High-fluorine wear-resistant self-lubricating material

A self-lubricating material and high fluorine technology, applied in the field of material manufacturing, can solve problems such as poor product stability, high impurity content, and material structural performance degradation, and achieve low production costs, low impurity content, and stable performance.

Inactive Publication Date: 2018-07-27
武汉鼎瑞新材料有限责任公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

From the above process, it can be seen that the traditional polymerization production method is more complicated, and there are still disadvantages such as poor product stability and high impurity content, and it will also bring a lot of "three wastes" to the environment, increasing the cost and pressure of environmental protection
[0005] In addition, the current common production of fluorine-containing materials is mainly to introduce fluorine atoms through chemical reactions, such as graft modification, copolymerization, etc. This method of chemical introduction limits the fluorine content to a low level, so it cannot fully display the fluorine-containing materials. If too much fluorine-containing material is forcibly added, there will be problems such as dissociation of fluorine-containing monomers, degradation of material structure performance, and serious environmental pollution. However, research has found that the introduction of high fluorine content can significantly improve the self-lubrication and wear resistance of materials

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Add 900 g of polycaprolactone polyol, 6.2 g of ethylene glycol, and 199.1 g of allyl heptafluoroisopropyl ether into the container. Use a high-speed stirrer to stir at 1000 rpm for 10 minutes, and then add 222 g of isophorone The isocyanate was stirred at 500 rpm for 2 minutes and then put into the curing box for curing at 100 degrees Celsius for 10 hours to obtain material 1.

Embodiment 2

[0023] Add 900 g of polycaprolactone polyol, 9 g of 1,4-butanediol, and 276.4 g of allyl pentafluorobenzene into the container. Use a high-speed stirrer to stir for 8 minutes at 1100 rpm, and then add 196.5 g of dicyclohexyl methane The diisocyanate was stirred at 600 rpm for 5 minutes and then put into a curing box for curing at a temperature of 100 degrees Celsius for 10 hours to obtain material 2.

Embodiment 3

[0025] Add 900g of polycaprolactone polyol, 13.4g of dipropylene glycol, 357.7g of 1H,1H-heptafluorobutylmethacrylamide into the container, use a high-speed stirrer to stir at 1500rpm for 10min, and then add 159.8g of benzodiazepine Methyl diisocyanate was stirred at 700 rpm for 2 minutes and then put into a curing box for curing at a temperature of 100 degrees Celsius for 12 hours to obtain material 3.

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Abstract

The invention relates to a high-fluorine wear-resistant self-lubricating material. According to a technical scheme in the invention, the high-fluorine wear-resistant self-lubricating material is prepared by mixing the following at least three raw materials: isocyanate and polyol with a melting point of no more than 150 DEG, and a fluorine-containing organic material with a melting point of no morethan 150 DEG and a kinematic viscosity of 0.75 to 100, 000 mm<2> / s at 20 DEG C. The wear-resistant self-lubricating material has the advantages of low production cost, stable performance, good compatibility and excellent performance.

Description

Technical field [0001] The invention relates to the field of material manufacturing, in particular to a high-fluorine wear-resistant self-lubricating material. Background technique [0002] Self-lubricating materials refer to the use of solid powders, films or some integral materials to reduce the friction and wear between two bearing surfaces. In the solid lubrication process, the solid lubricating material and the surrounding medium have to physically and chemically react with the friction surface to form a solid lubricating film to reduce friction and wear. [0003] Common self-lubricating materials, such as polytetrafluoroethylene (PTFE), although they have excellent properties such as corrosion resistance, weather resistance, high lubrication, and electrical insulation, but because polytetrafluoroethylene is a typical soft and weak polymer, large molecules The mutual gravitational force is small, rigidity, hardness, and strength are small. It will deform under long-term stres...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/66C08G18/42C08G18/32C08G18/48C08G18/62C08G18/65C08G18/67C10M149/14C10N30/06
CPCC08G18/3215C08G18/4238C08G18/4277C08G18/4833C08G18/4854C08G18/6204C08G18/6511C08G18/664C08G18/6644C08G18/6674C08G18/675C10M149/14C10M2217/045C10N2030/06
Inventor 梅黎黎朱顺全
Owner 武汉鼎瑞新材料有限责任公司
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