphate and high molecular weight ammonium polyphosphate, and the mass ratio of melamine polyphosphate and high molecular weight ammonium polyphosphate is 3:1.

[0062] The filler is a combination of superfine silica powder and calcium carbo...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
melt flow indexaaaaaaaaaa
densityaaaaaaaaaa
melt flow indexaaaaaaaaaa
Login to View More

Abstract

The invention provides an irradiation cross-linking low-smoke halogen-free fuel for vehicle cables, and a preparation method thereof, wherein the raw materials comprise, by weight, 30-60 parts of a base material resin, 10-25 parts of a compatibilizer, 15-35 parts of a flame retardant, 5-10 parts of a filler, 0.75-1.35 parts of an antioxidant, 2.5-5 parts of a lubricant, and 1.5-2.5 parts of a cross-linking sensitizing agent. According to the present invention, the base material resin is modified by adding the compatibilizer, the flame retardant and other auxiliary agents, such that the prepared irradiation cross-linking low-smoke halogen-free fuel has advantages of low material density, no halogen, environmental protection, flame retardant property and high wear resistance, can resist various oil products and corrosive liquids for vehicles, further has advantages of chemical corrosion resistance, ultra-low-temperature resistance, excellent mechanical property and extremely excellent production extrusion processing performance, and can meet the high-speed production requirements.

Description

technical field [0001] The invention relates to the field of polymer materials for electric wires and cables, and specifically discloses an irradiation cross-linked low-smoke and halogen-free flame retardant for automobile wires and a preparation method thereof. Background technique [0002] In recent years, the current automobile industry in the whole world is still developing rapidly, and my country's domestic automobile industry is also keeping up with the pace and developing at a high speed. At the same time, the performance requirements for various automobile accessories are also getting higher and higher. The raw material of traditional automotive wire insulation is almost all polyvinyl chloride. Although polyvinyl chloride has the advantages of low price and easy processing, it has disadvantages such as low decomposition temperature and poor high temperature resistance, which not only restrict its development, but also limit its use. The rapid development of the indu...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/08C08L23/16C08L51/06C08L23/06C08K13/02C08K5/3492C08K3/32C08K3/36C08K3/26C08K5/098H01B3/44C08J7/12
CPCC08J7/123C08J2323/08C08J2423/08C08K2201/014C08L23/0815C08L2201/02C08L2201/22C08L2203/202C08L2205/025C08L2205/035C08L2312/06H01B3/44H01B3/441C08L23/0869C08L23/06C08L51/06C08K13/02C08K5/34928C08K2003/323C08K3/36C08K2003/265C08K5/098
Inventor 王文君项健杨帅
Owner SHANGHAI KAIBO SPECIAL CABLE FACTORY
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products